Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates
In this study, boiler ash containing potassium silicate (BA 900) and potassium silicate (K2SiO3) were proven to be feasible Lewis acid catalysts for the synthesis of different organic carbonates (glycerol carbonate, ethylene carbonate, and propylene carbonate) from different polyol (glycerol, ethyle...
| Príomhchruthaitheoirí: | , , , , , |
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| Formáid: | Alt |
| Teanga: | English |
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Royal Society of Chemistry
2016
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| Ábhair: | |
| Rochtain ar líne: | http://umpir.ump.edu.my/id/eprint/12963/1/Versatile%20Boiler%20Ash%20Containing%20Potassium%20Silicate%20For%20The%20Synthesis%20Of%20Organic%20Carbonates.pdf |
| _version_ | 1825822894124433408 |
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| author | Vidhyaa, Paroo Indran Anisah Sajidah, Haji Saud Gaanty Pragas, Maniam M. M., Yusoff Yun Hin , Taufiq-Yap Mohd Hasbi, Ab. Rahim |
| author_facet | Vidhyaa, Paroo Indran Anisah Sajidah, Haji Saud Gaanty Pragas, Maniam M. M., Yusoff Yun Hin , Taufiq-Yap Mohd Hasbi, Ab. Rahim |
| author_sort | Vidhyaa, Paroo Indran |
| collection | UMP |
| description | In this study, boiler ash containing potassium silicate (BA 900) and potassium silicate (K2SiO3) were proven to be feasible Lewis acid catalysts for the synthesis of different organic carbonates (glycerol carbonate, ethylene carbonate, and propylene carbonate) from different polyol (glycerol, ethylene glycol, and propylene glycol) feedstocks. In addition, the developed catalytic reaction has the ability to produce propylene carbonate at milder reaction temperatures. BA 900 and K2SiO3 were reusable for three consecutive reaction cycles without the loss of activity. The reusable characteristics of catalysts were confirmed through several characterisation techniques, i.e. XRD, FTIR, XRF, N2 physisorption, FESEM-EDX, and Hammett test. All organic carbonates synthesised had a similar synthetic mechanistic pathway, which involved decomposition of intermediate carbamates into their
respective carbonates.
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| first_indexed | 2024-03-06T12:03:19Z |
| format | Article |
| id | UMPir12963 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:03:19Z |
| publishDate | 2016 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | UMPir129632020-02-28T03:45:51Z http://umpir.ump.edu.my/id/eprint/12963/ Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates Vidhyaa, Paroo Indran Anisah Sajidah, Haji Saud Gaanty Pragas, Maniam M. M., Yusoff Yun Hin , Taufiq-Yap Mohd Hasbi, Ab. Rahim Q Science (General) In this study, boiler ash containing potassium silicate (BA 900) and potassium silicate (K2SiO3) were proven to be feasible Lewis acid catalysts for the synthesis of different organic carbonates (glycerol carbonate, ethylene carbonate, and propylene carbonate) from different polyol (glycerol, ethylene glycol, and propylene glycol) feedstocks. In addition, the developed catalytic reaction has the ability to produce propylene carbonate at milder reaction temperatures. BA 900 and K2SiO3 were reusable for three consecutive reaction cycles without the loss of activity. The reusable characteristics of catalysts were confirmed through several characterisation techniques, i.e. XRD, FTIR, XRF, N2 physisorption, FESEM-EDX, and Hammett test. All organic carbonates synthesised had a similar synthetic mechanistic pathway, which involved decomposition of intermediate carbamates into their respective carbonates. Royal Society of Chemistry 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/12963/1/Versatile%20Boiler%20Ash%20Containing%20Potassium%20Silicate%20For%20The%20Synthesis%20Of%20Organic%20Carbonates.pdf Vidhyaa, Paroo Indran and Anisah Sajidah, Haji Saud and Gaanty Pragas, Maniam and M. M., Yusoff and Yun Hin , Taufiq-Yap and Mohd Hasbi, Ab. Rahim (2016) Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates. RSC Advances, 6 (41). pp. 34877-34884. ISSN 2046-2069. (Published) http://dx.doi.org/10.1039/C5RA26286K DOI: 10.1039/C5RA26286K |
| spellingShingle | Q Science (General) Vidhyaa, Paroo Indran Anisah Sajidah, Haji Saud Gaanty Pragas, Maniam M. M., Yusoff Yun Hin , Taufiq-Yap Mohd Hasbi, Ab. Rahim Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates |
| title | Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates |
| title_full | Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates |
| title_fullStr | Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates |
| title_full_unstemmed | Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates |
| title_short | Versatile Boiler Ash Containing Potassium Silicate for the Synthesis of Organic Carbonates |
| title_sort | versatile boiler ash containing potassium silicate for the synthesis of organic carbonates |
| topic | Q Science (General) |
| url | http://umpir.ump.edu.my/id/eprint/12963/1/Versatile%20Boiler%20Ash%20Containing%20Potassium%20Silicate%20For%20The%20Synthesis%20Of%20Organic%20Carbonates.pdf |
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