Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon

Microwave pyrolysis using a well-mixed bed of activated carbon as both the microwave absorber and reaction bed was investigated for its potential to recover useful products from waste palm cooking oil - a cooking oil widely used in Asia. The carbon bed provided rapid heating (~18 C/min) and a locali...

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Main Authors: Su, Shiung Lam, Wan Adibah, Wan Mahari, Cheng, C. K., Rozita, Omar, Cheng, Tung Chong, Chase, Howard A.
Format: Article
Language:English
Published: Elsevier 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/14446/1/fkksa-2016-ckcheng-Recovery%20of%20diesel-like%20fuel11.pdf
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author Su, Shiung Lam
Wan Adibah, Wan Mahari
Cheng, C. K.
Rozita, Omar
Cheng, Tung Chong
Chase, Howard A.
author_facet Su, Shiung Lam
Wan Adibah, Wan Mahari
Cheng, C. K.
Rozita, Omar
Cheng, Tung Chong
Chase, Howard A.
author_sort Su, Shiung Lam
collection UMP
description Microwave pyrolysis using a well-mixed bed of activated carbon as both the microwave absorber and reaction bed was investigated for its potential to recover useful products from waste palm cooking oil - a cooking oil widely used in Asia. The carbon bed provided rapid heating (~18 C/min) and a localized reaction hot zone that thermally promoted extensive pyrolysis cracking of the waste oil at 450 C, leading to increased production of a biofuel product in a process taking less than 25 min. It also created areducing reaction environment that prevented the formation of undesirable oxidized compounds in the biofuel. The pyrolysis produced a biofuel product that is low in oxygen, free of sulphur, carboxylic acid and triglycerides, and which also contains light C10-C15 hydrocarbons and a high calorific value nearly comparable to diesel fuel, thus showing great potential to be used as fuel. This pyrolysis approach offers an attractive alternative to transesterification that avoids the use of solvents and catalysts, and the need to remove free fatty acids and glycerol from the hydrocarbon product. The pyrolysis apparatus operated with an electrical power input of 1.12 kW was capable of producing a biofuel with an energy content equivalent to about 3 kW, showing a positive energy ratio of 2.7 and 73% recovery of the energy input to the system. The results show that the pyrolysis approach has huge potential as a technically and energetically viable means for the recovery of biofuels from the waste oil.
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spelling UMPir144462017-08-09T08:11:11Z http://umpir.ump.edu.my/id/eprint/14446/ Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon Su, Shiung Lam Wan Adibah, Wan Mahari Cheng, C. K. Rozita, Omar Cheng, Tung Chong Chase, Howard A. TP Chemical technology Microwave pyrolysis using a well-mixed bed of activated carbon as both the microwave absorber and reaction bed was investigated for its potential to recover useful products from waste palm cooking oil - a cooking oil widely used in Asia. The carbon bed provided rapid heating (~18 C/min) and a localized reaction hot zone that thermally promoted extensive pyrolysis cracking of the waste oil at 450 C, leading to increased production of a biofuel product in a process taking less than 25 min. It also created areducing reaction environment that prevented the formation of undesirable oxidized compounds in the biofuel. The pyrolysis produced a biofuel product that is low in oxygen, free of sulphur, carboxylic acid and triglycerides, and which also contains light C10-C15 hydrocarbons and a high calorific value nearly comparable to diesel fuel, thus showing great potential to be used as fuel. This pyrolysis approach offers an attractive alternative to transesterification that avoids the use of solvents and catalysts, and the need to remove free fatty acids and glycerol from the hydrocarbon product. The pyrolysis apparatus operated with an electrical power input of 1.12 kW was capable of producing a biofuel with an energy content equivalent to about 3 kW, showing a positive energy ratio of 2.7 and 73% recovery of the energy input to the system. The results show that the pyrolysis approach has huge potential as a technically and energetically viable means for the recovery of biofuels from the waste oil. Elsevier 2016-09-11 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/14446/1/fkksa-2016-ckcheng-Recovery%20of%20diesel-like%20fuel11.pdf Su, Shiung Lam and Wan Adibah, Wan Mahari and Cheng, C. K. and Rozita, Omar and Cheng, Tung Chong and Chase, Howard A. (2016) Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon. Energy, 115. pp. 791-799. ISSN 0360-5442 (Print), 1873-6785 (Online). (Published) http://dx.doi.org/10.1016/j.energy.2016.09.076 doi: 10.1016/j.energy.2016.09.076
spellingShingle TP Chemical technology
Su, Shiung Lam
Wan Adibah, Wan Mahari
Cheng, C. K.
Rozita, Omar
Cheng, Tung Chong
Chase, Howard A.
Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon
title Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon
title_full Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon
title_fullStr Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon
title_full_unstemmed Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon
title_short Recovery of Diesel-Like Fuel from Waste Palm Oil by Pyrolysis using a Microwave Heated Bed of Activated Carbon
title_sort recovery of diesel like fuel from waste palm oil by pyrolysis using a microwave heated bed of activated carbon
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/14446/1/fkksa-2016-ckcheng-Recovery%20of%20diesel-like%20fuel11.pdf
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