Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering

High density polyethylene (HDPE) degradation has been studied. In this study, HDPE was incorporated with manganese laurate, manganese palmitate and manganese stearate as pro-oxidant additives. Preparation of samples were conducted by adding the HDPE resin with pro-oxidant additives in the range of 0...

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Main Authors: Maryudi, M., Dewayanto, Nugroho, Beg, M. D. H., R. M., Yunus
Format: Article
Language:English
Published: Penerbit Universiti Teknologi Malaysia 2017
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/21170/1/Comparison%20of%20manganese%20laurate%2C%20manganese%20palmitate%20and%20manganese%20stearate%20on%20accelerating%20degradation%20of%20HDPE%20during%20natural%20weathering.pdf
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author Maryudi, M.
Dewayanto, Nugroho
Beg, M. D. H.
R. M., Yunus
author_facet Maryudi, M.
Dewayanto, Nugroho
Beg, M. D. H.
R. M., Yunus
author_sort Maryudi, M.
collection UMP
description High density polyethylene (HDPE) degradation has been studied. In this study, HDPE was incorporated with manganese laurate, manganese palmitate and manganese stearate as pro-oxidant additives. Preparation of samples were conducted by adding the HDPE resin with pro-oxidant additives in the range of 0-1.0 wt %. A twin screw extruder was employed prior to the injection molding technique. Samples were subjected to natural weathering for the maximum duration of 24 weeks. Assessments on the change of the properties of samples after natural weathering treatment were conducted by FTIR analysis, tensile testing and average molecular weight analysis. In term of their capabilities to accelerate degradation of HDPE, manganese stearate exhibited more influence than manganese laurate and manganese palmitate. The carbonyl group’s peak arises as a result of oxidation during the treatment as revealed by FTIR traces. Samples with pro-oxidant additives shows a loss of their strain at break. The amount of pro-oxidant additives increases the degradation of samples.
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spelling UMPir211702018-06-11T03:28:06Z http://umpir.ump.edu.my/id/eprint/21170/ Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering Maryudi, M. Dewayanto, Nugroho Beg, M. D. H. R. M., Yunus TP Chemical technology High density polyethylene (HDPE) degradation has been studied. In this study, HDPE was incorporated with manganese laurate, manganese palmitate and manganese stearate as pro-oxidant additives. Preparation of samples were conducted by adding the HDPE resin with pro-oxidant additives in the range of 0-1.0 wt %. A twin screw extruder was employed prior to the injection molding technique. Samples were subjected to natural weathering for the maximum duration of 24 weeks. Assessments on the change of the properties of samples after natural weathering treatment were conducted by FTIR analysis, tensile testing and average molecular weight analysis. In term of their capabilities to accelerate degradation of HDPE, manganese stearate exhibited more influence than manganese laurate and manganese palmitate. The carbonyl group’s peak arises as a result of oxidation during the treatment as revealed by FTIR traces. Samples with pro-oxidant additives shows a loss of their strain at break. The amount of pro-oxidant additives increases the degradation of samples. Penerbit Universiti Teknologi Malaysia 2017 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/21170/1/Comparison%20of%20manganese%20laurate%2C%20manganese%20palmitate%20and%20manganese%20stearate%20on%20accelerating%20degradation%20of%20HDPE%20during%20natural%20weathering.pdf Maryudi, M. and Dewayanto, Nugroho and Beg, M. D. H. and R. M., Yunus (2017) Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering. Jurnal Teknologi (Sciences and Engineering), 79 (7). pp. 123-130. ISSN 0127-9696 (print); 2180-3722 (online). (Published) https://jurnalteknologi.utm.my/index.php/jurnalteknologi/article/view/10533
spellingShingle TP Chemical technology
Maryudi, M.
Dewayanto, Nugroho
Beg, M. D. H.
R. M., Yunus
Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering
title Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering
title_full Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering
title_fullStr Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering
title_full_unstemmed Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering
title_short Comparison of manganese laurate, manganese palmitate and manganese stearate on accelerating degradation of HDPE during natural weathering
title_sort comparison of manganese laurate manganese palmitate and manganese stearate on accelerating degradation of hdpe during natural weathering
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/21170/1/Comparison%20of%20manganese%20laurate%2C%20manganese%20palmitate%20and%20manganese%20stearate%20on%20accelerating%20degradation%20of%20HDPE%20during%20natural%20weathering.pdf
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