Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels
This contribution presents the characterization of poly(acrylamide-co-acrylic acid)-grafted-poly(styrene-co-methyl methacrylate) [poly(AAm-co-AAc)-g-poly(St-co-MMA)] The chemical structure of poly(AAm-co-AAc)-g-poly(St-co-MMA) microgels was proposed. The effect of MBA contents on the degree of cross...
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| Format: | Conference or Workshop Item |
| Language: | English |
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IOP Publishing
2018
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| Online Access: | http://umpir.ump.edu.my/id/eprint/24361/1/Chemical%20structure%2C%20water%20absorbency%20and%20thermal%20properties%20of%20poly.pdf |
| _version_ | 1825812593311219712 |
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| author | Ros Azlinawati, Ramli Shahrir, Hashim Laftah, Waham Ashaier |
| author_facet | Ros Azlinawati, Ramli Shahrir, Hashim Laftah, Waham Ashaier |
| author_sort | Ros Azlinawati, Ramli |
| collection | UMP |
| description | This contribution presents the characterization of poly(acrylamide-co-acrylic acid)-grafted-poly(styrene-co-methyl methacrylate) [poly(AAm-co-AAc)-g-poly(St-co-MMA)] The chemical structure of poly(AAm-co-AAc)-g-poly(St-co-MMA) microgels was proposed. The effect of MBA contents on the degree of cross-linking (%), water absorbency (EWC, %), glass transition temperature, Tg and thermal degradation were studied. The degree of cross-linking (%) and EWC, % increased at 1.5 to 1.675 wt.% of MBA might be due to mono cross-links of MBA. The fluctuation of Tg and melting temperature (Tm ) from 1.85 to 2.2 wt.% of MBA might be due to di, poly and cyclic cross-links of MBA. Decomposition of poly(AAm-co-AAc)-g-poly(St-co-MMA) was slightly affected by increasing in MBA contents from 1.5 to 2.2 wt.%. Tg of poly(AAm-co-AAc)-g-poly(St-co-MMA) was decreased at 1.5 to 1.675 wt.% of MBA due to increase in ordered structure and crystallinity content, which led to an increase in Tm . |
| first_indexed | 2024-03-06T12:31:29Z |
| format | Conference or Workshop Item |
| id | UMPir24361 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:31:29Z |
| publishDate | 2018 |
| publisher | IOP Publishing |
| record_format | dspace |
| spelling | UMPir243612019-05-27T04:26:03Z http://umpir.ump.edu.my/id/eprint/24361/ Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels Ros Azlinawati, Ramli Shahrir, Hashim Laftah, Waham Ashaier Q Science (General) This contribution presents the characterization of poly(acrylamide-co-acrylic acid)-grafted-poly(styrene-co-methyl methacrylate) [poly(AAm-co-AAc)-g-poly(St-co-MMA)] The chemical structure of poly(AAm-co-AAc)-g-poly(St-co-MMA) microgels was proposed. The effect of MBA contents on the degree of cross-linking (%), water absorbency (EWC, %), glass transition temperature, Tg and thermal degradation were studied. The degree of cross-linking (%) and EWC, % increased at 1.5 to 1.675 wt.% of MBA might be due to mono cross-links of MBA. The fluctuation of Tg and melting temperature (Tm ) from 1.85 to 2.2 wt.% of MBA might be due to di, poly and cyclic cross-links of MBA. Decomposition of poly(AAm-co-AAc)-g-poly(St-co-MMA) was slightly affected by increasing in MBA contents from 1.5 to 2.2 wt.%. Tg of poly(AAm-co-AAc)-g-poly(St-co-MMA) was decreased at 1.5 to 1.675 wt.% of MBA due to increase in ordered structure and crystallinity content, which led to an increase in Tm . IOP Publishing 2018-12 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24361/1/Chemical%20structure%2C%20water%20absorbency%20and%20thermal%20properties%20of%20poly.pdf Ros Azlinawati, Ramli and Shahrir, Hashim and Laftah, Waham Ashaier (2018) Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels. In: 5th International Conference on Process Engineering and Advanced Materials (ICPEAM 2018) , 13-14 August 2018 , Kuala Lumpur. pp. 1-8., 458 (1). ISSN 1757-8981 (Print); 1757-899X (Online) (Published) https://iopscience.iop.org/article/10.1088/1757-899X/458/1/012003/pdf |
| spellingShingle | Q Science (General) Ros Azlinawati, Ramli Shahrir, Hashim Laftah, Waham Ashaier Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels |
| title | Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels |
| title_full | Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels |
| title_fullStr | Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels |
| title_full_unstemmed | Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels |
| title_short | Chemical structure, water absorbency and thermal properties of poly(acrylamide-co-acrylic acid)-grafed-poly(styrene-co-methyl methacrylate) "raspberry" – shape like structure microgels |
| title_sort | chemical structure water absorbency and thermal properties of poly acrylamide co acrylic acid grafed poly styrene co methyl methacrylate raspberry shape like structure microgels |
| topic | Q Science (General) |
| url | http://umpir.ump.edu.my/id/eprint/24361/1/Chemical%20structure%2C%20water%20absorbency%20and%20thermal%20properties%20of%20poly.pdf |
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