Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts
Ethylene glycol dry reforming (EGDR) was investigated for the first time on 10% Co/Al2O3 and 3% Ce–10% Co/Al2O3 catalysts at stoichiometric feed composition under atmospheric pressure and 923–998 K for syngas production. Catalysts were characterized using BET, H2-TPR, XRD and Raman spectroscopy meas...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Springer International Publishing
2018
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/27560/1/Jun2018_Article_EthyleneGlycolDryReformingForS.pdf |
| _version_ | 1796993899667914752 |
|---|---|
| author | Lau, N. Jun Mahadi, Bahari Pham, T. T. Phuong Nguyen, Huu Huy Phuc Chanatip, Samart Bawadi, Abdullah Setiabudi, H. D. Vo, Dai-Viet N. |
| author_facet | Lau, N. Jun Mahadi, Bahari Pham, T. T. Phuong Nguyen, Huu Huy Phuc Chanatip, Samart Bawadi, Abdullah Setiabudi, H. D. Vo, Dai-Viet N. |
| author_sort | Lau, N. Jun |
| collection | UMP |
| description | Ethylene glycol dry reforming (EGDR) was investigated for the first time on 10% Co/Al2O3 and 3% Ce–10% Co/Al2O3 catalysts at stoichiometric feed composition under atmospheric pressure and 923–998 K for syngas production. Catalysts were characterized using BET, H2-TPR, XRD and Raman spectroscopy measurements. The addition of Ce promoter eased the reduction of Co3O4 with lower reduction temperature and enhanced metal dispersion. Ce promotion also improved EGDR performance by increasing reactant conversions, syngas yields and reducing undesirable methane formation. The conversion of ethylene glycol and H2 yield reached up to 71.7% and 69.3%, respectively. |
| first_indexed | 2024-03-06T12:40:21Z |
| format | Article |
| id | UMPir27560 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:40:21Z |
| publishDate | 2018 |
| publisher | Springer International Publishing |
| record_format | dspace |
| spelling | UMPir275602020-01-29T01:16:37Z http://umpir.ump.edu.my/id/eprint/27560/ Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts Lau, N. Jun Mahadi, Bahari Pham, T. T. Phuong Nguyen, Huu Huy Phuc Chanatip, Samart Bawadi, Abdullah Setiabudi, H. D. Vo, Dai-Viet N. TA Engineering (General). Civil engineering (General) Ethylene glycol dry reforming (EGDR) was investigated for the first time on 10% Co/Al2O3 and 3% Ce–10% Co/Al2O3 catalysts at stoichiometric feed composition under atmospheric pressure and 923–998 K for syngas production. Catalysts were characterized using BET, H2-TPR, XRD and Raman spectroscopy measurements. The addition of Ce promoter eased the reduction of Co3O4 with lower reduction temperature and enhanced metal dispersion. Ce promotion also improved EGDR performance by increasing reactant conversions, syngas yields and reducing undesirable methane formation. The conversion of ethylene glycol and H2 yield reached up to 71.7% and 69.3%, respectively. Springer International Publishing 2018 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/27560/1/Jun2018_Article_EthyleneGlycolDryReformingForS.pdf Lau, N. Jun and Mahadi, Bahari and Pham, T. T. Phuong and Nguyen, Huu Huy Phuc and Chanatip, Samart and Bawadi, Abdullah and Setiabudi, H. D. and Vo, Dai-Viet N. (2018) Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts. Applied Petrochemical Research, 8 (4). pp. 253-261. ISSN 2190-5533. (Published) https://doi.org/10.1007/s13203-018-0223-8 https://doi.org/10.1007/s13203-018-0223-8 |
| spellingShingle | TA Engineering (General). Civil engineering (General) Lau, N. Jun Mahadi, Bahari Pham, T. T. Phuong Nguyen, Huu Huy Phuc Chanatip, Samart Bawadi, Abdullah Setiabudi, H. D. Vo, Dai-Viet N. Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts |
| title | Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts |
| title_full | Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts |
| title_fullStr | Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts |
| title_full_unstemmed | Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts |
| title_short | Ethylene glycol dry reforming for syngas generation on Ce‑promoted Co/Al2O3 catalysts |
| title_sort | ethylene glycol dry reforming for syngas generation on ce promoted co al2o3 catalysts |
| topic | TA Engineering (General). Civil engineering (General) |
| url | http://umpir.ump.edu.my/id/eprint/27560/1/Jun2018_Article_EthyleneGlycolDryReformingForS.pdf |
| work_keys_str_mv | AT launjun ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT mahadibahari ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT phamttphuong ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT nguyenhuuhuyphuc ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT chanatipsamart ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT bawadiabdullah ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT setiabudihd ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts AT vodaivietn ethyleneglycoldryreformingforsyngasgenerationoncepromotedcoal2o3catalysts |