Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
The azobenzene based gold nanomaterials was synthesised through Au-S bonding between thiol substituted azobenzene derivatives with gold nanomaterials core. The structures of the compounds were elucidated by nuclear magnetic resonance, IR, transmission electron microscopy and UV-Vis spectroscopic tec...
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Format: | Article |
Language: | English |
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The Institution of Engineering and Technology
2017
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Online Access: | http://umpir.ump.edu.my/id/eprint/16244/1/fist-2017-mashitah-Photo-induced%20characteristics%20of%20azobenzene1.pdf |
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author | Aralapura, Yuvaraj Rajkumar Lutfor, M. R. M. M., Yusoff Kular, Sandeep |
author_facet | Aralapura, Yuvaraj Rajkumar Lutfor, M. R. M. M., Yusoff Kular, Sandeep |
author_sort | Aralapura, Yuvaraj Rajkumar |
collection | UMP |
description | The azobenzene based gold nanomaterials was synthesised through Au-S bonding between thiol substituted azobenzene derivatives with gold nanomaterials core. The structures of the compounds were elucidated by nuclear magnetic resonance, IR, transmission electron microscopy and UV-Vis spectroscopic techniques. The photoisomerisation effect was investigated for the synthesised compounds using the absorption studies. The photosaturation was occurred at ∼24 s and back relaxation was found at ∼315 min. The sterical hindrance developed by the multiple attachments of azobenzene molecules to the central gold nanoparticle core is the reason for the lengthening of photo-switching time duration. This study gives good information about the light induced characters of azobenzene based gold nanoparticles. |
first_indexed | 2024-03-06T12:11:53Z |
format | Article |
id | UMPir16244 |
institution | Universiti Malaysia Pahang |
language | English |
last_indexed | 2024-03-06T12:11:53Z |
publishDate | 2017 |
publisher | The Institution of Engineering and Technology |
record_format | dspace |
spelling | UMPir162442018-02-14T07:09:41Z http://umpir.ump.edu.my/id/eprint/16244/ Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles Aralapura, Yuvaraj Rajkumar Lutfor, M. R. M. M., Yusoff Kular, Sandeep QD Chemistry The azobenzene based gold nanomaterials was synthesised through Au-S bonding between thiol substituted azobenzene derivatives with gold nanomaterials core. The structures of the compounds were elucidated by nuclear magnetic resonance, IR, transmission electron microscopy and UV-Vis spectroscopic techniques. The photoisomerisation effect was investigated for the synthesised compounds using the absorption studies. The photosaturation was occurred at ∼24 s and back relaxation was found at ∼315 min. The sterical hindrance developed by the multiple attachments of azobenzene molecules to the central gold nanoparticle core is the reason for the lengthening of photo-switching time duration. This study gives good information about the light induced characters of azobenzene based gold nanoparticles. The Institution of Engineering and Technology 2017-11-29 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16244/1/fist-2017-mashitah-Photo-induced%20characteristics%20of%20azobenzene1.pdf Aralapura, Yuvaraj Rajkumar and Lutfor, M. R. and M. M., Yusoff and Kular, Sandeep (2017) Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles. IET Micro & Nano Letters, 12 (3). pp. 201-204. ISSN 1750-0443. (Published) http://dx.doi.org/10.1049/mnl.2016.0507 doi: 10.1049/mnl.2016.0507 |
spellingShingle | QD Chemistry Aralapura, Yuvaraj Rajkumar Lutfor, M. R. M. M., Yusoff Kular, Sandeep Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles |
title | Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles |
title_full | Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles |
title_fullStr | Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles |
title_full_unstemmed | Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles |
title_short | Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles |
title_sort | photo induced characteristics of azobenzene based gold nanoparticles |
topic | QD Chemistry |
url | http://umpir.ump.edu.my/id/eprint/16244/1/fist-2017-mashitah-Photo-induced%20characteristics%20of%20azobenzene1.pdf |
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