The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity

In the present paper, bioresin was prepared from non-edible rubber seed oil via alcoholysis–polyesterification process over homogeneous base catalyst tailored by copper oxide (CuO) nanoparticles. CuO nanoparticles were synthesized in glycerol at room temperature and subsequently used in alkyd resin...

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Main Authors: Ong, Huei Ruey, Ramli, Ridzuan, Khan, Maksudur R., R. M., Yunus
Format: Article
Language:English
Published: Elsevier Ltd. 2016
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/16756/1/fkksa-2016-maksudur-%20The%20Influence%20of%20CuO%20Nanoparticle1.pdf
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author Ong, Huei Ruey
Ramli, Ridzuan
Khan, Maksudur R.
R. M., Yunus
author_facet Ong, Huei Ruey
Ramli, Ridzuan
Khan, Maksudur R.
R. M., Yunus
author_sort Ong, Huei Ruey
collection UMP
description In the present paper, bioresin was prepared from non-edible rubber seed oil via alcoholysis–polyesterification process over homogeneous base catalyst tailored by copper oxide (CuO) nanoparticles. CuO nanoparticles were synthesized in glycerol at room temperature and subsequently used in alkyd resin synthesis. The polyesterification process was monitored by determining the acid values as a function of time at different CuO nanoparticle concentrations. The formation of the alkyd resin was confirmed by FTIR with the presence of ester group (Csingle bondOsingle bondC). The antimicrobial activity of the pseudo–homogeneous additive was determined via Kirby–Bauer Method. The addition of CuO nanoparticle into the conventional homogeneous base catalyzed system explored a new catalytic route for the preparation of bioresin from vegetable oil while reducing the reaction time, as well as inducing the antimicrobial properties in the resin.
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spelling UMPir167562017-09-11T07:46:43Z http://umpir.ump.edu.my/id/eprint/16756/ The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity Ong, Huei Ruey Ramli, Ridzuan Khan, Maksudur R. R. M., Yunus TP Chemical technology In the present paper, bioresin was prepared from non-edible rubber seed oil via alcoholysis–polyesterification process over homogeneous base catalyst tailored by copper oxide (CuO) nanoparticles. CuO nanoparticles were synthesized in glycerol at room temperature and subsequently used in alkyd resin synthesis. The polyesterification process was monitored by determining the acid values as a function of time at different CuO nanoparticle concentrations. The formation of the alkyd resin was confirmed by FTIR with the presence of ester group (Csingle bondOsingle bondC). The antimicrobial activity of the pseudo–homogeneous additive was determined via Kirby–Bauer Method. The addition of CuO nanoparticle into the conventional homogeneous base catalyzed system explored a new catalytic route for the preparation of bioresin from vegetable oil while reducing the reaction time, as well as inducing the antimicrobial properties in the resin. Elsevier Ltd. 2016 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/16756/1/fkksa-2016-maksudur-%20The%20Influence%20of%20CuO%20Nanoparticle1.pdf Ong, Huei Ruey and Ramli, Ridzuan and Khan, Maksudur R. and R. M., Yunus (2016) The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity. Progress in Organic Coatings, 101. pp. 245-252. ISSN 0300-9440. (Published) http://dx.doi.org/10.1016/j.porgcoat.2016.08.017 10.1016/j.porgcoat.2016.08.017
spellingShingle TP Chemical technology
Ong, Huei Ruey
Ramli, Ridzuan
Khan, Maksudur R.
R. M., Yunus
The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity
title The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity
title_full The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity
title_fullStr The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity
title_full_unstemmed The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity
title_short The Influence of CuO Nanoparticle on Non-edible Rubber Seed Oil based Alkyd Resin Preparation and its Antimicrobial Activity
title_sort influence of cuo nanoparticle on non edible rubber seed oil based alkyd resin preparation and its antimicrobial activity
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/16756/1/fkksa-2016-maksudur-%20The%20Influence%20of%20CuO%20Nanoparticle1.pdf
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