Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB

Background/Objectives: A batch adsorption process of Pb (II) ions from aqueous solution using modified magnetic nanocomposite from Oil Palm Empty Fruit Bunch (OPEFB). Methods: OPEFB waste was ground using grinder and hammer mill prior to magnetize using Fe2O3 to produce a nano-composite with a final...

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Main Authors: Daneshfozoun, S., Redza, Reedzwan, Vo, Dai-Viet N., Ramli, Nasser Mohamed, Abdullah, M. Azmuddin, Abdullah, Bawadi
Format: Article
Language:English
Published: Indian Journal of Science and Technology 2017
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/18079/1/Ind%20J%20Sci%20Tech_2017.pdf
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author Daneshfozoun, S.
Redza, Reedzwan
Vo, Dai-Viet N.
Ramli, Nasser Mohamed
Abdullah, M. Azmuddin
Abdullah, Bawadi
author_facet Daneshfozoun, S.
Redza, Reedzwan
Vo, Dai-Viet N.
Ramli, Nasser Mohamed
Abdullah, M. Azmuddin
Abdullah, Bawadi
author_sort Daneshfozoun, S.
collection UMP
description Background/Objectives: A batch adsorption process of Pb (II) ions from aqueous solution using modified magnetic nanocomposite from Oil Palm Empty Fruit Bunch (OPEFB). Methods: OPEFB waste was ground using grinder and hammer mill prior to magnetize using Fe2O3 to produce a nano-composite with a final size range of 0.005-0.02 mm. The adsorbent was characterized using FESEM. Batch adsorption study was performed at different temperatures (298-338K) and initial Pb concentrations (100–1000 ppm). Findings: The adsorbent morphology reveals the dense structure with pores that would increase the surface area of adsorbent. The dynamic equilibrium between fluid and solid phase is achieved approximately 60-65 min and 45 min for OPEFB and MN-EFB respectively. MN-EFB exhibits better adsorption efficiency (the best: 93.7%) as compared to raw OPEFB (the best: 78%). The pseudo-second-order kinetic fitted well with the experimental data. The activation energy of sorption obtained was 22.76 kJ mol−1 indicates that physical sorption also contributes to the adsorption process. Application/Improvements: Bio-sorbent with magnetic properties provides better removal efficiency, high reusability and suitable to be used in the industry to remove heavy metals from wastewater.
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spelling UMPir180792018-01-15T06:49:38Z http://umpir.ump.edu.my/id/eprint/18079/ Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB Daneshfozoun, S. Redza, Reedzwan Vo, Dai-Viet N. Ramli, Nasser Mohamed Abdullah, M. Azmuddin Abdullah, Bawadi TP Chemical technology Background/Objectives: A batch adsorption process of Pb (II) ions from aqueous solution using modified magnetic nanocomposite from Oil Palm Empty Fruit Bunch (OPEFB). Methods: OPEFB waste was ground using grinder and hammer mill prior to magnetize using Fe2O3 to produce a nano-composite with a final size range of 0.005-0.02 mm. The adsorbent was characterized using FESEM. Batch adsorption study was performed at different temperatures (298-338K) and initial Pb concentrations (100–1000 ppm). Findings: The adsorbent morphology reveals the dense structure with pores that would increase the surface area of adsorbent. The dynamic equilibrium between fluid and solid phase is achieved approximately 60-65 min and 45 min for OPEFB and MN-EFB respectively. MN-EFB exhibits better adsorption efficiency (the best: 93.7%) as compared to raw OPEFB (the best: 78%). The pseudo-second-order kinetic fitted well with the experimental data. The activation energy of sorption obtained was 22.76 kJ mol−1 indicates that physical sorption also contributes to the adsorption process. Application/Improvements: Bio-sorbent with magnetic properties provides better removal efficiency, high reusability and suitable to be used in the industry to remove heavy metals from wastewater. Indian Journal of Science and Technology 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/18079/1/Ind%20J%20Sci%20Tech_2017.pdf Daneshfozoun, S. and Redza, Reedzwan and Vo, Dai-Viet N. and Ramli, Nasser Mohamed and Abdullah, M. Azmuddin and Abdullah, Bawadi (2017) Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB. Indian Journal of Science and Technology, 10 (11). pp. 1-5. ISSN (Print) : 0974-6846 ; (Online) : 0974-5645. (Published) DOI: 10.17485/ijst/2017/v10i11/111447
spellingShingle TP Chemical technology
Daneshfozoun, S.
Redza, Reedzwan
Vo, Dai-Viet N.
Ramli, Nasser Mohamed
Abdullah, M. Azmuddin
Abdullah, Bawadi
Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB
title Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB
title_full Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB
title_fullStr Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB
title_full_unstemmed Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB
title_short Adsorption Kinetics of Pb(II) Ions from Aqueous Solution using Modified Magnetic Nano-Composite of OPEFB
title_sort adsorption kinetics of pb ii ions from aqueous solution using modified magnetic nano composite of opefb
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/18079/1/Ind%20J%20Sci%20Tech_2017.pdf
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