Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings

A series of spherical mesoporous Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) catalysts with different Ni loadings (3-15 wt.%) were successfully synthesized and catalytically investigated by methane dry reforming. The XRD and Raman analyses indicated the structural stability of DFSBA-15 regardless of t...

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Main Authors: Chong, C. C., Bukhari, S. N., Cheng, Y. W., Setiabudi, H. D., Jalil, A. A., Phalakornkule, C.
Format: Article
Language:English
English
Published: Elsevier 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/25765/1/Robust%20NiDendritic%20Fibrous%20SBA-15.pdf
http://umpir.ump.edu.my/id/eprint/25765/2/Robust%20NiDendritic%20fibrous%20SBA-151.pdf
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author Chong, C. C.
Bukhari, S. N.
Cheng, Y. W.
Setiabudi, H. D.
Jalil, A. A.
Phalakornkule, C.
author_facet Chong, C. C.
Bukhari, S. N.
Cheng, Y. W.
Setiabudi, H. D.
Jalil, A. A.
Phalakornkule, C.
author_sort Chong, C. C.
collection UMP
description A series of spherical mesoporous Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) catalysts with different Ni loadings (3-15 wt.%) were successfully synthesized and catalytically investigated by methane dry reforming. The XRD and Raman analyses indicated the structural stability of DFSBA-15 regardless of the Ni loading quantity, and the NiO nanocrystalline size increased with increasing Ni loading. The BET analysis showed the surface area of the catalysts decreased upon increment in Ni loading. Meanwhile, the TEM images revealed the distribution of Ni particles over the spherical shape DFSBA-15, with the most homogeneous dispersion was shown by 10Ni/DFSBA15, while Ni agglomeration was observed for 15Ni/DFSBA-15. The optimal catalytic performance and stability was achieved by 10Ni/DFSBA-15 (
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spelling UMPir257652019-11-07T04:39:47Z http://umpir.ump.edu.my/id/eprint/25765/ Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings Chong, C. C. Bukhari, S. N. Cheng, Y. W. Setiabudi, H. D. Jalil, A. A. Phalakornkule, C. TP Chemical technology A series of spherical mesoporous Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) catalysts with different Ni loadings (3-15 wt.%) were successfully synthesized and catalytically investigated by methane dry reforming. The XRD and Raman analyses indicated the structural stability of DFSBA-15 regardless of the Ni loading quantity, and the NiO nanocrystalline size increased with increasing Ni loading. The BET analysis showed the surface area of the catalysts decreased upon increment in Ni loading. Meanwhile, the TEM images revealed the distribution of Ni particles over the spherical shape DFSBA-15, with the most homogeneous dispersion was shown by 10Ni/DFSBA15, while Ni agglomeration was observed for 15Ni/DFSBA-15. The optimal catalytic performance and stability was achieved by 10Ni/DFSBA-15 ( Elsevier 2019 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/25765/1/Robust%20NiDendritic%20Fibrous%20SBA-15.pdf pdf en http://umpir.ump.edu.my/id/eprint/25765/2/Robust%20NiDendritic%20fibrous%20SBA-151.pdf Chong, C. C. and Bukhari, S. N. and Cheng, Y. W. and Setiabudi, H. D. and Jalil, A. A. and Phalakornkule, C. (2019) Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings. Applied Catalysis A: General, 584 (117174). pp. 1-13. ISSN 0926-860X. (Published) https://doi.org/10.1016/j.apcata.2019.117174 https://doi.org/10.1016/j.apcata.2019.117174
spellingShingle TP Chemical technology
Chong, C. C.
Bukhari, S. N.
Cheng, Y. W.
Setiabudi, H. D.
Jalil, A. A.
Phalakornkule, C.
Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings
title Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings
title_full Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings
title_fullStr Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings
title_full_unstemmed Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings
title_short Robust Ni/Dendritic Fibrous SBA-15 (Ni/DFSBA-15) For Methane Dry Reforming: Effect of Ni Loadings
title_sort robust ni dendritic fibrous sba 15 ni dfsba 15 for methane dry reforming effect of ni loadings
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/25765/1/Robust%20NiDendritic%20Fibrous%20SBA-15.pdf
http://umpir.ump.edu.my/id/eprint/25765/2/Robust%20NiDendritic%20fibrous%20SBA-151.pdf
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