Size-dependent charge storage of graphene flakes

This paper focuses on the charge storage properties of reduced graphene oxide (rGO) in different flake sizes. Sonication is used to exfoliate rGO into different flake sizes, as confirmed by the spectroscopy and microscopy techniques. The oxygen-related functionalities on rGO samples are quantified b...

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Main Authors: K. F., Chong, C. Chan, Geraldine S., Ali, Gomaa A. M., Eunice Tang, Danella, Algarni, H.
Format: Conference or Workshop Item
Language:English
English
Published: 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/21996/1/38.%20Size-dependent%20charge%20storage%20of%20graphene%20flakes.pdf
http://umpir.ump.edu.my/id/eprint/21996/2/38.1%20Size-dependent%20charge%20storage%20of%20graphene%20flakes.pdf
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author K. F., Chong
C. Chan, Geraldine S.
Ali, Gomaa A. M.
Eunice Tang, Danella
Algarni, H.
author_facet K. F., Chong
C. Chan, Geraldine S.
Ali, Gomaa A. M.
Eunice Tang, Danella
Algarni, H.
author_sort K. F., Chong
collection UMP
description This paper focuses on the charge storage properties of reduced graphene oxide (rGO) in different flake sizes. Sonication is used to exfoliate rGO into different flake sizes, as confirmed by the spectroscopy and microscopy techniques. The oxygen-related functionalities on rGO samples are quantified by Fourier transform infrared spectroscopy and reveal that higher amount of unreduced oxygen functionalities can be found on rGO with smaller flake size. The charge storage properties of rGO in different flake sizes are studied by cyclic voltammetry, galvanostatic charge discharge and electrochemical impedance spectroscopy. The findings demonstrate that the rGO with smaller flake size possesses higher charge storage capability (238 F g-1 at x A g-1), as compared to that of rGO with larger flake size (147 F g-1 at x A g-1). Apart from larger surface area contribution, the unreduced oxygen functionalities in rGO with smaller flake size also plays an important role in contributing pseudocapacitance effect to the rGO. The current findings add substantial understanding of rGO flake size effect towards electrochemical properties.
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spelling UMPir219962018-09-21T07:14:22Z http://umpir.ump.edu.my/id/eprint/21996/ Size-dependent charge storage of graphene flakes K. F., Chong C. Chan, Geraldine S. Ali, Gomaa A. M. Eunice Tang, Danella Algarni, H. QD Chemistry This paper focuses on the charge storage properties of reduced graphene oxide (rGO) in different flake sizes. Sonication is used to exfoliate rGO into different flake sizes, as confirmed by the spectroscopy and microscopy techniques. The oxygen-related functionalities on rGO samples are quantified by Fourier transform infrared spectroscopy and reveal that higher amount of unreduced oxygen functionalities can be found on rGO with smaller flake size. The charge storage properties of rGO in different flake sizes are studied by cyclic voltammetry, galvanostatic charge discharge and electrochemical impedance spectroscopy. The findings demonstrate that the rGO with smaller flake size possesses higher charge storage capability (238 F g-1 at x A g-1), as compared to that of rGO with larger flake size (147 F g-1 at x A g-1). Apart from larger surface area contribution, the unreduced oxygen functionalities in rGO with smaller flake size also plays an important role in contributing pseudocapacitance effect to the rGO. The current findings add substantial understanding of rGO flake size effect towards electrochemical properties. 2018-03 Conference or Workshop Item NonPeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/21996/1/38.%20Size-dependent%20charge%20storage%20of%20graphene%20flakes.pdf pdf en http://umpir.ump.edu.my/id/eprint/21996/2/38.1%20Size-dependent%20charge%20storage%20of%20graphene%20flakes.pdf K. F., Chong and C. Chan, Geraldine S. and Ali, Gomaa A. M. and Eunice Tang, Danella and Algarni, H. (2018) Size-dependent charge storage of graphene flakes. In: 4th Nanomaterials for Energy and Environment 2018 , 27 - 29 Jun 2018 , Paris, France. pp. 1-20.. (Unpublished) (Unpublished)
spellingShingle QD Chemistry
K. F., Chong
C. Chan, Geraldine S.
Ali, Gomaa A. M.
Eunice Tang, Danella
Algarni, H.
Size-dependent charge storage of graphene flakes
title Size-dependent charge storage of graphene flakes
title_full Size-dependent charge storage of graphene flakes
title_fullStr Size-dependent charge storage of graphene flakes
title_full_unstemmed Size-dependent charge storage of graphene flakes
title_short Size-dependent charge storage of graphene flakes
title_sort size dependent charge storage of graphene flakes
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/21996/1/38.%20Size-dependent%20charge%20storage%20of%20graphene%20flakes.pdf
http://umpir.ump.edu.my/id/eprint/21996/2/38.1%20Size-dependent%20charge%20storage%20of%20graphene%20flakes.pdf
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