Physico-chemical principles governing the ageing of elastomers under the action of atmospheric ozone /

Complex process of ozone degradation of elastomers have been considered as phisico-chemical system. It was shown that reaction of ozone with double bonds in macromolecules was a limiting stage of process. Sensitive methods studying of cracks formation and growth were used in combination with ozone a...

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Main Authors: 355456 Razumovsky, S. D., Podmasteryev, V. V., Zaikov, G. E.
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Summary:Complex process of ozone degradation of elastomers have been considered as phisico-chemical system. It was shown that reaction of ozone with double bonds in macromolecules was a limiting stage of process. Sensitive methods studying of cracks formation and growth were used in combination with ozone absorption control. It was given basic dependences of cracks growth and stress relaxation upon time and ozone concentration.