The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils

Among the compounds implicated as Environmental Endocrine Disruptors (EEDs), the most potent to alter the normal functions of the endocrine systems of organisms and humans are the natural and synthetic oestrogen. They are hydrophobic and ubiquitous and remain in the final effluents for the vast majo...

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Main Authors: Edriyana, Abd Aziz, W. A., Wan Omar, Aznilnda, Zainodin, Islam, Mir Sujaul
Format: Article
Language:English
Published: IACSIT Press 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/11133/1/The%20Role%20of%20Organic%20Carbon%20in%20Natural%20and%20Synthetic%20Oestrogens%20Sorption%20onto%20Soils.pdf
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author Edriyana, Abd Aziz
W. A., Wan Omar
Aznilnda, Zainodin
Islam, Mir Sujaul
author_facet Edriyana, Abd Aziz
W. A., Wan Omar
Aznilnda, Zainodin
Islam, Mir Sujaul
author_sort Edriyana, Abd Aziz
collection UMP
description Among the compounds implicated as Environmental Endocrine Disruptors (EEDs), the most potent to alter the normal functions of the endocrine systems of organisms and humans are the natural and synthetic oestrogen. They are hydrophobic and ubiquitous and remain in the final effluents for the vast majority of sewage treatment plant. Land application of animal manures and sewage sludge as fertilizers has been reported to increase the amount of hormones in soil. However, the information on the factor that influences the occurrence of these compounds in this environmental compartment is limited. This study investigates the sorption affinity of these oestrogens on soils by determining its soil-water partition coefficient (Kd), sorption coefficient normalised to organic carbon (Koc) and octanol-water partition coefficient (Kow). In this study, different percentage of organic carbon was used. The results obtained shows that the Kow is a good predictor of sorption among contaminants as the affinity of oestrogens in soils is strongly dependent to their Kow values. This study also shows that the solid-water partition coefficient (Kd) of all oestrogens have good correlation to the organic carbon content. The calculated sorption coefficient normalised to organic carbon (Koc) indicate a strong association of all oestrogens with organic carbon. Therefore it is concluded that the organic carbon is pertinent to the sorption of oestrogens in soils.
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spelling UMPir111332018-09-28T02:20:05Z http://umpir.ump.edu.my/id/eprint/11133/ The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils Edriyana, Abd Aziz W. A., Wan Omar Aznilnda, Zainodin Islam, Mir Sujaul TA Engineering (General). Civil engineering (General) Among the compounds implicated as Environmental Endocrine Disruptors (EEDs), the most potent to alter the normal functions of the endocrine systems of organisms and humans are the natural and synthetic oestrogen. They are hydrophobic and ubiquitous and remain in the final effluents for the vast majority of sewage treatment plant. Land application of animal manures and sewage sludge as fertilizers has been reported to increase the amount of hormones in soil. However, the information on the factor that influences the occurrence of these compounds in this environmental compartment is limited. This study investigates the sorption affinity of these oestrogens on soils by determining its soil-water partition coefficient (Kd), sorption coefficient normalised to organic carbon (Koc) and octanol-water partition coefficient (Kow). In this study, different percentage of organic carbon was used. The results obtained shows that the Kow is a good predictor of sorption among contaminants as the affinity of oestrogens in soils is strongly dependent to their Kow values. This study also shows that the solid-water partition coefficient (Kd) of all oestrogens have good correlation to the organic carbon content. The calculated sorption coefficient normalised to organic carbon (Koc) indicate a strong association of all oestrogens with organic carbon. Therefore it is concluded that the organic carbon is pertinent to the sorption of oestrogens in soils. IACSIT Press 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11133/1/The%20Role%20of%20Organic%20Carbon%20in%20Natural%20and%20Synthetic%20Oestrogens%20Sorption%20onto%20Soils.pdf Edriyana, Abd Aziz and W. A., Wan Omar and Aznilnda, Zainodin and Islam, Mir Sujaul (2016) The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils. International Journal of Environmental Science and Development, 7 (7). pp. 520-524. ISSN 2010-0264. (Published) http://www.ijesd.org/vol7/832-ES005.pdf doi: 10.18178/ijesd.2016.7.7.832
spellingShingle TA Engineering (General). Civil engineering (General)
Edriyana, Abd Aziz
W. A., Wan Omar
Aznilnda, Zainodin
Islam, Mir Sujaul
The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils
title The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils
title_full The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils
title_fullStr The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils
title_full_unstemmed The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils
title_short The Role of Organic Carbon in Natural and Synthetic Oestrogens Sorption onto Soils
title_sort role of organic carbon in natural and synthetic oestrogens sorption onto soils
topic TA Engineering (General). Civil engineering (General)
url http://umpir.ump.edu.my/id/eprint/11133/1/The%20Role%20of%20Organic%20Carbon%20in%20Natural%20and%20Synthetic%20Oestrogens%20Sorption%20onto%20Soils.pdf
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