Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons

Discharge of nonsteroidal anti-inflammatory drugs (NSAIDs) from wastewater has been increasingly alarmed, led to the advent of the treatment techniques. Among these methods, adsorption is regarded as a tunable and green approach with the utilization of mesoporous carbon (MC) as an efficient and recy...

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Main Authors: Van Tran, Thuan, Nguyen, Duyen Thi Cam, Le, Hanh T. N., Bach, Long Giang, Vo, Dai-Viet N., Dao, To-Uyen T., Lim, Kwon Taek, Nguyen, Trinh Duy
Format: Article
Language:English
Published: Elsevier Ltd 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/26499/1/Effect%20of%20thermolysis%20condition%20on%20characteristics%20and%20nonsteroidal.pdf
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author Van Tran, Thuan
Nguyen, Duyen Thi Cam
Le, Hanh T. N.
Bach, Long Giang
Vo, Dai-Viet N.
Dao, To-Uyen T.
Lim, Kwon Taek
Nguyen, Trinh Duy
author_facet Van Tran, Thuan
Nguyen, Duyen Thi Cam
Le, Hanh T. N.
Bach, Long Giang
Vo, Dai-Viet N.
Dao, To-Uyen T.
Lim, Kwon Taek
Nguyen, Trinh Duy
author_sort Van Tran, Thuan
collection UMP
description Discharge of nonsteroidal anti-inflammatory drugs (NSAIDs) from wastewater has been increasingly alarmed, led to the advent of the treatment techniques. Among these methods, adsorption is regarded as a tunable and green approach with the utilization of mesoporous carbon (MC) as an efficient and recyclable adsorbent. Herein, we described the strategy for the synthesis of novel MC from Fe-MIL-88B as a self-sacrificial template. Three thermolysis temperatures (550, 750, and 950 °C) were investigated to compare the structural characteristics and absorbability towards selected NSAIDs compounds including diclofenac sodium (DCF), aspirin (APR), and ibuprofen (IBU). Effect of contact time (0–480 min), concentration (10–40 mg/L), pH (2–10), and MC dosage (0.1–0.5 g/L) was systematically studied. Kinetic and isotherm models were also used to find out the adsorption mechanism and behavior of NSAIDs pharmaceutical over MC materials. Proposed mechanism and recyclability test were rigorously studied to gain more insight into how the NSAIDs molecules adsorb on the MC materials and their potential towards drug treatment.
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spelling UMPir264992019-12-09T07:32:35Z http://umpir.ump.edu.my/id/eprint/26499/ Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons Van Tran, Thuan Nguyen, Duyen Thi Cam Le, Hanh T. N. Bach, Long Giang Vo, Dai-Viet N. Dao, To-Uyen T. Lim, Kwon Taek Nguyen, Trinh Duy QD Chemistry RM Therapeutics. Pharmacology TP Chemical technology Discharge of nonsteroidal anti-inflammatory drugs (NSAIDs) from wastewater has been increasingly alarmed, led to the advent of the treatment techniques. Among these methods, adsorption is regarded as a tunable and green approach with the utilization of mesoporous carbon (MC) as an efficient and recyclable adsorbent. Herein, we described the strategy for the synthesis of novel MC from Fe-MIL-88B as a self-sacrificial template. Three thermolysis temperatures (550, 750, and 950 °C) were investigated to compare the structural characteristics and absorbability towards selected NSAIDs compounds including diclofenac sodium (DCF), aspirin (APR), and ibuprofen (IBU). Effect of contact time (0–480 min), concentration (10–40 mg/L), pH (2–10), and MC dosage (0.1–0.5 g/L) was systematically studied. Kinetic and isotherm models were also used to find out the adsorption mechanism and behavior of NSAIDs pharmaceutical over MC materials. Proposed mechanism and recyclability test were rigorously studied to gain more insight into how the NSAIDs molecules adsorb on the MC materials and their potential towards drug treatment. Elsevier Ltd 2019-10 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26499/1/Effect%20of%20thermolysis%20condition%20on%20characteristics%20and%20nonsteroidal.pdf Van Tran, Thuan and Nguyen, Duyen Thi Cam and Le, Hanh T. N. and Bach, Long Giang and Vo, Dai-Viet N. and Dao, To-Uyen T. and Lim, Kwon Taek and Nguyen, Trinh Duy (2019) Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons. Journal of Environmental Chemical Engineering, 7 (5). pp. 1-2. ISSN 2213-3437. (Published) https://doi.org/10.1016/j.jece.2019.103356 https://doi.org/10.1016/j.jece.2019.103356
spellingShingle QD Chemistry
RM Therapeutics. Pharmacology
TP Chemical technology
Van Tran, Thuan
Nguyen, Duyen Thi Cam
Le, Hanh T. N.
Bach, Long Giang
Vo, Dai-Viet N.
Dao, To-Uyen T.
Lim, Kwon Taek
Nguyen, Trinh Duy
Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons
title Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons
title_full Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons
title_fullStr Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons
title_full_unstemmed Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons
title_short Effect of thermolysis condition on characteristics and nonsteroidal anti-inflammatory drugs (NSAIDs) absorbability of Fe-MIL-88B-derived mesoporous carbons
title_sort effect of thermolysis condition on characteristics and nonsteroidal anti inflammatory drugs nsaids absorbability of fe mil 88b derived mesoporous carbons
topic QD Chemistry
RM Therapeutics. Pharmacology
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/26499/1/Effect%20of%20thermolysis%20condition%20on%20characteristics%20and%20nonsteroidal.pdf
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