The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
The effect of the addition of aluminium and niobium, and processing conditions, including cooling rate and rolling condition, on the corrosion behaviour of HSLA steel in 10 wt% sulphuric acid environment has been investigated. The experimental procedures included electrochemical corrosion techniques...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2020
|
Subjects: | |
Online Access: | http://umpir.ump.edu.my/id/eprint/28735/2/The%20effect%20of%20Al%20and%20Nb%20contents%2C%20cooling%20rate%20and%20rolling.pdf |
_version_ | 1796994129917378560 |
---|---|
author | Qaban, Abdullah Mohmed, Tasneem M. M., Quazi Naher, Sumsun |
author_facet | Qaban, Abdullah Mohmed, Tasneem M. M., Quazi Naher, Sumsun |
author_sort | Qaban, Abdullah |
collection | UMP |
description | The effect of the addition of aluminium and niobium, and processing conditions, including cooling rate and rolling condition, on the corrosion behaviour of HSLA steel in 10 wt% sulphuric acid environment has been investigated. The experimental procedures included electrochemical corrosion techniques using potentiodynamic and electrochemical impedance spectroscopy, as well as weight loss method. The microstructure was examined using optical and scanning electron microscopes in order to investigate the effect of the microstructural features on the corrosion behaviour. Surface films were evaluated by X-ray photoelectron spectroscopy (XPS) to identify the corrosion products formed on the surface. The results showed that increasing the Al content enhanced the corrosion resistance through obstructing pitting attack on the surface by the refinement of grain boundary carbides and the formation of a protective passive layer rich in carbide and oxide compounds. The combination of both Al and Nb promoted the corrosion resistance further, by enriching the passive layer with Nb and higher levels of carbide and oxide compounds, despite the presence of martensite and grain size refinement by NbCN. Increasing the cooling rate reduced the corrosion resistance due to the refinement of grain size, giving a higher density of grain boundaries that act as active sites, besides increasing the level of carbide distribution in the microstructure. Controlled rolling offered higher corrosion resistance than hot rolling, independent of the composition, because of the absence of martensite, the presence of low-angle boundary and the refinement of grain boundary carbides provided by controlled rolling. |
first_indexed | 2024-03-06T12:43:32Z |
format | Article |
id | UMPir28735 |
institution | Universiti Malaysia Pahang |
language | English |
last_indexed | 2024-03-06T12:43:32Z |
publishDate | 2020 |
publisher | Elsevier |
record_format | dspace |
spelling | UMPir287352022-11-17T07:04:16Z http://umpir.ump.edu.my/id/eprint/28735/ The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel Qaban, Abdullah Mohmed, Tasneem M. M., Quazi Naher, Sumsun TJ Mechanical engineering and machinery The effect of the addition of aluminium and niobium, and processing conditions, including cooling rate and rolling condition, on the corrosion behaviour of HSLA steel in 10 wt% sulphuric acid environment has been investigated. The experimental procedures included electrochemical corrosion techniques using potentiodynamic and electrochemical impedance spectroscopy, as well as weight loss method. The microstructure was examined using optical and scanning electron microscopes in order to investigate the effect of the microstructural features on the corrosion behaviour. Surface films were evaluated by X-ray photoelectron spectroscopy (XPS) to identify the corrosion products formed on the surface. The results showed that increasing the Al content enhanced the corrosion resistance through obstructing pitting attack on the surface by the refinement of grain boundary carbides and the formation of a protective passive layer rich in carbide and oxide compounds. The combination of both Al and Nb promoted the corrosion resistance further, by enriching the passive layer with Nb and higher levels of carbide and oxide compounds, despite the presence of martensite and grain size refinement by NbCN. Increasing the cooling rate reduced the corrosion resistance due to the refinement of grain size, giving a higher density of grain boundaries that act as active sites, besides increasing the level of carbide distribution in the microstructure. Controlled rolling offered higher corrosion resistance than hot rolling, independent of the composition, because of the absence of martensite, the presence of low-angle boundary and the refinement of grain boundary carbides provided by controlled rolling. Elsevier 2020 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28735/2/The%20effect%20of%20Al%20and%20Nb%20contents%2C%20cooling%20rate%20and%20rolling.pdf Qaban, Abdullah and Mohmed, Tasneem and M. M., Quazi and Naher, Sumsun (2020) The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel. Materials Today Communications, 25 (101362). pp. 1-11. ISSN 2352-4928. (Published) https://doi.org/10.1016/j.mtcomm.2020.101362 https://doi.org/10.1016/j.mtcomm.2020.101362 |
spellingShingle | TJ Mechanical engineering and machinery Qaban, Abdullah Mohmed, Tasneem M. M., Quazi Naher, Sumsun The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel |
title | The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel |
title_full | The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel |
title_fullStr | The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel |
title_full_unstemmed | The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel |
title_short | The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel |
title_sort | effect of al and nb contents cooling rate and rolling condition on the microstructure and corrosion behaviour of hsla steel |
topic | TJ Mechanical engineering and machinery |
url | http://umpir.ump.edu.my/id/eprint/28735/2/The%20effect%20of%20Al%20and%20Nb%20contents%2C%20cooling%20rate%20and%20rolling.pdf |
work_keys_str_mv | AT qabanabdullah theeffectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT mohmedtasneem theeffectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT mmquazi theeffectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT nahersumsun theeffectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT qabanabdullah effectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT mohmedtasneem effectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT mmquazi effectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel AT nahersumsun effectofalandnbcontentscoolingrateandrollingconditiononthemicrostructureandcorrosionbehaviourofhslasteel |