Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes
The carboxymethyl cellulose and polyvinyl alcohol (CMC/PVA) based hybrid polymer (HPe) system with different ratio of composition have been prepared via solution casting. The features of interaction between CMC and PVA were investigated using X-ray diffraction (XRD), and infrared (IR) spectroscopy t...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English English |
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Elsevier Ltd
2019
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| Online Access: | http://umpir.ump.edu.my/id/eprint/28704/7/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC_PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/28704/8/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC_PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes_ABS.pdf |
| _version_ | 1796994124871630848 |
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| author | Saadiah, Mohd Ali Zhang, Dalun Nagao, Yuki Saifful Kamaluddin, Muzakir Ahmad Salihin, Samsudin |
| author_facet | Saadiah, Mohd Ali Zhang, Dalun Nagao, Yuki Saifful Kamaluddin, Muzakir Ahmad Salihin, Samsudin |
| author_sort | Saadiah, Mohd Ali |
| collection | UMP |
| description | The carboxymethyl cellulose and polyvinyl alcohol (CMC/PVA) based hybrid polymer (HPe) system with different ratio of composition have been prepared via solution casting. The features of interaction between CMC and PVA were investigated using X-ray diffraction (XRD), and infrared (IR) spectroscopy to disclose the reduction of crystallinity of the HPe system. Morphological properties observed by Scanning electron microscopy (SEM) confirmed the homogeneity of the HPe system. Differential scanning calorimetry (DSC) result explains the miscibility of the HPe system which was confirmed by means of variations in the glass transition temperature (Tg). Two degradation mechanisms were revealed by thermogravimetric analysis (TGA) in the HPe system attributed to the decarboxylation in CMC and degradation of bond scission in PVA backbone. The blend of 80:20 compositions of CMC/PVA HPe system was found to be the optimum ratio with an increase in conductivity of CMC/PVA by one magnitude order from 10−7 to 10−6 S/cm with the lowest in crystallinity. |
| first_indexed | 2024-03-06T12:43:28Z |
| format | Article |
| id | UMPir28704 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-03-06T12:43:28Z |
| publishDate | 2019 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | UMPir287042024-01-03T04:04:04Z http://umpir.ump.edu.my/id/eprint/28704/ Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes Saadiah, Mohd Ali Zhang, Dalun Nagao, Yuki Saifful Kamaluddin, Muzakir Ahmad Salihin, Samsudin QC Physics TD Environmental technology. Sanitary engineering TP Chemical technology The carboxymethyl cellulose and polyvinyl alcohol (CMC/PVA) based hybrid polymer (HPe) system with different ratio of composition have been prepared via solution casting. The features of interaction between CMC and PVA were investigated using X-ray diffraction (XRD), and infrared (IR) spectroscopy to disclose the reduction of crystallinity of the HPe system. Morphological properties observed by Scanning electron microscopy (SEM) confirmed the homogeneity of the HPe system. Differential scanning calorimetry (DSC) result explains the miscibility of the HPe system which was confirmed by means of variations in the glass transition temperature (Tg). Two degradation mechanisms were revealed by thermogravimetric analysis (TGA) in the HPe system attributed to the decarboxylation in CMC and degradation of bond scission in PVA backbone. The blend of 80:20 compositions of CMC/PVA HPe system was found to be the optimum ratio with an increase in conductivity of CMC/PVA by one magnitude order from 10−7 to 10−6 S/cm with the lowest in crystallinity. Elsevier Ltd 2019-03-01 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28704/7/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC_PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes.pdf pdf en http://umpir.ump.edu.my/id/eprint/28704/8/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC_PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes_ABS.pdf Saadiah, Mohd Ali and Zhang, Dalun and Nagao, Yuki and Saifful Kamaluddin, Muzakir and Ahmad Salihin, Samsudin (2019) Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes. Journal of Non-Crystalline Solids, 511. pp. 201-211. ISSN 0022-3093. (Published) https://www.journals.elsevier.com/journal-of-non-crystalline-solids https://doi.org/10.1016/j.jnoncrysol.2018.11.032 |
| spellingShingle | QC Physics TD Environmental technology. Sanitary engineering TP Chemical technology Saadiah, Mohd Ali Zhang, Dalun Nagao, Yuki Saifful Kamaluddin, Muzakir Ahmad Salihin, Samsudin Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes |
| title | Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes |
| title_full | Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes |
| title_fullStr | Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes |
| title_full_unstemmed | Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes |
| title_short | Reducing crystallinity on thin film based CMC/PVA hybrid polymer for application as a host in polymer electrolytes |
| title_sort | reducing crystallinity on thin film based cmc pva hybrid polymer for application as a host in polymer electrolytes |
| topic | QC Physics TD Environmental technology. Sanitary engineering TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/28704/7/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC_PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes.pdf http://umpir.ump.edu.my/id/eprint/28704/8/Reducing%20crystallinity%20on%20thin%20film%20based%20CMC_PVA%20hybrid%20polymer%20for%20application%20as%20a%20host%20in%20polymer%20electrolytes_ABS.pdf |
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