In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement

A fast and facile approach is proposed to enhance the specific capacitance of N-Methyl-2-pyrrolidone (NMP)–exfoliated graphene. Redox–active nickel ferricyanide (NiFeCN) nanoparticles were grown on the surface of graphene sheets using a simple co–precipitation method. Apart from the synergetic effec...

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Main Authors: Puteri, Emme Marina, Ali, Gomaa A. M., Li, Min See, Ellie Teo, Yi Lih, Eng, Poh Ng, K. F., Chong
Format: Article
Language:English
Published: Elsevier Ltd 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/11985/1/In%20Situ%20Growth%20of%20Redox%E2%80%93Active%20Iron%E2%80%93Centered%20Particles%20On%20Graphene%20Sheets%20for%20Specific%20Capacitance%20Enhancement.pdf
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author Puteri, Emme Marina
Ali, Gomaa A. M.
Li, Min See
Ellie Teo, Yi Lih
Eng, Poh Ng
K. F., Chong
author_facet Puteri, Emme Marina
Ali, Gomaa A. M.
Li, Min See
Ellie Teo, Yi Lih
Eng, Poh Ng
K. F., Chong
author_sort Puteri, Emme Marina
collection UMP
description A fast and facile approach is proposed to enhance the specific capacitance of N-Methyl-2-pyrrolidone (NMP)–exfoliated graphene. Redox–active nickel ferricyanide (NiFeCN) nanoparticles were grown on the surface of graphene sheets using a simple co–precipitation method. Apart from the synergetic effect of graphene as double layer capacitance and NiFeCN as pseudocapacitance in specific capacitance enhancement, the NiFeCN nanoparticles served as the spacer to prevent the graphene sheets agglomeration. The NiFeCN/graphene exhibited specific capacitance of 113.5 F g-1, which was 2 times higher than the NMP–exfoliated graphene (52 F g-1) and 6 times higher than the pure NiFeCN (18 F g-1). The findings suggested the NiFeCN/graphene could be the potential candidate for supercapacitors electrode.
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spelling UMPir119852017-02-13T00:48:36Z http://umpir.ump.edu.my/id/eprint/11985/ In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement Puteri, Emme Marina Ali, Gomaa A. M. Li, Min See Ellie Teo, Yi Lih Eng, Poh Ng K. F., Chong Q Science (General) A fast and facile approach is proposed to enhance the specific capacitance of N-Methyl-2-pyrrolidone (NMP)–exfoliated graphene. Redox–active nickel ferricyanide (NiFeCN) nanoparticles were grown on the surface of graphene sheets using a simple co–precipitation method. Apart from the synergetic effect of graphene as double layer capacitance and NiFeCN as pseudocapacitance in specific capacitance enhancement, the NiFeCN nanoparticles served as the spacer to prevent the graphene sheets agglomeration. The NiFeCN/graphene exhibited specific capacitance of 113.5 F g-1, which was 2 times higher than the NMP–exfoliated graphene (52 F g-1) and 6 times higher than the pure NiFeCN (18 F g-1). The findings suggested the NiFeCN/graphene could be the potential candidate for supercapacitors electrode. Elsevier Ltd 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/11985/1/In%20Situ%20Growth%20of%20Redox%E2%80%93Active%20Iron%E2%80%93Centered%20Particles%20On%20Graphene%20Sheets%20for%20Specific%20Capacitance%20Enhancement.pdf Puteri, Emme Marina and Ali, Gomaa A. M. and Li, Min See and Ellie Teo, Yi Lih and Eng, Poh Ng and K. F., Chong (2016) In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement. Arabian Journal of Chemistry. pp. 1-7. ISSN 1878-5352. (In Press / Online First) (In Press / Online First) http://dx.doi.org/10.1016/j.arabjc.2016.02.006 DOI: 10.1016/j.arabjc.2016.02.006
spellingShingle Q Science (General)
Puteri, Emme Marina
Ali, Gomaa A. M.
Li, Min See
Ellie Teo, Yi Lih
Eng, Poh Ng
K. F., Chong
In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement
title In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement
title_full In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement
title_fullStr In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement
title_full_unstemmed In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement
title_short In Situ Growth of Redox-Active Iron-Centered Particles On Graphene Sheets for Specific Capacitance Enhancement
title_sort in situ growth of redox active iron centered particles on graphene sheets for specific capacitance enhancement
topic Q Science (General)
url http://umpir.ump.edu.my/id/eprint/11985/1/In%20Situ%20Growth%20of%20Redox%E2%80%93Active%20Iron%E2%80%93Centered%20Particles%20On%20Graphene%20Sheets%20for%20Specific%20Capacitance%20Enhancement.pdf
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