Recovery of fatty acids by immobilized solvent extraction /

The use of silicone rubber tubes swollen with solutions of TOPO (trioctyl phospine oxide) in kerosene as membranes for the recovery of fatty acids from anaerobic digesters was investigated. The flux of acetic and propionic acids was found to increase with the concentration of TOPO when the concentra...

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প্রধান লেখক: 333347 Lau, Isaac, Hayward, Gordon
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author 333347 Lau, Isaac
Hayward, Gordon
author_facet 333347 Lau, Isaac
Hayward, Gordon
author_sort 333347 Lau, Isaac
collection OCEAN
description The use of silicone rubber tubes swollen with solutions of TOPO (trioctyl phospine oxide) in kerosene as membranes for the recovery of fatty acids from anaerobic digesters was investigated. The flux of acetic and propionic acids was found to increase with the concentration of TOPO when the concentrationwas low. At very high TOPO concentration, the flux decreased indicating the existance of an optimum TOPO concentration. The relationship between the flux and concentration of unionized propionic acid did not agree with that expected for pure diffusion. This was due to the reversible reaction between TOPO and propionic acid in the membrane. The flux of propionic acid was measured as a function of time for new membranes and for membranes removed from storage. Rather long times, 70 to 300 hours, were required to achieve steady acid fluxes. This time was required to fully developed the concentration profiles within the membranes.
first_indexed 2024-03-05T07:38:45Z
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id KOHA-OAI-TEST:382970
institution Universiti Teknologi Malaysia - OCEAN
last_indexed 2024-03-05T07:38:45Z
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spelling KOHA-OAI-TEST:3829702020-12-19T17:13:21ZRecovery of fatty acids by immobilized solvent extraction / 333347 Lau, Isaac Hayward, Gordon The use of silicone rubber tubes swollen with solutions of TOPO (trioctyl phospine oxide) in kerosene as membranes for the recovery of fatty acids from anaerobic digesters was investigated. The flux of acetic and propionic acids was found to increase with the concentration of TOPO when the concentrationwas low. At very high TOPO concentration, the flux decreased indicating the existance of an optimum TOPO concentration. The relationship between the flux and concentration of unionized propionic acid did not agree with that expected for pure diffusion. This was due to the reversible reaction between TOPO and propionic acid in the membrane. The flux of propionic acid was measured as a function of time for new membranes and for membranes removed from storage. Rather long times, 70 to 300 hours, were required to achieve steady acid fluxes. This time was required to fully developed the concentration profiles within the membranes.The use of silicone rubber tubes swollen with solutions of TOPO (trioctyl phospine oxide) in kerosene as membranes for the recovery of fatty acids from anaerobic digesters was investigated. The flux of acetic and propionic acids was found to increase with the concentration of TOPO when the concentrationwas low. At very high TOPO concentration, the flux decreased indicating the existance of an optimum TOPO concentration. The relationship between the flux and concentration of unionized propionic acid did not agree with that expected for pure diffusion. This was due to the reversible reaction between TOPO and propionic acid in the membrane. The flux of propionic acid was measured as a function of time for new membranes and for membranes removed from storage. Rather long times, 70 to 300 hours, were required to achieve steady acid fluxes. This time was required to fully developed the concentration profiles within the membranes.47PSZJBLFatty acidsMembrane separation
spellingShingle Fatty acids
Membrane separation
333347 Lau, Isaac
Hayward, Gordon
Recovery of fatty acids by immobilized solvent extraction /
title Recovery of fatty acids by immobilized solvent extraction /
title_full Recovery of fatty acids by immobilized solvent extraction /
title_fullStr Recovery of fatty acids by immobilized solvent extraction /
title_full_unstemmed Recovery of fatty acids by immobilized solvent extraction /
title_short Recovery of fatty acids by immobilized solvent extraction /
title_sort recovery of fatty acids by immobilized solvent extraction
topic Fatty acids
Membrane separation
work_keys_str_mv AT 333347lauisaac recoveryoffattyacidsbyimmobilizedsolventextraction
AT haywardgordon recoveryoffattyacidsbyimmobilizedsolventextraction