Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane

The emission of harmful gases such as carbon dioxide (CO2) via gas processing plant and daily human activities gave negative impacts to the environment and global inhabitant. Flat sheet asymmetric membranes were produced from homogenous solution of Poly(vinylideneflouride) (PVDF) via phase inversion...

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Main Authors: M. Z., Zuwairi, Sunarti, Abd Rahman
Format: Conference or Workshop Item
Language:English
English
Published: IOP Publishing 2017
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/18349/1/Study%20on%20CO2-%20N2%C2%A0separation-%20The%20effect%20of%20rubbery%20polymer%20coating%20on%20PVDF%20membrane.pdf
http://umpir.ump.edu.my/id/eprint/18349/2/Study%20on%20CO2-%20N2%C2%A0separation-%20The%20effect%20of%20rubbery%20polymer%20coating%20on%20PVDF%20membrane%201.pdf
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author M. Z., Zuwairi
Sunarti, Abd Rahman
author_facet M. Z., Zuwairi
Sunarti, Abd Rahman
author_sort M. Z., Zuwairi
collection UMP
description The emission of harmful gases such as carbon dioxide (CO2) via gas processing plant and daily human activities gave negative impacts to the environment and global inhabitant. Flat sheet asymmetric membranes were produced from homogenous solution of Poly(vinylideneflouride) (PVDF) via phase inversion method using N-methyl-2-pyrrolidone (NMP) as the solvent. While the poly ether b-amide (PEBAX) was dissolve by using of (70 ethanol and 30 water) as a solvent and and lithium chloride as a additives. The morphology and cross section of the produced membranes were observed by Scanning Electron Microscope (SEM). Then, the membranes were tested for chemical analysis to define the presence of PEBAX in the membrane by using Fourier Transform Infrared (FTIR) spectroscopy. The permeation performances of the membranes were evaluated in terms of permeability and selectivity of the membranes by using gas permeation test. Increasing the PEBAX content significantly increased the selectivity of the PVDF membrane to separate the CO2/N2 gases but decreased the amount of the gases that passed through the membrane.
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spelling UMPir183492017-12-13T06:17:51Z http://umpir.ump.edu.my/id/eprint/18349/ Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane M. Z., Zuwairi Sunarti, Abd Rahman TP Chemical technology The emission of harmful gases such as carbon dioxide (CO2) via gas processing plant and daily human activities gave negative impacts to the environment and global inhabitant. Flat sheet asymmetric membranes were produced from homogenous solution of Poly(vinylideneflouride) (PVDF) via phase inversion method using N-methyl-2-pyrrolidone (NMP) as the solvent. While the poly ether b-amide (PEBAX) was dissolve by using of (70 ethanol and 30 water) as a solvent and and lithium chloride as a additives. The morphology and cross section of the produced membranes were observed by Scanning Electron Microscope (SEM). Then, the membranes were tested for chemical analysis to define the presence of PEBAX in the membrane by using Fourier Transform Infrared (FTIR) spectroscopy. The permeation performances of the membranes were evaluated in terms of permeability and selectivity of the membranes by using gas permeation test. Increasing the PEBAX content significantly increased the selectivity of the PVDF membrane to separate the CO2/N2 gases but decreased the amount of the gases that passed through the membrane. IOP Publishing 2017-06 Conference or Workshop Item PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/18349/1/Study%20on%20CO2-%20N2%C2%A0separation-%20The%20effect%20of%20rubbery%20polymer%20coating%20on%20PVDF%20membrane.pdf application/pdf en http://umpir.ump.edu.my/id/eprint/18349/2/Study%20on%20CO2-%20N2%C2%A0separation-%20The%20effect%20of%20rubbery%20polymer%20coating%20on%20PVDF%20membrane%201.pdf M. Z., Zuwairi and Sunarti, Abd Rahman (2017) Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane. In: 29th Symposium of Malaysian Chemical Engineers (SOMChE) 2016 , 1st - 3rd December 2016 , Sarawak, Malaysia. pp. 1-7., 260 (1). ISSN 1757-8981 (Print), 1757-899X (Online) (Published) http://iopscience.iop.org/article/10.1088/1757-899X/206/1/012047/meta doi:10.1088/1757-899X/206/1/012047
spellingShingle TP Chemical technology
M. Z., Zuwairi
Sunarti, Abd Rahman
Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane
title Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane
title_full Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane
title_fullStr Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane
title_full_unstemmed Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane
title_short Study on CO2/ N2 Separation: The Effect of Rubbery Polymer Coating on PVDF Membrane
title_sort study on co2 n2 separation the effect of rubbery polymer coating on pvdf membrane
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/18349/1/Study%20on%20CO2-%20N2%C2%A0separation-%20The%20effect%20of%20rubbery%20polymer%20coating%20on%20PVDF%20membrane.pdf
http://umpir.ump.edu.my/id/eprint/18349/2/Study%20on%20CO2-%20N2%C2%A0separation-%20The%20effect%20of%20rubbery%20polymer%20coating%20on%20PVDF%20membrane%201.pdf
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