Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes

In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The el...

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Váldodahkkit: Norfatihah, Mazuki, Nur Muhitul Jalilah, Rasali, Saadiah, M. A., Ahmad Salihin, Samsudin
Materiálatiipa: Conference or Workshop Item
Giella:English
English
Almmustuhtton: American Institute of Physics Inc. 2018
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Liŋkkat:http://umpir.ump.edu.my/id/eprint/23991/7/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMCPVA1.pdf
http://umpir.ump.edu.my/id/eprint/23991/13/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMC-PVA-NH4Cl%20based%20solid%20biopolymer%20electrolytes.pdf
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author Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Saadiah, M. A.
Ahmad Salihin, Samsudin
author_facet Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Saadiah, M. A.
Ahmad Salihin, Samsudin
author_sort Norfatihah, Mazuki
collection UMP
description In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The electrical conductivity of solid biopolymer electrolytes (SBEs) system was investigated by using Electrical Impedance Spectroscopy (EIS). Electrical study shows the highest ionic conductivity in room temperature (303 K) was achieved at 8.86 × 10−5 Scm−1 for sample containing 6 wt. % of NH4Cl. The present system shown unexpected drop after different amount of NH4Cl (1-5 wt. %) were added into the CMC/PVA and its might attributed to the factor of composition of dopant. All SBEs systems were found to be obeys Arrhenius behaviour where the plots show close to unity (R2∼1) and thermally activated.
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spelling UMPir239912023-12-04T02:47:26Z http://umpir.ump.edu.my/id/eprint/23991/ Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes Norfatihah, Mazuki Nur Muhitul Jalilah, Rasali Saadiah, M. A. Ahmad Salihin, Samsudin Q Science (General) QC Physics QD Chemistry In this present work, solid biopolymer electrolytes (SBEs) system consists of the blended polymer namely carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVA) doped ammonium chloride (NH4Cl) at different composition from 0 to 10 wt. % were successfully prepared by using casting technique. The electrical conductivity of solid biopolymer electrolytes (SBEs) system was investigated by using Electrical Impedance Spectroscopy (EIS). Electrical study shows the highest ionic conductivity in room temperature (303 K) was achieved at 8.86 × 10−5 Scm−1 for sample containing 6 wt. % of NH4Cl. The present system shown unexpected drop after different amount of NH4Cl (1-5 wt. %) were added into the CMC/PVA and its might attributed to the factor of composition of dopant. All SBEs systems were found to be obeys Arrhenius behaviour where the plots show close to unity (R2∼1) and thermally activated. American Institute of Physics Inc. 2018 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/23991/7/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMCPVA1.pdf pdf en http://umpir.ump.edu.my/id/eprint/23991/13/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMC-PVA-NH4Cl%20based%20solid%20biopolymer%20electrolytes.pdf Norfatihah, Mazuki and Nur Muhitul Jalilah, Rasali and Saadiah, M. A. and Ahmad Salihin, Samsudin (2018) Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes. In: AIP Conference Proceedings: 4th International Conference on Green Design and Manufacture 2018, IConGDM 2018 , 29-30 April 2018 , Ho Chi Minh, Vietnam. pp. 1-7., 2030 (020221). ISSN 0094-243X ISBN 978-0-7354-1752-6 (Published) https://doi.org/10.1063/1.5066862 10.1063/1.5066862
spellingShingle Q Science (General)
QC Physics
QD Chemistry
Norfatihah, Mazuki
Nur Muhitul Jalilah, Rasali
Saadiah, M. A.
Ahmad Salihin, Samsudin
Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_full Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_fullStr Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_full_unstemmed Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_short Irregularities trend in electrical conductivity of CMC/PVA-NH4Cl based solid biopolymer electrolytes
title_sort irregularities trend in electrical conductivity of cmc pva nh4cl based solid biopolymer electrolytes
topic Q Science (General)
QC Physics
QD Chemistry
url http://umpir.ump.edu.my/id/eprint/23991/7/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMCPVA1.pdf
http://umpir.ump.edu.my/id/eprint/23991/13/Irregularities%20trend%20in%20electrical%20conductivity%20of%20CMC-PVA-NH4Cl%20based%20solid%20biopolymer%20electrolytes.pdf
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