Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin
Micro sized carbonaceous materials were synthesized by pyrolysis of rubber wood fibers and their dispersion in urea formaldehyde (UF) was investigated. The carbonaceous material reinforced in UF has been prepared with a weight concentration up to 5%. The uniform dispersion of the carbonaceous materi...
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| Format: | Article |
| Language: | English |
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Elsevier
2020
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| Online Access: | http://umpir.ump.edu.my/id/eprint/28464/2/Synthesis%20of%20micro%20carbonaceous%20material%20by%20pyrolysis%20.pdf |
| _version_ | 1825813359181692928 |
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| author | Khan, Tanveer Ahmed Gupta, Arun Jamari, Saidatul Shima Mohammed, Nasir Jang, Seounguk Kim, Hyun-Joong Asim, M. |
| author_facet | Khan, Tanveer Ahmed Gupta, Arun Jamari, Saidatul Shima Mohammed, Nasir Jang, Seounguk Kim, Hyun-Joong Asim, M. |
| author_sort | Khan, Tanveer Ahmed |
| collection | UMP |
| description | Micro sized carbonaceous materials were synthesized by pyrolysis of rubber wood fibers and their dispersion in urea formaldehyde (UF) was investigated. The carbonaceous material reinforced in UF has been prepared with a weight concentration up to 5%. The uniform dispersion of the carbonaceous material in the UF was achieved by mechanical stirring. All resin hybrids were characterized by solution rheology, Fourier transform infrared spectroscopy (FTIR) and powder X-ray diffractometry (XRD) while the dispersion of carbonaceous materials was analyzed by scanning electron microscopy (SEM). FTIR spectroscopy results showed that carbonaceous materials can make hydrogen bonds with UF resins. The X-ray-based measurement of the crystallinity index (CrI) indicated that carbonaceous material increased the crystallinity of UF resin, whereas the maximum value of CrI was observed at UF-1 i.e., 85.7%. Curing reactions were examined with differential scanning calorimetry (DSC), and it was observed that the curing temperature of UF resin is affected by the addition of carbonaceous materials. Thermo-gravimetric analysis (TGA) revealed that carbonaceous materials have little effect on the thermal stability of the resin. Wood particleboards were fabricated and their performance was measured. The internal bonding strength and the modulus of rupture were measured for the particle boards, and a maximum at a 1% weight concentration was observed. The formaldehyde content of particle boards decreased with the addition of carbonaceous materials. At a 1% weight concentration, a maximum reduction of formaldehyde content was obtained using the perforator method. |
| first_indexed | 2024-03-06T12:42:49Z |
| format | Article |
| id | UMPir28464 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:42:49Z |
| publishDate | 2020 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | UMPir284642021-01-26T03:42:37Z http://umpir.ump.edu.my/id/eprint/28464/ Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin Khan, Tanveer Ahmed Gupta, Arun Jamari, Saidatul Shima Mohammed, Nasir Jang, Seounguk Kim, Hyun-Joong Asim, M. TP Chemical technology Micro sized carbonaceous materials were synthesized by pyrolysis of rubber wood fibers and their dispersion in urea formaldehyde (UF) was investigated. The carbonaceous material reinforced in UF has been prepared with a weight concentration up to 5%. The uniform dispersion of the carbonaceous material in the UF was achieved by mechanical stirring. All resin hybrids were characterized by solution rheology, Fourier transform infrared spectroscopy (FTIR) and powder X-ray diffractometry (XRD) while the dispersion of carbonaceous materials was analyzed by scanning electron microscopy (SEM). FTIR spectroscopy results showed that carbonaceous materials can make hydrogen bonds with UF resins. The X-ray-based measurement of the crystallinity index (CrI) indicated that carbonaceous material increased the crystallinity of UF resin, whereas the maximum value of CrI was observed at UF-1 i.e., 85.7%. Curing reactions were examined with differential scanning calorimetry (DSC), and it was observed that the curing temperature of UF resin is affected by the addition of carbonaceous materials. Thermo-gravimetric analysis (TGA) revealed that carbonaceous materials have little effect on the thermal stability of the resin. Wood particleboards were fabricated and their performance was measured. The internal bonding strength and the modulus of rupture were measured for the particle boards, and a maximum at a 1% weight concentration was observed. The formaldehyde content of particle boards decreased with the addition of carbonaceous materials. At a 1% weight concentration, a maximum reduction of formaldehyde content was obtained using the perforator method. Elsevier 2020-04-02 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28464/2/Synthesis%20of%20micro%20carbonaceous%20material%20by%20pyrolysis%20.pdf Khan, Tanveer Ahmed and Gupta, Arun and Jamari, Saidatul Shima and Mohammed, Nasir and Jang, Seounguk and Kim, Hyun-Joong and Asim, M. (2020) Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin. Chemical Engineering Journal, 394 (124900). pp. 1-8. ISSN 1385-8947. (Published) https://doi.org/10.1016/j.cej.2020.124900 https://doi.org/10.1016/j.cej.2020.124900 |
| spellingShingle | TP Chemical technology Khan, Tanveer Ahmed Gupta, Arun Jamari, Saidatul Shima Mohammed, Nasir Jang, Seounguk Kim, Hyun-Joong Asim, M. Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin |
| title | Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin |
| title_full | Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin |
| title_fullStr | Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin |
| title_full_unstemmed | Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin |
| title_short | Synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea-formaldehyde (UF) resin |
| title_sort | synthesis of micro carbonaceous material by pyrolysis of rubber wood and its effect on properties of urea formaldehyde uf resin |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/28464/2/Synthesis%20of%20micro%20carbonaceous%20material%20by%20pyrolysis%20.pdf |
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