Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source

Integrated perovskite solar capacitor (IPSC) systems are the new paradigm for power generation and storage. Herein, a novel configuration and combination of materials for an IPSC, theoretically affording a maximized areal capacitance of 2.35 mF cm−2 and exceeding a 25% overall photo-chemical-electri...

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Main Authors: Farhadi, Bita, Marriam, Ifra, Yang, Shengyuan, Zhang, Hui, Tebyetekerwa, Mike, Zhu, Meifang, Ramakrishna, Seeram, Rajan, Jose, Zabihi, Fatemeh
Formato: Artigo
Idioma:English
Publicado: Elsevier Ltd 2019
Subjects:
Acceso en liña:http://umpir.ump.edu.my/id/eprint/25320/1/Highly%20efficient%20photovoltaic%20energy%20storage%20hybrid%20system%20based%20.pdf
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author Farhadi, Bita
Marriam, Ifra
Yang, Shengyuan
Zhang, Hui
Tebyetekerwa, Mike
Zhu, Meifang
Ramakrishna, Seeram
Rajan, Jose
Zabihi, Fatemeh
author_facet Farhadi, Bita
Marriam, Ifra
Yang, Shengyuan
Zhang, Hui
Tebyetekerwa, Mike
Zhu, Meifang
Ramakrishna, Seeram
Rajan, Jose
Zabihi, Fatemeh
author_sort Farhadi, Bita
collection UMP
description Integrated perovskite solar capacitor (IPSC) systems are the new paradigm for power generation and storage. Herein, a novel configuration and combination of materials for an IPSC, theoretically affording a maximized areal capacitance of 2.35 mF cm−2 and exceeding a 25% overall photo-chemical-electricity energy conversion efficiency is reported. A ∼1 μm solid-state photocapacitor is suggested based on a CH3NH3PbI3 photoactive layer, inorganic buffer junctions, an ultrathin nanocarbon border and top electrodes. For the first time, bulk and interfacial imperfections in the perovskite layer are reckoned in simulation, realizing the recombination rate to 14-order of magnitude higher than that in the perfect perovskite structure. The simulation considers the band gap energy, the valance and conduction bands, carrier mobility and carrier density of every individual layer of the designed IPSC. Overall, the results for the areal capacitance, output voltage and photocharging efficiency under various illumination conditions, frequencies and dielectric materials show that the performance of the perovskite power pack is mildly susceptible to external and internal triggers. This ultrathin and sturdy architecture, shows promise for use in self-powered portable and wearable personal devices.
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spelling UMPir253202019-10-25T02:49:15Z http://umpir.ump.edu.my/id/eprint/25320/ Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source Farhadi, Bita Marriam, Ifra Yang, Shengyuan Zhang, Hui Tebyetekerwa, Mike Zhu, Meifang Ramakrishna, Seeram Rajan, Jose Zabihi, Fatemeh TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology Integrated perovskite solar capacitor (IPSC) systems are the new paradigm for power generation and storage. Herein, a novel configuration and combination of materials for an IPSC, theoretically affording a maximized areal capacitance of 2.35 mF cm−2 and exceeding a 25% overall photo-chemical-electricity energy conversion efficiency is reported. A ∼1 μm solid-state photocapacitor is suggested based on a CH3NH3PbI3 photoactive layer, inorganic buffer junctions, an ultrathin nanocarbon border and top electrodes. For the first time, bulk and interfacial imperfections in the perovskite layer are reckoned in simulation, realizing the recombination rate to 14-order of magnitude higher than that in the perfect perovskite structure. The simulation considers the band gap energy, the valance and conduction bands, carrier mobility and carrier density of every individual layer of the designed IPSC. Overall, the results for the areal capacitance, output voltage and photocharging efficiency under various illumination conditions, frequencies and dielectric materials show that the performance of the perovskite power pack is mildly susceptible to external and internal triggers. This ultrathin and sturdy architecture, shows promise for use in self-powered portable and wearable personal devices. Elsevier Ltd 2019-05-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25320/1/Highly%20efficient%20photovoltaic%20energy%20storage%20hybrid%20system%20based%20.pdf Farhadi, Bita and Marriam, Ifra and Yang, Shengyuan and Zhang, Hui and Tebyetekerwa, Mike and Zhu, Meifang and Ramakrishna, Seeram and Rajan, Jose and Zabihi, Fatemeh (2019) Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source. Journal of Power Sources, 422. pp. 196-207. ISSN 0378-7753 (Print), 1873-2755 (Online). (Published) https://doi.org/10.1016/j.jpowsour.2019.02.091 https://doi.org/10.1016/j.jpowsour.2019.02.091
spellingShingle TK Electrical engineering. Electronics Nuclear engineering
TP Chemical technology
Farhadi, Bita
Marriam, Ifra
Yang, Shengyuan
Zhang, Hui
Tebyetekerwa, Mike
Zhu, Meifang
Ramakrishna, Seeram
Rajan, Jose
Zabihi, Fatemeh
Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
title Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
title_full Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
title_fullStr Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
title_full_unstemmed Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
title_short Highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
title_sort highly efficient photovoltaic energy storage hybrid system based on ultrathin carbon electrodes designed for a portable and flexible power source
topic TK Electrical engineering. Electronics Nuclear engineering
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/25320/1/Highly%20efficient%20photovoltaic%20energy%20storage%20hybrid%20system%20based%20.pdf
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