Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)

The tremendous fuel ashes are deserted by palm oil industries into environment were not processed for commercializable products such as zeolites, etc. There are a few methods for zeolites synthesis, such as molten-salt, sol-gel, etc., but it takes considerable time, extensive set up and needs to hig...

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Main Authors: Said, N., R. M., Yunus, Abdul Aziz, Mohd Azoddein, Syafiqah , A. Khairuddin, Hajar Athirah, M. Sukri, Chuah, C. Wooi
Format: Conference or Workshop Item
Language:English
Published: Knowledge Transfer Centre, USM 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/14845/1/Paper%2033%20I-GT-058-Said%20Nurdin-UMP.pdf
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author Said, N.
R. M., Yunus
Abdul Aziz, Mohd Azoddein
Syafiqah , A. Khairuddin
Hajar Athirah, M. Sukri
Chuah, C. Wooi
author_facet Said, N.
R. M., Yunus
Abdul Aziz, Mohd Azoddein
Syafiqah , A. Khairuddin
Hajar Athirah, M. Sukri
Chuah, C. Wooi
author_sort Said, N.
collection UMP
description The tremendous fuel ashes are deserted by palm oil industries into environment were not processed for commercializable products such as zeolites, etc. There are a few methods for zeolites synthesis, such as molten-salt, sol-gel, etc., but it takes considerable time, extensive set up and needs to high cost, thus this work aims to solve this issues by knowledge transfer of hydrothermal-alkaline-ultrasound technique (HAUT) for palm oil mill fuel ash (POMFA) based zeolites synthesis as sustainability and green material processing technology initiatives. The knowledge transfer methods of the POMFA characterization and analysis procedure completed via talks, workshop, practical, exercise and data analysis. The analysis of POMFA using Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Fourier Transformed Infra Red (FTIR), and X-Ray Flourescent (XRF) for composition approval has been conducted. The XRF result reveals 37.92 % silicon dioxide and 3.42% aluminium oxide etc. as major components typically used in the manufactures of zeolites. Next, the green technology transfer for zeolites synthesis from POMFA via HAUT utilization, process parameter effect, analysis equipments and operational procedure has been achieved. The highest Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) using HAUT was found at the operation condition of POMFA-akaline ratio of 1:2, ultrasonic exposure time of 2.5 h, medium temperature of 80°C, irradiation power of 800 W and frequency of 45 kHz. The synthesized G-POMFAZ can be considered as an alternative material for industrial application, like construction, petrochemical, etc. The knowledge transfer program via training and dissemination of morphology analysis of G-POMFAZ was directed to the company staff. The staff knowledge is drastically increased on the POMFA characterization and zeolites synthesis. The project contributes also to the reduction of the CH Biotech-wastes and contaminated particulate matter gradually.
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spelling UMPir148452017-12-15T06:55:33Z http://umpir.ump.edu.my/id/eprint/14845/ Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT) Said, N. R. M., Yunus Abdul Aziz, Mohd Azoddein Syafiqah , A. Khairuddin Hajar Athirah, M. Sukri Chuah, C. Wooi TP Chemical technology The tremendous fuel ashes are deserted by palm oil industries into environment were not processed for commercializable products such as zeolites, etc. There are a few methods for zeolites synthesis, such as molten-salt, sol-gel, etc., but it takes considerable time, extensive set up and needs to high cost, thus this work aims to solve this issues by knowledge transfer of hydrothermal-alkaline-ultrasound technique (HAUT) for palm oil mill fuel ash (POMFA) based zeolites synthesis as sustainability and green material processing technology initiatives. The knowledge transfer methods of the POMFA characterization and analysis procedure completed via talks, workshop, practical, exercise and data analysis. The analysis of POMFA using Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Fourier Transformed Infra Red (FTIR), and X-Ray Flourescent (XRF) for composition approval has been conducted. The XRF result reveals 37.92 % silicon dioxide and 3.42% aluminium oxide etc. as major components typically used in the manufactures of zeolites. Next, the green technology transfer for zeolites synthesis from POMFA via HAUT utilization, process parameter effect, analysis equipments and operational procedure has been achieved. The highest Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) using HAUT was found at the operation condition of POMFA-akaline ratio of 1:2, ultrasonic exposure time of 2.5 h, medium temperature of 80°C, irradiation power of 800 W and frequency of 45 kHz. The synthesized G-POMFAZ can be considered as an alternative material for industrial application, like construction, petrochemical, etc. The knowledge transfer program via training and dissemination of morphology analysis of G-POMFAZ was directed to the company staff. The staff knowledge is drastically increased on the POMFA characterization and zeolites synthesis. The project contributes also to the reduction of the CH Biotech-wastes and contaminated particulate matter gradually. Knowledge Transfer Centre, USM 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/14845/1/Paper%2033%20I-GT-058-Said%20Nurdin-UMP.pdf Said, N. and R. M., Yunus and Abdul Aziz, Mohd Azoddein and Syafiqah , A. Khairuddin and Hajar Athirah, M. Sukri and Chuah, C. Wooi (2016) Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT). In: Proceedings of International Conference on Knowledge Transfer (ICKT'15) , 1-3 December 2015 , Putrajaya Marriott Hotel, Malaysia. pp. 198-205.. ISBN 978-967-394-255-8 (Published) https://drive.google.com/file/d/0ByBlFVsjNeg5ZERwSFNYUGFmVWs/view
spellingShingle TP Chemical technology
Said, N.
R. M., Yunus
Abdul Aziz, Mohd Azoddein
Syafiqah , A. Khairuddin
Hajar Athirah, M. Sukri
Chuah, C. Wooi
Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)
title Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)
title_full Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)
title_fullStr Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)
title_full_unstemmed Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)
title_short Synthesis of Green Palm Oil Mill Fuel Ash Zeolites (G-POMFAZ) Using Hydrothermal-Alkaline-Ultrasound Technique (HAUT)
title_sort synthesis of green palm oil mill fuel ash zeolites g pomfaz using hydrothermal alkaline ultrasound technique haut
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/14845/1/Paper%2033%20I-GT-058-Said%20Nurdin-UMP.pdf
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