CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading
CO2 reforming of CH4 has recently attracted considerable attention due to the simultaneous utilization and reduction of two greenhouse gases, into the synthesis gas (syngas) with low H2/CO ratio than those available industrial processes. CO2 reforming of CH4 has been studied extensively using variet...
| Main Authors: | , , , , , |
|---|---|
| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
2015
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/11907/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15%20catalyst-%20Effect%20of%20Nickel%20Loading.pdf |
| _version_ | 1796991053806436352 |
|---|---|
| author | Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y. |
| author_facet | Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y. |
| author_sort | Setiabudi, H. D. |
| collection | UMP |
| description | CO2 reforming of CH4 has recently attracted considerable attention due to the simultaneous utilization and reduction of two greenhouse gases, into the synthesis gas (syngas) with low H2/CO ratio than those available industrial processes. CO2 reforming of CH4 has been studied extensively using variety of supported metal catalysts. Regarding to the choice of catalyst, Nickel (Ni) supported on mesoporous material shows good catalytic activity and selectivity. This study investigates the effects of Ni loading (0-10 wt%) on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4, owing to the fact that metal has a significant influence on the properties and catalytic performance of the catalyst. Characterization using XRD, BET, FTIR and TG/DTA revealed that the amount of Ni content plays an important role in controlling the properties and catalytic performance of Ni/SBA-15. The activity of CO2 reforming of CH4 followed the order of 5wt%Ni/SBA-15 > 10wt%Ni/SBA-15 > 3wt%Ni/SBA-15 > SBA-15. The superior catalytic behaviour of 5wt%Ni/SBA-15 towards CO2 reforming of CH4 was related with the interaction of Ni with SBA-15, which altered the properties of catalyst towards an excellent catalytic performance.
The conversion of CH4 and CO2 over 5wt%Ni/SBA-15 was about 88.2% and 91.4%, respectively with CO2/CH4 ratio of 1. This study provides new perspectives on the Ni-based catalyst, particularly on the effects of Ni on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4.
|
| first_indexed | 2024-03-06T12:00:37Z |
| format | Conference or Workshop Item |
| id | UMPir11907 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:00:37Z |
| publishDate | 2015 |
| record_format | dspace |
| spelling | UMPir119072018-05-22T01:27:50Z http://umpir.ump.edu.my/id/eprint/11907/ CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y. TP Chemical technology CO2 reforming of CH4 has recently attracted considerable attention due to the simultaneous utilization and reduction of two greenhouse gases, into the synthesis gas (syngas) with low H2/CO ratio than those available industrial processes. CO2 reforming of CH4 has been studied extensively using variety of supported metal catalysts. Regarding to the choice of catalyst, Nickel (Ni) supported on mesoporous material shows good catalytic activity and selectivity. This study investigates the effects of Ni loading (0-10 wt%) on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4, owing to the fact that metal has a significant influence on the properties and catalytic performance of the catalyst. Characterization using XRD, BET, FTIR and TG/DTA revealed that the amount of Ni content plays an important role in controlling the properties and catalytic performance of Ni/SBA-15. The activity of CO2 reforming of CH4 followed the order of 5wt%Ni/SBA-15 > 10wt%Ni/SBA-15 > 3wt%Ni/SBA-15 > SBA-15. The superior catalytic behaviour of 5wt%Ni/SBA-15 towards CO2 reforming of CH4 was related with the interaction of Ni with SBA-15, which altered the properties of catalyst towards an excellent catalytic performance. The conversion of CH4 and CO2 over 5wt%Ni/SBA-15 was about 88.2% and 91.4%, respectively with CO2/CH4 ratio of 1. This study provides new perspectives on the Ni-based catalyst, particularly on the effects of Ni on the properties and catalytic performance of Ni/SBA-15 towards CO2 reforming of CH4. 2015 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11907/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15%20catalyst-%20Effect%20of%20Nickel%20Loading.pdf Setiabudi, H. D. and Nurul, Ainirazali and S. F. R. M., Suhaimi and Fatin Nadia, Pauzi and K. H., Lim and Chin, S. Y. (2015) CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading. In: 4th Conference on Emerging Energy and Process Technology (CONCEPT2015) , 15-16 December 2015 , Melaka. p. 1.. (Unpublished) |
| spellingShingle | TP Chemical technology Setiabudi, H. D. Nurul, Ainirazali S. F. R. M., Suhaimi Fatin Nadia, Pauzi K. H., Lim Chin, S. Y. CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading |
| title | CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading |
| title_full | CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading |
| title_fullStr | CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading |
| title_full_unstemmed | CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading |
| title_short | CO2 reforming of CH4 over Ni/SBA-15 catalyst: Effect of Nickel Loading |
| title_sort | co2 reforming of ch4 over ni sba 15 catalyst effect of nickel loading |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/11907/1/CO2%20reforming%20of%20CH4%20over%20Ni-SBA-15%20catalyst-%20Effect%20of%20Nickel%20Loading.pdf |
| work_keys_str_mv | AT setiabudihd co2reformingofch4overnisba15catalysteffectofnickelloading AT nurulainirazali co2reformingofch4overnisba15catalysteffectofnickelloading AT sfrmsuhaimi co2reformingofch4overnisba15catalysteffectofnickelloading AT fatinnadiapauzi co2reformingofch4overnisba15catalysteffectofnickelloading AT khlim co2reformingofch4overnisba15catalysteffectofnickelloading AT chinsy co2reformingofch4overnisba15catalysteffectofnickelloading |