The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel

The effect of the addition of aluminium and niobium, and processing conditions, including cooling rate and rolling condition, on the corrosion behaviour of HSLA steel in 10 wt% sulphuric acid environment has been investigated. The experimental procedures included electrochemical corrosion techniques...

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Main Authors: Qaban, Abdullah, Mohmed, Tasneem, M. M., Quazi, Naher, Sumsun
Format: Article
Language:English
Published: Elsevier 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/28735/2/The%20effect%20of%20Al%20and%20Nb%20contents%2C%20cooling%20rate%20and%20rolling.pdf
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author Qaban, Abdullah
Mohmed, Tasneem
M. M., Quazi
Naher, Sumsun
author_facet Qaban, Abdullah
Mohmed, Tasneem
M. M., Quazi
Naher, Sumsun
author_sort Qaban, Abdullah
collection UMP
description The effect of the addition of aluminium and niobium, and processing conditions, including cooling rate and rolling condition, on the corrosion behaviour of HSLA steel in 10 wt% sulphuric acid environment has been investigated. The experimental procedures included electrochemical corrosion techniques using potentiodynamic and electrochemical impedance spectroscopy, as well as weight loss method. The microstructure was examined using optical and scanning electron microscopes in order to investigate the effect of the microstructural features on the corrosion behaviour. Surface films were evaluated by X-ray photoelectron spectroscopy (XPS) to identify the corrosion products formed on the surface. The results showed that increasing the Al content enhanced the corrosion resistance through obstructing pitting attack on the surface by the refinement of grain boundary carbides and the formation of a protective passive layer rich in carbide and oxide compounds. The combination of both Al and Nb promoted the corrosion resistance further, by enriching the passive layer with Nb and higher levels of carbide and oxide compounds, despite the presence of martensite and grain size refinement by NbCN. Increasing the cooling rate reduced the corrosion resistance due to the refinement of grain size, giving a higher density of grain boundaries that act as active sites, besides increasing the level of carbide distribution in the microstructure. Controlled rolling offered higher corrosion resistance than hot rolling, independent of the composition, because of the absence of martensite, the presence of low-angle boundary and the refinement of grain boundary carbides provided by controlled rolling.
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spelling UMPir287352022-11-17T07:04:16Z http://umpir.ump.edu.my/id/eprint/28735/ The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel Qaban, Abdullah Mohmed, Tasneem M. M., Quazi Naher, Sumsun TJ Mechanical engineering and machinery The effect of the addition of aluminium and niobium, and processing conditions, including cooling rate and rolling condition, on the corrosion behaviour of HSLA steel in 10 wt% sulphuric acid environment has been investigated. The experimental procedures included electrochemical corrosion techniques using potentiodynamic and electrochemical impedance spectroscopy, as well as weight loss method. The microstructure was examined using optical and scanning electron microscopes in order to investigate the effect of the microstructural features on the corrosion behaviour. Surface films were evaluated by X-ray photoelectron spectroscopy (XPS) to identify the corrosion products formed on the surface. The results showed that increasing the Al content enhanced the corrosion resistance through obstructing pitting attack on the surface by the refinement of grain boundary carbides and the formation of a protective passive layer rich in carbide and oxide compounds. The combination of both Al and Nb promoted the corrosion resistance further, by enriching the passive layer with Nb and higher levels of carbide and oxide compounds, despite the presence of martensite and grain size refinement by NbCN. Increasing the cooling rate reduced the corrosion resistance due to the refinement of grain size, giving a higher density of grain boundaries that act as active sites, besides increasing the level of carbide distribution in the microstructure. Controlled rolling offered higher corrosion resistance than hot rolling, independent of the composition, because of the absence of martensite, the presence of low-angle boundary and the refinement of grain boundary carbides provided by controlled rolling. Elsevier 2020 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28735/2/The%20effect%20of%20Al%20and%20Nb%20contents%2C%20cooling%20rate%20and%20rolling.pdf Qaban, Abdullah and Mohmed, Tasneem and M. M., Quazi and Naher, Sumsun (2020) The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel. Materials Today Communications, 25 (101362). pp. 1-11. ISSN 2352-4928. (Published) https://doi.org/10.1016/j.mtcomm.2020.101362 https://doi.org/10.1016/j.mtcomm.2020.101362
spellingShingle TJ Mechanical engineering and machinery
Qaban, Abdullah
Mohmed, Tasneem
M. M., Quazi
Naher, Sumsun
The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
title The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
title_full The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
title_fullStr The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
title_full_unstemmed The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
title_short The effect of Al and Nb contents, cooling rate and rolling condition on the microstructure and corrosion behaviour of HSLA steel
title_sort effect of al and nb contents cooling rate and rolling condition on the microstructure and corrosion behaviour of hsla steel
topic TJ Mechanical engineering and machinery
url http://umpir.ump.edu.my/id/eprint/28735/2/The%20effect%20of%20Al%20and%20Nb%20contents%2C%20cooling%20rate%20and%20rolling.pdf
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