Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles

The azobenzene based gold nanomaterials was synthesised through Au-S bonding between thiol substituted azobenzene derivatives with gold nanomaterials core. The structures of the compounds were elucidated by nuclear magnetic resonance, IR, transmission electron microscopy and UV-Vis spectroscopic tec...

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Main Authors: Aralapura, Yuvaraj Rajkumar, Lutfor, M. R., M. M., Yusoff, Kular, Sandeep
Format: Article
Language:English
Published: The Institution of Engineering and Technology 2017
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/16244/1/fist-2017-mashitah-Photo-induced%20characteristics%20of%20azobenzene1.pdf
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author Aralapura, Yuvaraj Rajkumar
Lutfor, M. R.
M. M., Yusoff
Kular, Sandeep
author_facet Aralapura, Yuvaraj Rajkumar
Lutfor, M. R.
M. M., Yusoff
Kular, Sandeep
author_sort Aralapura, Yuvaraj Rajkumar
collection UMP
description The azobenzene based gold nanomaterials was synthesised through Au-S bonding between thiol substituted azobenzene derivatives with gold nanomaterials core. The structures of the compounds were elucidated by nuclear magnetic resonance, IR, transmission electron microscopy and UV-Vis spectroscopic techniques. The photoisomerisation effect was investigated for the synthesised compounds using the absorption studies. The photosaturation was occurred at ∼24 s and back relaxation was found at ∼315 min. The sterical hindrance developed by the multiple attachments of azobenzene molecules to the central gold nanoparticle core is the reason for the lengthening of photo-switching time duration. This study gives good information about the light induced characters of azobenzene based gold nanoparticles.
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spelling UMPir162442018-02-14T07:09:41Z http://umpir.ump.edu.my/id/eprint/16244/ Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles Aralapura, Yuvaraj Rajkumar Lutfor, M. R. M. M., Yusoff Kular, Sandeep QD Chemistry The azobenzene based gold nanomaterials was synthesised through Au-S bonding between thiol substituted azobenzene derivatives with gold nanomaterials core. The structures of the compounds were elucidated by nuclear magnetic resonance, IR, transmission electron microscopy and UV-Vis spectroscopic techniques. The photoisomerisation effect was investigated for the synthesised compounds using the absorption studies. The photosaturation was occurred at ∼24 s and back relaxation was found at ∼315 min. The sterical hindrance developed by the multiple attachments of azobenzene molecules to the central gold nanoparticle core is the reason for the lengthening of photo-switching time duration. This study gives good information about the light induced characters of azobenzene based gold nanoparticles. The Institution of Engineering and Technology 2017-11-29 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16244/1/fist-2017-mashitah-Photo-induced%20characteristics%20of%20azobenzene1.pdf Aralapura, Yuvaraj Rajkumar and Lutfor, M. R. and M. M., Yusoff and Kular, Sandeep (2017) Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles. IET Micro & Nano Letters, 12 (3). pp. 201-204. ISSN 1750-0443. (Published) http://dx.doi.org/10.1049/mnl.2016.0507 doi: 10.1049/mnl.2016.0507
spellingShingle QD Chemistry
Aralapura, Yuvaraj Rajkumar
Lutfor, M. R.
M. M., Yusoff
Kular, Sandeep
Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
title Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
title_full Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
title_fullStr Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
title_full_unstemmed Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
title_short Photo-Induced Characteristics of Azobenzene Based Gold Nanoparticles
title_sort photo induced characteristics of azobenzene based gold nanoparticles
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/16244/1/fist-2017-mashitah-Photo-induced%20characteristics%20of%20azobenzene1.pdf
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AT lutformr photoinducedcharacteristicsofazobenzenebasedgoldnanoparticles
AT mmyusoff photoinducedcharacteristicsofazobenzenebasedgoldnanoparticles
AT kularsandeep photoinducedcharacteristicsofazobenzenebasedgoldnanoparticles