Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal

A new adsorbent (egg-shell treated oil palm fronds (EG-OPF)) prepared from wastes was evaluated for methylene blue (MB) removal. Optimization among three significant variables (initial concentration (X1), initial pH (X2), and adsorbent dosage (X3)) were executed using response surface methodology (R...

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Main Authors: Rosalyza, Hasan, Nur Aida Farihin, Ahliyasah, Chong, Chi Cheng, Rohayu, Jusoh, Setiabudi, H. D.
Format: Article
Language:English
Published: Diponegoro University 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/24283/1/Egg-shell%20treated%20oil%20palm%20fronds%20%28EG-OPF%29%20as%20low-cost%20adsorbent%20for%20methylene%20blue%20removal.pdf
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author Rosalyza, Hasan
Nur Aida Farihin, Ahliyasah
Chong, Chi Cheng
Rohayu, Jusoh
Setiabudi, H. D.
author_facet Rosalyza, Hasan
Nur Aida Farihin, Ahliyasah
Chong, Chi Cheng
Rohayu, Jusoh
Setiabudi, H. D.
author_sort Rosalyza, Hasan
collection UMP
description A new adsorbent (egg-shell treated oil palm fronds (EG-OPF)) prepared from wastes was evaluated for methylene blue (MB) removal. Optimization among three significant variables (initial concentration (X1), initial pH (X2), and adsorbent dosage (X3)) were executed using response surface methodology (RSM). The most excellent performance was marked at X1 = 291.7 mg/L, X2 = pH 5, and X3 = 1.82 g/L, with MB removal of 80.26 %. The kinetic study was fitted perfectly with the pseudo-second-order model (R2 > 0.990), indicating the chemisorption process. The isotherm study was found to follow the Langmuir isotherm model (R2 = 0.999), with maximal adsorption magnitude of 714.3 mg/g, implying the monolayer adsorption on a homogenous adsorbent surface. The reusability study affirmed the feasibility of EG-OPF in MB removal, credited to its excellent performance during reusability studies. The present study successfully discovered a new low-cost adsorbent (EG-OPF) for MB removal.
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spelling UMPir242832019-03-18T03:09:35Z http://umpir.ump.edu.my/id/eprint/24283/ Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal Rosalyza, Hasan Nur Aida Farihin, Ahliyasah Chong, Chi Cheng Rohayu, Jusoh Setiabudi, H. D. TP Chemical technology A new adsorbent (egg-shell treated oil palm fronds (EG-OPF)) prepared from wastes was evaluated for methylene blue (MB) removal. Optimization among three significant variables (initial concentration (X1), initial pH (X2), and adsorbent dosage (X3)) were executed using response surface methodology (RSM). The most excellent performance was marked at X1 = 291.7 mg/L, X2 = pH 5, and X3 = 1.82 g/L, with MB removal of 80.26 %. The kinetic study was fitted perfectly with the pseudo-second-order model (R2 > 0.990), indicating the chemisorption process. The isotherm study was found to follow the Langmuir isotherm model (R2 = 0.999), with maximal adsorption magnitude of 714.3 mg/g, implying the monolayer adsorption on a homogenous adsorbent surface. The reusability study affirmed the feasibility of EG-OPF in MB removal, credited to its excellent performance during reusability studies. The present study successfully discovered a new low-cost adsorbent (EG-OPF) for MB removal. Diponegoro University 2019-04 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24283/1/Egg-shell%20treated%20oil%20palm%20fronds%20%28EG-OPF%29%20as%20low-cost%20adsorbent%20for%20methylene%20blue%20removal.pdf Rosalyza, Hasan and Nur Aida Farihin, Ahliyasah and Chong, Chi Cheng and Rohayu, Jusoh and Setiabudi, H. D. (2019) Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1). pp. 158-164. ISSN 1978-2993. (Published) https://ejournal2.undip.ac.id/index.php/bcrec/article/view/3322/2272 https://doi.org/10.9767/bcrec.14.1.3322.158-164
spellingShingle TP Chemical technology
Rosalyza, Hasan
Nur Aida Farihin, Ahliyasah
Chong, Chi Cheng
Rohayu, Jusoh
Setiabudi, H. D.
Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal
title Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal
title_full Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal
title_fullStr Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal
title_full_unstemmed Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal
title_short Egg-shell treated oil palm fronds (EG-OPF) as low-cost adsorbent for methylene blue removal
title_sort egg shell treated oil palm fronds eg opf as low cost adsorbent for methylene blue removal
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/24283/1/Egg-shell%20treated%20oil%20palm%20fronds%20%28EG-OPF%29%20as%20low-cost%20adsorbent%20for%20methylene%20blue%20removal.pdf
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AT nuraidafarihinahliyasah eggshelltreatedoilpalmfrondsegopfaslowcostadsorbentformethyleneblueremoval
AT chongchicheng eggshelltreatedoilpalmfrondsegopfaslowcostadsorbentformethyleneblueremoval
AT rohayujusoh eggshelltreatedoilpalmfrondsegopfaslowcostadsorbentformethyleneblueremoval
AT setiabudihd eggshelltreatedoilpalmfrondsegopfaslowcostadsorbentformethyleneblueremoval