Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture

The capture and storage of CO2 have been suggested as an effective strategy to reduce the global emissions of greenhouse gases. Hence, many studies have been carried out to develop highly efficient materials for capturing CO2. Herein, the CO2 capture performance of mesoporous ceria nanoparticle (MCN...

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Main Authors: Azmi, A. A., Ngadi, Norzita, Kamaruddin, M. J., Zakaria, Z. Y., Teh, Lee Peng, Annuar, N. H. R., Herma Dina, Setiabudi, Jalil, A. A., Aziz, M. A. A.
Format: Article
Language:English
Published: AIDIC 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/24972/1/Rapid%20one%20pot%20synthesis%20of%20mesoporous%20ceria%20nanoparticles%20.pdf
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author Azmi, A. A.
Ngadi, Norzita
Kamaruddin, M. J.
Zakaria, Z. Y.
Teh, Lee Peng
Annuar, N. H. R.
Herma Dina, Setiabudi
Jalil, A. A.
Aziz, M. A. A.
author_facet Azmi, A. A.
Ngadi, Norzita
Kamaruddin, M. J.
Zakaria, Z. Y.
Teh, Lee Peng
Annuar, N. H. R.
Herma Dina, Setiabudi
Jalil, A. A.
Aziz, M. A. A.
author_sort Azmi, A. A.
collection UMP
description The capture and storage of CO2 have been suggested as an effective strategy to reduce the global emissions of greenhouse gases. Hence, many studies have been carried out to develop highly efficient materials for capturing CO2. Herein, the CO2 capture performance of mesoporous ceria nanoparticle (MCN) was described. The MCN was synthesized under mild conditions through a sol-gel method using hexadecyltrimethylammonium bromide (CTAB) as a surfactant and further undergone a calcination process at 673 K for 3 h. The prepared MCN possess high surface area (76.0 m2 g -1 ) which is around 9-fold higher than that of commercial CeO2 (8.7 m2 g -1 ), indicating that the organic modification using CTAB is an effective way of preparing a porous structure. The MCN exhibited high CO2 uptake of 213.8 μmol g -1 at 298 K and 1 bar. The prepared MCN using sol gel has shown a rapid and cost-effective method compared to the hydrothermal method.
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spelling UMPir249722019-10-14T04:38:01Z http://umpir.ump.edu.my/id/eprint/24972/ Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture Azmi, A. A. Ngadi, Norzita Kamaruddin, M. J. Zakaria, Z. Y. Teh, Lee Peng Annuar, N. H. R. Herma Dina, Setiabudi Jalil, A. A. Aziz, M. A. A. TP Chemical technology The capture and storage of CO2 have been suggested as an effective strategy to reduce the global emissions of greenhouse gases. Hence, many studies have been carried out to develop highly efficient materials for capturing CO2. Herein, the CO2 capture performance of mesoporous ceria nanoparticle (MCN) was described. The MCN was synthesized under mild conditions through a sol-gel method using hexadecyltrimethylammonium bromide (CTAB) as a surfactant and further undergone a calcination process at 673 K for 3 h. The prepared MCN possess high surface area (76.0 m2 g -1 ) which is around 9-fold higher than that of commercial CeO2 (8.7 m2 g -1 ), indicating that the organic modification using CTAB is an effective way of preparing a porous structure. The MCN exhibited high CO2 uptake of 213.8 μmol g -1 at 298 K and 1 bar. The prepared MCN using sol gel has shown a rapid and cost-effective method compared to the hydrothermal method. AIDIC 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/24972/1/Rapid%20one%20pot%20synthesis%20of%20mesoporous%20ceria%20nanoparticles%20.pdf Azmi, A. A. and Ngadi, Norzita and Kamaruddin, M. J. and Zakaria, Z. Y. and Teh, Lee Peng and Annuar, N. H. R. and Herma Dina, Setiabudi and Jalil, A. A. and Aziz, M. A. A. (2019) Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture. Chemical Engineering Transactions, 72. pp. 403-408. ISSN 2283-9216. (Published) https://doi.org/10.3303/CET1972068 https://doi.org/10.3303/CET1972068
spellingShingle TP Chemical technology
Azmi, A. A.
Ngadi, Norzita
Kamaruddin, M. J.
Zakaria, Z. Y.
Teh, Lee Peng
Annuar, N. H. R.
Herma Dina, Setiabudi
Jalil, A. A.
Aziz, M. A. A.
Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture
title Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture
title_full Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture
title_fullStr Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture
title_full_unstemmed Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture
title_short Rapid one pot synthesis of mesoporous ceria nanoparticles by sol-gel method for enhanced CO2 capture
title_sort rapid one pot synthesis of mesoporous ceria nanoparticles by sol gel method for enhanced co2 capture
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/24972/1/Rapid%20one%20pot%20synthesis%20of%20mesoporous%20ceria%20nanoparticles%20.pdf
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