Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)

Silica-based fibrous material has been extensively studied by researchers after the discovery of fibrous silica nanosphere (KCC-1) by Polshettiwar et al., 2010. The KCC-1 was first prepared using the microwave-assisted hydrothermal technique exhibited excellent properties, including a high surface a...

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Main Authors: S., Triwahyono, A. A., Jalil, N. S., Jamari, M. L., Firmansyah, N. A., Fatah, S. M., Izan, S. F., Jamian, Herma Dina, Setiabudi
Format: Conference or Workshop Item
Language:English
Published: Universiti Malaysia Pahang 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/23664/1/8.%20Isomerization%20of%20linear%20c5-c7%20over%20pt%20loaded.pdf
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author S., Triwahyono
A. A., Jalil
N. S., Jamari
M. L., Firmansyah
N. A., Fatah
S. M., Izan
S. F., Jamian
Herma Dina, Setiabudi
author_facet S., Triwahyono
A. A., Jalil
N. S., Jamari
M. L., Firmansyah
N. A., Fatah
S. M., Izan
S. F., Jamian
Herma Dina, Setiabudi
author_sort S., Triwahyono
collection UMP
description Silica-based fibrous material has been extensively studied by researchers after the discovery of fibrous silica nanosphere (KCC-1) by Polshettiwar et al., 2010. The KCC-1 was first prepared using the microwave-assisted hydrothermal technique exhibited excellent properties, including a high surface area, a fibrous surface morphology, good thermal and hydrothermal stabilities and mechanical stability. Moon, et al., (2012) reported that the mesoporous silica with fibrous morphology has high surface area compared with a typical hexagonal or cubic pore structure which suitable for good catalytic support. Previous study has many discovered related to the acid-catalyzed for isomerization reaction. They discovered that the isomerization supports must have appropriated acidity for the good catalytic activity. However, the KCC-1 which fully composed with silica does not provided an adequate acid sites to promote acid-catalyzed isomerization reaction [1,2]. In the present work, newly combined zeolite-based with fibrous silica was prepared via self-assembly process in the microemulsion system. This new catalyst has a potential to overcome inadequate acidity provided by KCC-1. Therefore, implementation of combined silica based material with zeolite enhanced the acidity of the catalyst to overcome the inadequate acidity provided by solely silica of KCC-1. The high acidity will enhanced the isomerization reaction towards producing high octane number gasoline [3].
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spelling UMPir236642019-01-08T04:20:25Z http://umpir.ump.edu.my/id/eprint/23664/ Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y) S., Triwahyono A. A., Jalil N. S., Jamari M. L., Firmansyah N. A., Fatah S. M., Izan S. F., Jamian Herma Dina, Setiabudi TP Chemical technology Silica-based fibrous material has been extensively studied by researchers after the discovery of fibrous silica nanosphere (KCC-1) by Polshettiwar et al., 2010. The KCC-1 was first prepared using the microwave-assisted hydrothermal technique exhibited excellent properties, including a high surface area, a fibrous surface morphology, good thermal and hydrothermal stabilities and mechanical stability. Moon, et al., (2012) reported that the mesoporous silica with fibrous morphology has high surface area compared with a typical hexagonal or cubic pore structure which suitable for good catalytic support. Previous study has many discovered related to the acid-catalyzed for isomerization reaction. They discovered that the isomerization supports must have appropriated acidity for the good catalytic activity. However, the KCC-1 which fully composed with silica does not provided an adequate acid sites to promote acid-catalyzed isomerization reaction [1,2]. In the present work, newly combined zeolite-based with fibrous silica was prepared via self-assembly process in the microemulsion system. This new catalyst has a potential to overcome inadequate acidity provided by KCC-1. Therefore, implementation of combined silica based material with zeolite enhanced the acidity of the catalyst to overcome the inadequate acidity provided by solely silica of KCC-1. The high acidity will enhanced the isomerization reaction towards producing high octane number gasoline [3]. Universiti Malaysia Pahang 2018 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23664/1/8.%20Isomerization%20of%20linear%20c5-c7%20over%20pt%20loaded.pdf S., Triwahyono and A. A., Jalil and N. S., Jamari and M. L., Firmansyah and N. A., Fatah and S. M., Izan and S. F., Jamian and Herma Dina, Setiabudi (2018) Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y). In: 4th International Conference Of Chemical Engineering And Industrial Biotechnology (ICCEIB 2018) , 1-2 August 2018 , Seri Pacific Hotel, Kuala Lumpur. pp. 98-100..
spellingShingle TP Chemical technology
S., Triwahyono
A. A., Jalil
N. S., Jamari
M. L., Firmansyah
N. A., Fatah
S. M., Izan
S. F., Jamian
Herma Dina, Setiabudi
Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)
title Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)
title_full Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)
title_fullStr Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)
title_full_unstemmed Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)
title_short Isomerization of linear c5-c7 over pt loaded on protonated fibrous silica@y zeolite (Pt/Hsi@Y)
title_sort isomerization of linear c5 c7 over pt loaded on protonated fibrous silica y zeolite pt hsi y
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/23664/1/8.%20Isomerization%20of%20linear%20c5-c7%20over%20pt%20loaded.pdf
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