Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies

Recently, there is a growing interest in identifying low-cost alternative adsorbents which have reasonable adsorption efficiency for dye removal. In this study, agricultural waste, Artocarpus Integer peel (AI-Peel) was used as the adsorbent to remove methylene blue (MB) from aqueous solution. The ba...

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Main Authors: Rosalyza, Hasan, Nurul Adina, Mohamed Razifuddin, Nurfatehah Wahyuny, Che Jusoh, Rohayu, Jusoh, Herma Dina, Setiabudi
Format: Article
Language:English
Published: UTM Press 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/21335/1/Artocarpus%20integer%20peel%20as%20a%20highly%20effective-fkksa-2018.pdf
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author Rosalyza, Hasan
Nurul Adina, Mohamed Razifuddin
Nurfatehah Wahyuny, Che Jusoh
Rohayu, Jusoh
Herma Dina, Setiabudi
author_facet Rosalyza, Hasan
Nurul Adina, Mohamed Razifuddin
Nurfatehah Wahyuny, Che Jusoh
Rohayu, Jusoh
Herma Dina, Setiabudi
author_sort Rosalyza, Hasan
collection UMP
description Recently, there is a growing interest in identifying low-cost alternative adsorbents which have reasonable adsorption efficiency for dye removal. In this study, agricultural waste, Artocarpus Integer peel (AI-Peel) was used as the adsorbent to remove methylene blue (MB) from aqueous solution. The batch adsorption process was conducted to evaluate the effect of contact time (1 – 40 min), adsorbent dosage (0.25 – 4.0 g L-1), pH (2 – 8), initial dye concentration (100 – 500 mg L-1) and temperature (30 – 50 oC). The experimental data followed well pseudo-second-order kinetic model and Langmuir isotherm (Type 2) with maximum adsorption capacity of 396.825 mg g-1. The analysis of thermodynamic studies indicated that the adsorption process was exothermic, controlled by a chemisorption process, feasible and spontaneous in nature with decrease in degree of spontaneity at higher temperature. The characterization results revealed that the functional groups of AI-Peel play an important role in the adsorption of MB onto AI-Peel. The study of pelletized and reusability of AI-Peel indicated the great potential of pelletized AI-Peel as low-cost adsorbent for efficient removal of MB from aqueous solution. This study successfully discovers a new highly effective low-cost adsorbent for MB removal.
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spelling UMPir213352018-07-12T08:05:35Z http://umpir.ump.edu.my/id/eprint/21335/ Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies Rosalyza, Hasan Nurul Adina, Mohamed Razifuddin Nurfatehah Wahyuny, Che Jusoh Rohayu, Jusoh Herma Dina, Setiabudi TP Chemical technology Recently, there is a growing interest in identifying low-cost alternative adsorbents which have reasonable adsorption efficiency for dye removal. In this study, agricultural waste, Artocarpus Integer peel (AI-Peel) was used as the adsorbent to remove methylene blue (MB) from aqueous solution. The batch adsorption process was conducted to evaluate the effect of contact time (1 – 40 min), adsorbent dosage (0.25 – 4.0 g L-1), pH (2 – 8), initial dye concentration (100 – 500 mg L-1) and temperature (30 – 50 oC). The experimental data followed well pseudo-second-order kinetic model and Langmuir isotherm (Type 2) with maximum adsorption capacity of 396.825 mg g-1. The analysis of thermodynamic studies indicated that the adsorption process was exothermic, controlled by a chemisorption process, feasible and spontaneous in nature with decrease in degree of spontaneity at higher temperature. The characterization results revealed that the functional groups of AI-Peel play an important role in the adsorption of MB onto AI-Peel. The study of pelletized and reusability of AI-Peel indicated the great potential of pelletized AI-Peel as low-cost adsorbent for efficient removal of MB from aqueous solution. This study successfully discovers a new highly effective low-cost adsorbent for MB removal. UTM Press 2018 Article PeerReviewed application/pdf en http://umpir.ump.edu.my/id/eprint/21335/1/Artocarpus%20integer%20peel%20as%20a%20highly%20effective-fkksa-2018.pdf Rosalyza, Hasan and Nurul Adina, Mohamed Razifuddin and Nurfatehah Wahyuny, Che Jusoh and Rohayu, Jusoh and Herma Dina, Setiabudi (2018) Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies. Malaysian Journal of Fundamental and Applied Sciences, 14 (1). pp. 25-31. ISSN 2289-5981. (Published) https://mjfas.utm.my/index.php/mjfas/article/view/791
spellingShingle TP Chemical technology
Rosalyza, Hasan
Nurul Adina, Mohamed Razifuddin
Nurfatehah Wahyuny, Che Jusoh
Rohayu, Jusoh
Herma Dina, Setiabudi
Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies
title Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies
title_full Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies
title_fullStr Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies
title_full_unstemmed Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies
title_short Artocarpus integer peel as a highly effective low-cost adsorbent for methylene blue removal: Kinetics, isotherm, thermodynamic and pelletized studies
title_sort artocarpus integer peel as a highly effective low cost adsorbent for methylene blue removal kinetics isotherm thermodynamic and pelletized studies
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/21335/1/Artocarpus%20integer%20peel%20as%20a%20highly%20effective-fkksa-2018.pdf
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