Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts
Co/mesoporous alumina (MA) catalysts promoted with Ce, La, Sm, and Y were evaluated via methane dry reforming. Co particle dispersion on MA was evidently improved after promoter incorporation, resulting in smaller crystallite size and lesser Co agglomeration. Unlike Ce and La promoters, the employme...
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2020
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| Online Access: | http://umpir.ump.edu.my/id/eprint/28860/1/Mahadi%20B.%20Bahari%20INPRESS-PRE-PROOFS.pdf |
| _version_ | 1825813427110543360 |
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| author | Mahadi, Bahari Herma Dina, Setiabudi Nguyen, Trinh Duy Phuong, Pham T. T. Truong, Quang Duc Aishah, Abdul Jalil Nurul Aini, Razali Vo, Dai-Viet N. |
| author_facet | Mahadi, Bahari Herma Dina, Setiabudi Nguyen, Trinh Duy Phuong, Pham T. T. Truong, Quang Duc Aishah, Abdul Jalil Nurul Aini, Razali Vo, Dai-Viet N. |
| author_sort | Mahadi, Bahari |
| collection | UMP |
| description | Co/mesoporous alumina (MA) catalysts promoted with Ce, La, Sm, and Y were evaluated via methane dry reforming. Co particle dispersion on MA was evidently improved after promoter incorporation, resulting in smaller crystallite size and lesser Co agglomeration. Unlike Ce and La promoters, the employment of Y and Sm promoters reduced catalyst reducibility by strengthening Co-MA interaction. The reactant conversions improved in the order of YCo/MA > LaCo/MA > CeCo/MA > SmCo/MA > Co/MA, while the amount of carbon deposit was recorded with the sequence of Co/MA > SmCo/MA > LaCo/MA > CeCo/MA > YCo/MA. Additionally, YCo/MA attained the highest activity (CH4 conversion = 85.8%, CO2 conversion = 92.2%) and possessed the lowest carbon deposition (7.02%) due to great Co dispersion, small Co particle size with strong Co-MA interaction and higher oxygen storage capacity. H2/CO ratios were obtained within 0.78-0.86, slightly lower than 1 in consequence of the reverse water-gas shift. |
| first_indexed | 2024-03-06T12:43:51Z |
| format | Article |
| id | UMPir28860 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:43:51Z |
| publishDate | 2020 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | UMPir288602022-06-20T06:11:11Z http://umpir.ump.edu.my/id/eprint/28860/ Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts Mahadi, Bahari Herma Dina, Setiabudi Nguyen, Trinh Duy Phuong, Pham T. T. Truong, Quang Duc Aishah, Abdul Jalil Nurul Aini, Razali Vo, Dai-Viet N. TP Chemical technology Co/mesoporous alumina (MA) catalysts promoted with Ce, La, Sm, and Y were evaluated via methane dry reforming. Co particle dispersion on MA was evidently improved after promoter incorporation, resulting in smaller crystallite size and lesser Co agglomeration. Unlike Ce and La promoters, the employment of Y and Sm promoters reduced catalyst reducibility by strengthening Co-MA interaction. The reactant conversions improved in the order of YCo/MA > LaCo/MA > CeCo/MA > SmCo/MA > Co/MA, while the amount of carbon deposit was recorded with the sequence of Co/MA > SmCo/MA > LaCo/MA > CeCo/MA > YCo/MA. Additionally, YCo/MA attained the highest activity (CH4 conversion = 85.8%, CO2 conversion = 92.2%) and possessed the lowest carbon deposition (7.02%) due to great Co dispersion, small Co particle size with strong Co-MA interaction and higher oxygen storage capacity. H2/CO ratios were obtained within 0.78-0.86, slightly lower than 1 in consequence of the reverse water-gas shift. Elsevier 2020-07-15 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/28860/1/Mahadi%20B.%20Bahari%20INPRESS-PRE-PROOFS.pdf Mahadi, Bahari and Herma Dina, Setiabudi and Nguyen, Trinh Duy and Phuong, Pham T. T. and Truong, Quang Duc and Aishah, Abdul Jalil and Nurul Aini, Razali and Vo, Dai-Viet N. (2020) Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts. Chemical Engineering Science, 228 (115967). pp. 1-11. ISSN 0009-2509. (Published) https://doi.org/10.1016/j.ces.2020.115967 https://doi.org/10.1016/j.ces.2020.115967 |
| spellingShingle | TP Chemical technology Mahadi, Bahari Herma Dina, Setiabudi Nguyen, Trinh Duy Phuong, Pham T. T. Truong, Quang Duc Aishah, Abdul Jalil Nurul Aini, Razali Vo, Dai-Viet N. Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts |
| title | Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts |
| title_full | Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts |
| title_fullStr | Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts |
| title_full_unstemmed | Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts |
| title_short | Insight into the influence of rare-earth promoter (CeO2, La2O3, Y2O3, and Sm2O3) addition toward methane dry reforming over Co/mesoporous alumina catalysts |
| title_sort | insight into the influence of rare earth promoter ceo2 la2o3 y2o3 and sm2o3 addition toward methane dry reforming over co mesoporous alumina catalysts |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/28860/1/Mahadi%20B.%20Bahari%20INPRESS-PRE-PROOFS.pdf |
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