Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)

Wood and plants are cellular hierarchical bio-composites produced by nature, and are essentially semicrystalline cellulose microfibrilreinforced amorphous matrices made of hemicellulose, lignin, waxes, extractive and trace elements. Cellulose acts as a structural reinforcing agent that provides mec...

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Main Authors: Poddar, Pradeep Kumar, Gupta, Arun, Saidatul Shima, Jamari, Rashid, Shah Samiur, Sharma, Swati, Malini, Subramaniam, Jayshree, Thraisingam
Format: Conference or Workshop Item
Language:English
Published: Universiti Malaysia Pahang 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/15772/1/P095%20pg704-711.pdf
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author Poddar, Pradeep Kumar
Gupta, Arun
Saidatul Shima, Jamari
Rashid, Shah Samiur
Sharma, Swati
Malini, Subramaniam
Jayshree, Thraisingam
author_facet Poddar, Pradeep Kumar
Gupta, Arun
Saidatul Shima, Jamari
Rashid, Shah Samiur
Sharma, Swati
Malini, Subramaniam
Jayshree, Thraisingam
author_sort Poddar, Pradeep Kumar
collection UMP
description Wood and plants are cellular hierarchical bio-composites produced by nature, and are essentially semicrystalline cellulose microfibrilreinforced amorphous matrices made of hemicellulose, lignin, waxes, extractive and trace elements. Cellulose acts as a structural reinforcing agent that provides mechanical strength as well as chemical stability to plants. The development of low-cost, sustainable and renewable resources is critical to meet the growing environmental concerns and energy demands; the use of rubber wood is extremely beneficial to Malaysia as it is one of the main commodities. The current study aims to extract cellulose nanofibres from rubber wood (Heveabrasiliensis) fibers via high pressure homogenisation combined with enzymatic and chemical pretreatments. In this study the application of enzymes in fiber processing has been mainly directed towards the modification of hemicelluloses and lignin while preserving the cellulosic fraction .The diameter distributions of the resulting nanofibers were dependent on the number of times of cellulose solution is passing. The extent of dispersion improved significantly with increasing when number of passes through the high pressure homogenised. Fe-SEM study showed that the diameters of the nanofibersisolated ranged from 37 to 85 nanometer(nm) and estimated length is several micrometers (µm). The nanocellulosefibres were studied further by examining with Fourier Transform Infrared Spectroscopy (FTIR). There was a disappearance of vibration peaks at 1730.28 and 1234 cm-1 from spectra of treated fibres which shows the removal of hemicellulose and lignin components respectively. XRD results showed an increase in crystalline which resulted from the removal of lignin and hemicellulose. Moreover, the isolated cellulose nanofibres were used to reinforce poly(ethylene oxide) (PEO). PEO was dissolved in isolated nanocellulose liquid suspension followed by casting. The nanocomposites were characterized by using FTIR analysis and X-Ray diffractometry.
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spelling UMPir157722019-08-28T07:25:30Z http://umpir.ump.edu.my/id/eprint/15772/ Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide) Poddar, Pradeep Kumar Gupta, Arun Saidatul Shima, Jamari Rashid, Shah Samiur Sharma, Swati Malini, Subramaniam Jayshree, Thraisingam QD Chemistry Wood and plants are cellular hierarchical bio-composites produced by nature, and are essentially semicrystalline cellulose microfibrilreinforced amorphous matrices made of hemicellulose, lignin, waxes, extractive and trace elements. Cellulose acts as a structural reinforcing agent that provides mechanical strength as well as chemical stability to plants. The development of low-cost, sustainable and renewable resources is critical to meet the growing environmental concerns and energy demands; the use of rubber wood is extremely beneficial to Malaysia as it is one of the main commodities. The current study aims to extract cellulose nanofibres from rubber wood (Heveabrasiliensis) fibers via high pressure homogenisation combined with enzymatic and chemical pretreatments. In this study the application of enzymes in fiber processing has been mainly directed towards the modification of hemicelluloses and lignin while preserving the cellulosic fraction .The diameter distributions of the resulting nanofibers were dependent on the number of times of cellulose solution is passing. The extent of dispersion improved significantly with increasing when number of passes through the high pressure homogenised. Fe-SEM study showed that the diameters of the nanofibersisolated ranged from 37 to 85 nanometer(nm) and estimated length is several micrometers (µm). The nanocellulosefibres were studied further by examining with Fourier Transform Infrared Spectroscopy (FTIR). There was a disappearance of vibration peaks at 1730.28 and 1234 cm-1 from spectra of treated fibres which shows the removal of hemicellulose and lignin components respectively. XRD results showed an increase in crystalline which resulted from the removal of lignin and hemicellulose. Moreover, the isolated cellulose nanofibres were used to reinforce poly(ethylene oxide) (PEO). PEO was dissolved in isolated nanocellulose liquid suspension followed by casting. The nanocomposites were characterized by using FTIR analysis and X-Ray diffractometry. Universiti Malaysia Pahang 2016 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/15772/1/P095%20pg704-711.pdf Poddar, Pradeep Kumar and Gupta, Arun and Saidatul Shima, Jamari and Rashid, Shah Samiur and Sharma, Swati and Malini, Subramaniam and Jayshree, Thraisingam (2016) Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide). In: Proceedings of The National Conference for Postgraduate Research (NCON-PGR 2016) , 24-25 September 2016 , Universiti Malaysia Pahang (UMP), Pekan, Pahang. pp. 704-711.. http://ee.ump.edu.my/ncon/wp-content/uploads/2016/10/Proceeding-NCON-PGR-2016.zip
spellingShingle QD Chemistry
Poddar, Pradeep Kumar
Gupta, Arun
Saidatul Shima, Jamari
Rashid, Shah Samiur
Sharma, Swati
Malini, Subramaniam
Jayshree, Thraisingam
Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)
title Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)
title_full Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)
title_fullStr Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)
title_full_unstemmed Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)
title_short Isolation of Nano Cellulose from Rubber Wood Fibre and Fibrillation Effects on Nano Cellulose Reinforced Poly (Ethylene Oxide)
title_sort isolation of nano cellulose from rubber wood fibre and fibrillation effects on nano cellulose reinforced poly ethylene oxide
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/15772/1/P095%20pg704-711.pdf
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