Cycloolefin Polymerization

Highly active metallocenes and other single-site catalysts as well as Grubbs and Schrock metathesis systems have opened up the possibility to polymerize cycloolefins or to copolymerize them with ethene or propene. The polymers obtained show exciting structures and properties. The cycloolefins such a...

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Main Authors: Kaminsky, Walter, Boggioni, Laura, Tritto, Incoronata, S. N., Aqida
Format: Book Chapter
Language:English
Published: Elsevier Ltd 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/26915/1/Cycloolefin%20Polymerization1.pdf
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author Kaminsky, Walter
Boggioni, Laura
Tritto, Incoronata
S. N., Aqida
author_facet Kaminsky, Walter
Boggioni, Laura
Tritto, Incoronata
S. N., Aqida
author_sort Kaminsky, Walter
collection UMP
description Highly active metallocenes and other single-site catalysts as well as Grubbs and Schrock metathesis systems have opened up the possibility to polymerize cycloolefins or to copolymerize them with ethene or propene. The polymers obtained show exciting structures and properties. The cycloolefins such as cyclopentene, cyclooctene, norbornene, and their substituted compounds are incorporated into the polymer chain either by double bond or by ring-opening metathesis polymerization (ROMP). Materials with elastomeric properties or tactic polymers with high glass transitions and melting points are obtained depending on the wide range of different microstructures. Cycloolefin copolymers (COCs) and other homo- and copolymers of norbornene are of great academic and industrial interest because of their properties and applications in optoelectronics, lenses, and coating.
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spelling UMPir269152019-12-16T02:41:54Z http://umpir.ump.edu.my/id/eprint/26915/ Cycloolefin Polymerization Kaminsky, Walter Boggioni, Laura Tritto, Incoronata S. N., Aqida QD Chemistry Highly active metallocenes and other single-site catalysts as well as Grubbs and Schrock metathesis systems have opened up the possibility to polymerize cycloolefins or to copolymerize them with ethene or propene. The polymers obtained show exciting structures and properties. The cycloolefins such as cyclopentene, cyclooctene, norbornene, and their substituted compounds are incorporated into the polymer chain either by double bond or by ring-opening metathesis polymerization (ROMP). Materials with elastomeric properties or tactic polymers with high glass transitions and melting points are obtained depending on the wide range of different microstructures. Cycloolefin copolymers (COCs) and other homo- and copolymers of norbornene are of great academic and industrial interest because of their properties and applications in optoelectronics, lenses, and coating. Elsevier Ltd 2019 Book Chapter PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/26915/1/Cycloolefin%20Polymerization1.pdf Kaminsky, Walter and Boggioni, Laura and Tritto, Incoronata and S. N., Aqida (2019) Cycloolefin Polymerization. In: Reference Module in Materials Science and Materials Engineering. Elsevier Ltd, Netherlands, pp. 843-873. ISBN 978-0-12-803581-8 https://doi.org/10.1016/B978-0-12-803581-8.11675-3 https://doi.org/10.1016/B978-0-12-803581-8.11675-3
spellingShingle QD Chemistry
Kaminsky, Walter
Boggioni, Laura
Tritto, Incoronata
S. N., Aqida
Cycloolefin Polymerization
title Cycloolefin Polymerization
title_full Cycloolefin Polymerization
title_fullStr Cycloolefin Polymerization
title_full_unstemmed Cycloolefin Polymerization
title_short Cycloolefin Polymerization
title_sort cycloolefin polymerization
topic QD Chemistry
url http://umpir.ump.edu.my/id/eprint/26915/1/Cycloolefin%20Polymerization1.pdf
work_keys_str_mv AT kaminskywalter cycloolefinpolymerization
AT boggionilaura cycloolefinpolymerization
AT trittoincoronata cycloolefinpolymerization
AT snaqida cycloolefinpolymerization