Potential solvent for reconditioning polyolefin waste materials

Waste polymer reconditioning was examined by a method of dissolution/reprecipitation on low- and high-density polyethylene (PE) and polypropylene (PP). Toluene and petroleum ether, in different proportions, were used as solvents, and n-hexane was used as a non-solvent. Commercial polymer products us...

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Main Authors: J. Hadiab, Arkan, Ghazi Faisal, Najmuldeen, Iqbal, AKM Asif
Format: Article
Language:English
Published: Walter de Gruyter GmbH 2012
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/26895/1/Potential%20solvent%20for%20reconditioning%20polyolefin%20waste%20materials.pdf
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author J. Hadiab, Arkan
Ghazi Faisal, Najmuldeen
Iqbal, AKM Asif
author_facet J. Hadiab, Arkan
Ghazi Faisal, Najmuldeen
Iqbal, AKM Asif
author_sort J. Hadiab, Arkan
collection UMP
description Waste polymer reconditioning was examined by a method of dissolution/reprecipitation on low- and high-density polyethylene (PE) and polypropylene (PP). Toluene and petroleum ether, in different proportions, were used as solvents, and n-hexane was used as a non-solvent. Commercial polymer products used on an everyday basis were used with a virgin polymer, to optimize the qualities of the final product, and 98% polymer was recovered in each case. Fourier transform infrared spectroscopy (FTIR) images and tensile mechanical properties of the samples, before and after recycling, were analyzed. The potential recycling-based degradation of the polymer was further investigated by measuring the thermal properties (melting point and crystallinity) before and after recycling, using differential scanning calorimetry (DSC). High reconditioning was observed in most recycled samples, with no significant difference from the virgin materials. The studied technique seems to be viable for waste polyolefin polymer recycling.
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spelling UMPir268952020-02-26T08:12:43Z http://umpir.ump.edu.my/id/eprint/26895/ Potential solvent for reconditioning polyolefin waste materials J. Hadiab, Arkan Ghazi Faisal, Najmuldeen Iqbal, AKM Asif TP Chemical technology Waste polymer reconditioning was examined by a method of dissolution/reprecipitation on low- and high-density polyethylene (PE) and polypropylene (PP). Toluene and petroleum ether, in different proportions, were used as solvents, and n-hexane was used as a non-solvent. Commercial polymer products used on an everyday basis were used with a virgin polymer, to optimize the qualities of the final product, and 98% polymer was recovered in each case. Fourier transform infrared spectroscopy (FTIR) images and tensile mechanical properties of the samples, before and after recycling, were analyzed. The potential recycling-based degradation of the polymer was further investigated by measuring the thermal properties (melting point and crystallinity) before and after recycling, using differential scanning calorimetry (DSC). High reconditioning was observed in most recycled samples, with no significant difference from the virgin materials. The studied technique seems to be viable for waste polyolefin polymer recycling. Walter de Gruyter GmbH 2012 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26895/1/Potential%20solvent%20for%20reconditioning%20polyolefin%20waste%20materials.pdf J. Hadiab, Arkan and Ghazi Faisal, Najmuldeen and Iqbal, AKM Asif (2012) Potential solvent for reconditioning polyolefin waste materials. Journal of Polymer Engineering, 32 (8-9). pp. 585-591. ISSN 2191-0340. (Published) https://doi.org/10.1515/polyeng-2012-0081 https://doi.org/10.1515/polyeng-2012-0081
spellingShingle TP Chemical technology
J. Hadiab, Arkan
Ghazi Faisal, Najmuldeen
Iqbal, AKM Asif
Potential solvent for reconditioning polyolefin waste materials
title Potential solvent for reconditioning polyolefin waste materials
title_full Potential solvent for reconditioning polyolefin waste materials
title_fullStr Potential solvent for reconditioning polyolefin waste materials
title_full_unstemmed Potential solvent for reconditioning polyolefin waste materials
title_short Potential solvent for reconditioning polyolefin waste materials
title_sort potential solvent for reconditioning polyolefin waste materials
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/26895/1/Potential%20solvent%20for%20reconditioning%20polyolefin%20waste%20materials.pdf
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