Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash
Palm oil fuel ash (POFA) is a waste material generated from the boiler due to the burning of palm oil biomass e.g. kernel shell and fiber as fuel to generate electricity. The present research focused on the study of adsorption isotherms, kinetics and thermodynamic properties on the removal of mercur...
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| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Elsevier Ltd
2018
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| Предмети: | |
| Онлайн доступ: | http://umpir.ump.edu.my/id/eprint/24022/1/23-Imla%20-%20MT_2018.pdf |
| _version_ | 1825812538948845568 |
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| author | Imla Syafiqah, Mohd Salleh Wan Mohd Hafizuddin, Wan Yussof |
| author_facet | Imla Syafiqah, Mohd Salleh Wan Mohd Hafizuddin, Wan Yussof |
| author_sort | Imla Syafiqah, Mohd Salleh |
| collection | UMP |
| description | Palm oil fuel ash (POFA) is a waste material generated from the boiler due to the burning of palm oil biomass e.g. kernel shell and fiber as fuel to generate electricity. The present research focused on the study of adsorption isotherms, kinetics and thermodynamic properties on the removal of mercury (II) ion onto POFA. The prepared POFA was characterized by FTIR, TGA and BET analysis. The equilibrium data at various concentrations were analyzed by Langmuir and Freundlich isotherms models. From this present study, the maximum adsorption capacity obtained from the Freundlich isotherm was 0.99 mg/g. A kinetic study was carried out with pseudo first order and pseudo second order reaction equations. It was found that the mercury (II) ion uptake process followed the pseudo second order rate expression. Thermodynamic parameters of the Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were also determined. The negative Gibbs free energy change (-788.90 kJ/mol) and the positive enthalpy change (73,680.33 kJ/mol) indicated that adsorption was spontaneous process and endothermic nature. Overall, POFA looks to be a promising adsorbent for removal of mercury (II) ion from aqueous solutions due to its high performance and availability at low cost. |
| first_indexed | 2024-03-06T12:30:40Z |
| format | Article |
| id | UMPir24022 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:30:40Z |
| publishDate | 2018 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | UMPir240222019-01-30T04:57:44Z http://umpir.ump.edu.my/id/eprint/24022/ Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash Imla Syafiqah, Mohd Salleh Wan Mohd Hafizuddin, Wan Yussof TD Environmental technology. Sanitary engineering Palm oil fuel ash (POFA) is a waste material generated from the boiler due to the burning of palm oil biomass e.g. kernel shell and fiber as fuel to generate electricity. The present research focused on the study of adsorption isotherms, kinetics and thermodynamic properties on the removal of mercury (II) ion onto POFA. The prepared POFA was characterized by FTIR, TGA and BET analysis. The equilibrium data at various concentrations were analyzed by Langmuir and Freundlich isotherms models. From this present study, the maximum adsorption capacity obtained from the Freundlich isotherm was 0.99 mg/g. A kinetic study was carried out with pseudo first order and pseudo second order reaction equations. It was found that the mercury (II) ion uptake process followed the pseudo second order rate expression. Thermodynamic parameters of the Gibbs free energy (ΔG°), enthalpy (ΔH°), and entropy (ΔS°) were also determined. The negative Gibbs free energy change (-788.90 kJ/mol) and the positive enthalpy change (73,680.33 kJ/mol) indicated that adsorption was spontaneous process and endothermic nature. Overall, POFA looks to be a promising adsorbent for removal of mercury (II) ion from aqueous solutions due to its high performance and availability at low cost. Elsevier Ltd 2018 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24022/1/23-Imla%20-%20MT_2018.pdf Imla Syafiqah, Mohd Salleh and Wan Mohd Hafizuddin, Wan Yussof (2018) Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash. Materials Today: Proceedings, 5 (10). pp. 21690-21697. ISSN 2214-7853. (Published) https://doi.org/10.1016/j.matpr.2018.07.020 https://doi.org/10.1016/j.matpr.2018.07.020 |
| spellingShingle | TD Environmental technology. Sanitary engineering Imla Syafiqah, Mohd Salleh Wan Mohd Hafizuddin, Wan Yussof Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash |
| title | Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash |
| title_full | Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash |
| title_fullStr | Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash |
| title_full_unstemmed | Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash |
| title_short | Kinetics, isotherms, and thermodynamic studies on the adsorption of mercury (ii) ion from aqueous solution using modified palm oil fuel ash |
| title_sort | kinetics isotherms and thermodynamic studies on the adsorption of mercury ii ion from aqueous solution using modified palm oil fuel ash |
| topic | TD Environmental technology. Sanitary engineering |
| url | http://umpir.ump.edu.my/id/eprint/24022/1/23-Imla%20-%20MT_2018.pdf |
| work_keys_str_mv | AT imlasyafiqahmohdsalleh kineticsisothermsandthermodynamicstudiesontheadsorptionofmercuryiiionfromaqueoussolutionusingmodifiedpalmoilfuelash AT wanmohdhafizuddinwanyussof kineticsisothermsandthermodynamicstudiesontheadsorptionofmercuryiiionfromaqueoussolutionusingmodifiedpalmoilfuelash |