Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite

The modification of pristine nanoclay and its application in wood plastic composite (WPC) have been investigated in this paper. Pristine nanoclay was modified using transition metal ion (TMI) which was copper (II) chloride to achieve good dispersion and to improve properties of WPC. The morphology,...

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Main Authors: Yadav, Sumit Manohar, Kamal, Yusoh
Format: Article
Language:English
Published: De Gruyter 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/14762/1/fkksa-2016-sumit-Modification%20of%20pristine%20nanoclay%20and%20its%20application.pdf
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author Yadav, Sumit Manohar
Kamal, Yusoh
author_facet Yadav, Sumit Manohar
Kamal, Yusoh
author_sort Yadav, Sumit Manohar
collection UMP
description The modification of pristine nanoclay and its application in wood plastic composite (WPC) have been investigated in this paper. Pristine nanoclay was modified using transition metal ion (TMI) which was copper (II) chloride to achieve good dispersion and to improve properties of WPC. The morphology, composition, structure, and thermal stability of TMI-modified nanoclay were studied by field emission scanning electron microscopy (FESEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) and thermogravimetric analysis (TGA) analysis. The pristine (WPC/MMT) and TMI-modified (WPC/MMT Cu) nanoclay based WPC were made from polypropylene (PP), wood flour (WF), and maleic anhydride grafted polypropylene (MAPP) coupling agent. Pristine and modified nanoclay with different concentration (1 wt%, 2.5 wt%, 4 wt% and 5 wt%) were used as a reinforcing filler for WPC. Mechanical, physical, morphological, and thermal properties of the prepared composites were evaluated. Result exhibit that at 1 wt% nanoclay content, the tensile, flexural, and impact strength of WPC/MMT improved by approximately 6%, 4%, and 8%, respectively, compared to WPC without nanoclay. For the WPC/MMT Cu, the improvements in these properties were about 2.6, 2.1 and 3 times higher than the WPC/MMT. The physical and thermal properties also improved by incorporating modified nanoclay in WPC.
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spelling UMPir147622017-12-13T08:35:06Z http://umpir.ump.edu.my/id/eprint/14762/ Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite Yadav, Sumit Manohar Kamal, Yusoh TP Chemical technology The modification of pristine nanoclay and its application in wood plastic composite (WPC) have been investigated in this paper. Pristine nanoclay was modified using transition metal ion (TMI) which was copper (II) chloride to achieve good dispersion and to improve properties of WPC. The morphology, composition, structure, and thermal stability of TMI-modified nanoclay were studied by field emission scanning electron microscopy (FESEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD) and thermogravimetric analysis (TGA) analysis. The pristine (WPC/MMT) and TMI-modified (WPC/MMT Cu) nanoclay based WPC were made from polypropylene (PP), wood flour (WF), and maleic anhydride grafted polypropylene (MAPP) coupling agent. Pristine and modified nanoclay with different concentration (1 wt%, 2.5 wt%, 4 wt% and 5 wt%) were used as a reinforcing filler for WPC. Mechanical, physical, morphological, and thermal properties of the prepared composites were evaluated. Result exhibit that at 1 wt% nanoclay content, the tensile, flexural, and impact strength of WPC/MMT improved by approximately 6%, 4%, and 8%, respectively, compared to WPC without nanoclay. For the WPC/MMT Cu, the improvements in these properties were about 2.6, 2.1 and 3 times higher than the WPC/MMT. The physical and thermal properties also improved by incorporating modified nanoclay in WPC. De Gruyter 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/14762/1/fkksa-2016-sumit-Modification%20of%20pristine%20nanoclay%20and%20its%20application.pdf Yadav, Sumit Manohar and Kamal, Yusoh (2016) Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite. e-Polymers, 16 (6). pp. 447-461. ISSN 2197-4586 (Print); 1618-7229 (Online). (Published) http://dx.doi.org/10.1515/epoly-2016-0217 DOI: 10.1515/epoly-2016-0217
spellingShingle TP Chemical technology
Yadav, Sumit Manohar
Kamal, Yusoh
Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite
title Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite
title_full Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite
title_fullStr Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite
title_full_unstemmed Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite
title_short Modification of Pristine Nanoclay and its Application in Wood-Plastic Composite
title_sort modification of pristine nanoclay and its application in wood plastic composite
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/14762/1/fkksa-2016-sumit-Modification%20of%20pristine%20nanoclay%20and%20its%20application.pdf
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