Cyclopentane hydrate slurry viscosity measurements coupled with visualization

One of the advanced strategies in hydrate plug prevention is to obtain an in-depth knowledge of the rheological properties of hydrate slurries. A major challenge in hydrate rheological measurements is that the viscosity profile can be difficult to attribute to physical phenomena, such as particle ag...

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Main Authors: Majid, Ahmad A. A., Tanner, Braeden, Koh, Carolyn A.
Format: Article
Language:English
Published: Taylor and Francis Ltd. 2019
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/27801/1/Cyclopentane%20hydrate%20slurry%20viscosity%20measurements%20coupled%20with%20visualization.pdf
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author Majid, Ahmad A. A.
Tanner, Braeden
Koh, Carolyn A.
author_facet Majid, Ahmad A. A.
Tanner, Braeden
Koh, Carolyn A.
author_sort Majid, Ahmad A. A.
collection UMP
description One of the advanced strategies in hydrate plug prevention is to obtain an in-depth knowledge of the rheological properties of hydrate slurries. A major challenge in hydrate rheological measurements is that the viscosity profile can be difficult to attribute to physical phenomena, such as particle agglomerate breakup, particle bedding/settling and wall growth. In this work, a novel visual rheometer has been developed to help overcome these previous limitations by enabling the visualisation of the evolution of cyclopentane hydrate slurries during viscosity measurements. Two different model systems were used in this investigation: (1) non-emulsified and (2) emulsified systems. The physical phenomena, including initial hydrate formation, hydrate wall growth, bedding and sloughing were visually observed and directly correlated to the corresponding viscosity profile. For the non-emulsified system, there are four different stages of hydrate slurry development including initial hydrate formation, wall adhesion and growth and sloughing that caused changes in the viscosity profiles. Large fluctuations in the viscosity profile for a non-emulsified system were found to be the result of a sloughing phenomenon. On the other hand, the emulsified system showed a well-dispersed hydrate slurry with minimal wall and impeller growth, corresponding to a smooth viscosity profile.
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spelling UMPir278012021-01-18T04:56:25Z http://umpir.ump.edu.my/id/eprint/27801/ Cyclopentane hydrate slurry viscosity measurements coupled with visualization Majid, Ahmad A. A. Tanner, Braeden Koh, Carolyn A. TP Chemical technology One of the advanced strategies in hydrate plug prevention is to obtain an in-depth knowledge of the rheological properties of hydrate slurries. A major challenge in hydrate rheological measurements is that the viscosity profile can be difficult to attribute to physical phenomena, such as particle agglomerate breakup, particle bedding/settling and wall growth. In this work, a novel visual rheometer has been developed to help overcome these previous limitations by enabling the visualisation of the evolution of cyclopentane hydrate slurries during viscosity measurements. Two different model systems were used in this investigation: (1) non-emulsified and (2) emulsified systems. The physical phenomena, including initial hydrate formation, hydrate wall growth, bedding and sloughing were visually observed and directly correlated to the corresponding viscosity profile. For the non-emulsified system, there are four different stages of hydrate slurry development including initial hydrate formation, wall adhesion and growth and sloughing that caused changes in the viscosity profiles. Large fluctuations in the viscosity profile for a non-emulsified system were found to be the result of a sloughing phenomenon. On the other hand, the emulsified system showed a well-dispersed hydrate slurry with minimal wall and impeller growth, corresponding to a smooth viscosity profile. Taylor and Francis Ltd. 2019-12-17 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/27801/1/Cyclopentane%20hydrate%20slurry%20viscosity%20measurements%20coupled%20with%20visualization.pdf Majid, Ahmad A. A. and Tanner, Braeden and Koh, Carolyn A. (2019) Cyclopentane hydrate slurry viscosity measurements coupled with visualization. Molecular Physics, 117 (23-24). pp. 3860-3870. ISSN 0026-8976. (Published) https://doi.org/10.1080/00268976.2019.1670877 https://doi.org/10.1080/00268976.2019.1670877
spellingShingle TP Chemical technology
Majid, Ahmad A. A.
Tanner, Braeden
Koh, Carolyn A.
Cyclopentane hydrate slurry viscosity measurements coupled with visualization
title Cyclopentane hydrate slurry viscosity measurements coupled with visualization
title_full Cyclopentane hydrate slurry viscosity measurements coupled with visualization
title_fullStr Cyclopentane hydrate slurry viscosity measurements coupled with visualization
title_full_unstemmed Cyclopentane hydrate slurry viscosity measurements coupled with visualization
title_short Cyclopentane hydrate slurry viscosity measurements coupled with visualization
title_sort cyclopentane hydrate slurry viscosity measurements coupled with visualization
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/27801/1/Cyclopentane%20hydrate%20slurry%20viscosity%20measurements%20coupled%20with%20visualization.pdf
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AT kohcarolyna cyclopentanehydrateslurryviscositymeasurementscoupledwithvisualization