Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection

Surface modification of metallic implants is often required to facilitate positive interaction between the implant and the surrounding hard tissue. In the present study, an oxide layer (Cr2O3) was successfully created on a Co-Cr-Mo alloys substrate by using thermal oxidation technique in atmospheric...

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Main Authors: Mas Ayu, Hassan, R., Daud, A., Shah, H. M., Hazwan, Siti Haryani, Tomadi, Salwani, Mohd Salleh
Format: Article
Language:English
Published: Trans Tech Publications 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/24066/7/Effect%20of%20Thermal%20Oxidation%20and%20Carbon%20Concentrations.pdf
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author Mas Ayu, Hassan
R., Daud
A., Shah
H. M., Hazwan
Siti Haryani, Tomadi
Salwani, Mohd Salleh
author_facet Mas Ayu, Hassan
R., Daud
A., Shah
H. M., Hazwan
Siti Haryani, Tomadi
Salwani, Mohd Salleh
author_sort Mas Ayu, Hassan
collection UMP
description Surface modification of metallic implants is often required to facilitate positive interaction between the implant and the surrounding hard tissue. In the present study, an oxide layer (Cr2O3) was successfully created on a Co-Cr-Mo alloys substrate by using thermal oxidation technique in atmospheric condition. The effect of different carbon content (0.03% and 0.24%) of oxidized Co-Cr-Mo alloys was investigated in terms of its corrosion behavior using electrochemical impedance spectroscopy techniques that immersed in simulated body fluid. The corrosion tests were repeated for five times for each of sample condition. The results demonstrated that thermal oxidation and carbon content have correlation in influencing the corrosion performance in Co-Cr-Mo alloys. Ahigh carbon content sample generates a lower corrosion-rate compared to low carbon content sample even though all samples were treated at similar oxidation temperature and time duration. Observation also showed that less diffusion of cobalt released in high carbon sample which is believed has effects in creating the uniformity and dense oxide layer without any presence of microcracks and delamination. This phenomenon can be concluded that carbon content in Co-Cr-Mo alloy have influenced in controlling the reaction of metal elements during thermal oxidation which is beneficial in formation of oxide layer. The uniformity and compact oxide layer substantially have enhanced the corrosion resistance of high carbon Co-Cr-Mo alloy.
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spelling UMPir240662019-02-12T08:55:03Z http://umpir.ump.edu.my/id/eprint/24066/ Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection Mas Ayu, Hassan R., Daud A., Shah H. M., Hazwan Siti Haryani, Tomadi Salwani, Mohd Salleh TJ Mechanical engineering and machinery Surface modification of metallic implants is often required to facilitate positive interaction between the implant and the surrounding hard tissue. In the present study, an oxide layer (Cr2O3) was successfully created on a Co-Cr-Mo alloys substrate by using thermal oxidation technique in atmospheric condition. The effect of different carbon content (0.03% and 0.24%) of oxidized Co-Cr-Mo alloys was investigated in terms of its corrosion behavior using electrochemical impedance spectroscopy techniques that immersed in simulated body fluid. The corrosion tests were repeated for five times for each of sample condition. The results demonstrated that thermal oxidation and carbon content have correlation in influencing the corrosion performance in Co-Cr-Mo alloys. Ahigh carbon content sample generates a lower corrosion-rate compared to low carbon content sample even though all samples were treated at similar oxidation temperature and time duration. Observation also showed that less diffusion of cobalt released in high carbon sample which is believed has effects in creating the uniformity and dense oxide layer without any presence of microcracks and delamination. This phenomenon can be concluded that carbon content in Co-Cr-Mo alloy have influenced in controlling the reaction of metal elements during thermal oxidation which is beneficial in formation of oxide layer. The uniformity and compact oxide layer substantially have enhanced the corrosion resistance of high carbon Co-Cr-Mo alloy. Trans Tech Publications 2018-03-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24066/7/Effect%20of%20Thermal%20Oxidation%20and%20Carbon%20Concentrations.pdf Mas Ayu, Hassan and R., Daud and A., Shah and H. M., Hazwan and Siti Haryani, Tomadi and Salwani, Mohd Salleh (2018) Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection. Materials Science Forum, 916. pp. 170-176. ISSN 0255-5476. (Published) https://doi.org/10.4028/www.scientific.net/MSF.916.170 https://doi.org/10.4028/www.scientific.net/MSF.916.170
spellingShingle TJ Mechanical engineering and machinery
Mas Ayu, Hassan
R., Daud
A., Shah
H. M., Hazwan
Siti Haryani, Tomadi
Salwani, Mohd Salleh
Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection
title Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection
title_full Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection
title_fullStr Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection
title_full_unstemmed Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection
title_short Effect of Thermal Oxidation and Carbon Concentrations on Co-Cr-Mo Alloy in Enhanced Corrosion Protection
title_sort effect of thermal oxidation and carbon concentrations on co cr mo alloy in enhanced corrosion protection
topic TJ Mechanical engineering and machinery
url http://umpir.ump.edu.my/id/eprint/24066/7/Effect%20of%20Thermal%20Oxidation%20and%20Carbon%20Concentrations.pdf
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