Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions
Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric a...
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| Format: | Article |
| Language: | English |
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Elsevier
2017
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| Online Access: | http://umpir.ump.edu.my/id/eprint/17471/2/Highly%20active%20bio-waste%20cellulose%20supported%20poly%28amidoxime%29%20palladium%28II%29%20complex%20for%20Heck%20reactions%201.pdf |
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| author | Islam, Md. Shaharul Lutfor, M. R. M. M., Yusoff Sarkar, Shaheen M. |
| author_facet | Islam, Md. Shaharul Lutfor, M. R. M. M., Yusoff Sarkar, Shaheen M. |
| author_sort | Islam, Md. Shaharul |
| collection | UMP |
| description | Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analyses. The cellulose supported heterogeneous Pd(II) complex showed high stability and catalytic activity towards Mizoroki-Heck reaction of aryl halides and arenediazonium tetrafluoroborate with a variety of olefins to give the corresponding cross-coupling products in up to 97% yield. The Pd(II) complex was separated from the reaction mixtures and repeatedly used up to seven times without any significant decrease of its catalytic performance. |
| first_indexed | 2024-03-06T12:15:01Z |
| format | Article |
| id | UMPir17471 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:15:01Z |
| publishDate | 2017 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | UMPir174712018-01-31T02:55:32Z http://umpir.ump.edu.my/id/eprint/17471/ Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions Islam, Md. Shaharul Lutfor, M. R. M. M., Yusoff Sarkar, Shaheen M. Q Science (General) Corn-cob cellulose supported poly(amidoxime) Pd(II) complex was synthesized and characterized by field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), energy dispersive X-ray (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA) and inductively coupled plasma atomic emission spectroscopy (ICP-AES) analyses. The cellulose supported heterogeneous Pd(II) complex showed high stability and catalytic activity towards Mizoroki-Heck reaction of aryl halides and arenediazonium tetrafluoroborate with a variety of olefins to give the corresponding cross-coupling products in up to 97% yield. The Pd(II) complex was separated from the reaction mixtures and repeatedly used up to seven times without any significant decrease of its catalytic performance. Elsevier 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/17471/2/Highly%20active%20bio-waste%20cellulose%20supported%20poly%28amidoxime%29%20palladium%28II%29%20complex%20for%20Heck%20reactions%201.pdf Islam, Md. Shaharul and Lutfor, M. R. and M. M., Yusoff and Sarkar, Shaheen M. (2017) Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions. Journal of Cleaner Production, 149. pp. 1045-1050. ISSN 0959-6526 (print), 1879-1786 (online). (Published) https://doi.org/10.1016/j.jclepro.2017.02.121 doi: 10.1016/j.jclepro.2017.02.121 |
| spellingShingle | Q Science (General) Islam, Md. Shaharul Lutfor, M. R. M. M., Yusoff Sarkar, Shaheen M. Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions |
| title | Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions |
| title_full | Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions |
| title_fullStr | Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions |
| title_full_unstemmed | Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions |
| title_short | Highly Active Bio-Waste Cellulose Supported Poly(Amidoxime) Palladium(II) Complex for Heck Reactions |
| title_sort | highly active bio waste cellulose supported poly amidoxime palladium ii complex for heck reactions |
| topic | Q Science (General) |
| url | http://umpir.ump.edu.my/id/eprint/17471/2/Highly%20active%20bio-waste%20cellulose%20supported%20poly%28amidoxime%29%20palladium%28II%29%20complex%20for%20Heck%20reactions%201.pdf |
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