The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector
The simple and simultaneous determination of silicic, boric and carbonic acids was made using ion-exclusion chromatography (IEC) and a Corona™ charged aerosol detector (C-CAD). Silicic and boric acids were separated by the column packed with a weakly acidic cation-exchange resin in H+-form and ultra...
| Autors principals: | , , , , , |
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| Format: | Article |
| Idioma: | English |
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MDPI
2016
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| Matèries: | |
| Accés en línia: | http://umpir.ump.edu.my/id/eprint/29878/1/The%20simultaneous%20determination%20of%20silicic%2C%20boric%20and%20carbonic.pdf |
| _version_ | 1825813593260556288 |
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| author | Otsuka, Yu Nakatani, Nobutake Takahashi, Takuya Kozaki, Daisuke Mori, Masanobu Tanaka, Kazuhiko |
| author_facet | Otsuka, Yu Nakatani, Nobutake Takahashi, Takuya Kozaki, Daisuke Mori, Masanobu Tanaka, Kazuhiko |
| author_sort | Otsuka, Yu |
| collection | UMP |
| description | The simple and simultaneous determination of silicic, boric and carbonic acids was made using ion-exclusion chromatography (IEC) and a Corona™ charged aerosol detector (C-CAD). Silicic and boric acids were separated by the column packed with a weakly acidic cation-exchange resin in H+-form and ultra-pure water eluent, and the detector responses were improved by the addition of acetonitrile to eluent. Under the optimized conditions, the simultaneous determination of weak inorganic acids, except for carbonic acid, was successfully performed. When the conversion column packed with a strong acidic cation-exchange resin in Na+- or K+-form was inserted between the separation column and the detector, weak inorganic acids including carbonic acid could be detected by the C-CAD. The calibration curves were linear in the range of 0.5–10 mg·L−1 as Si for silicic acid (r2 = 0.996), 10–100 mg·L−1 as B for boric acid (r2 = 0.998) and 1.3–21 mg·L−1 as C for carbonic acid (r2 = 0.993). The detection limits based on three times the standard deviation were 0.03 mg·L−1 as Si for silicic acid, 0.40 mg·L−1 as B for boric acid and 0.08 mg·L−1 as C for carbonic acid. This method was applicable to river, hot spring and drinking water. |
| first_indexed | 2024-03-06T12:46:19Z |
| format | Article |
| id | UMPir29878 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:46:19Z |
| publishDate | 2016 |
| publisher | MDPI |
| record_format | dspace |
| spelling | UMPir298782020-11-12T06:46:43Z http://umpir.ump.edu.my/id/eprint/29878/ The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector Otsuka, Yu Nakatani, Nobutake Takahashi, Takuya Kozaki, Daisuke Mori, Masanobu Tanaka, Kazuhiko TP Chemical technology The simple and simultaneous determination of silicic, boric and carbonic acids was made using ion-exclusion chromatography (IEC) and a Corona™ charged aerosol detector (C-CAD). Silicic and boric acids were separated by the column packed with a weakly acidic cation-exchange resin in H+-form and ultra-pure water eluent, and the detector responses were improved by the addition of acetonitrile to eluent. Under the optimized conditions, the simultaneous determination of weak inorganic acids, except for carbonic acid, was successfully performed. When the conversion column packed with a strong acidic cation-exchange resin in Na+- or K+-form was inserted between the separation column and the detector, weak inorganic acids including carbonic acid could be detected by the C-CAD. The calibration curves were linear in the range of 0.5–10 mg·L−1 as Si for silicic acid (r2 = 0.996), 10–100 mg·L−1 as B for boric acid (r2 = 0.998) and 1.3–21 mg·L−1 as C for carbonic acid (r2 = 0.993). The detection limits based on three times the standard deviation were 0.03 mg·L−1 as Si for silicic acid, 0.40 mg·L−1 as B for boric acid and 0.08 mg·L−1 as C for carbonic acid. This method was applicable to river, hot spring and drinking water. MDPI 2016-03 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/29878/1/The%20simultaneous%20determination%20of%20silicic%2C%20boric%20and%20carbonic.pdf Otsuka, Yu and Nakatani, Nobutake and Takahashi, Takuya and Kozaki, Daisuke and Mori, Masanobu and Tanaka, Kazuhiko (2016) The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector. Separations, 3 (1). pp. 1-10. ISSN 2297-8739. (Published) https://doi.org/10.3390/chromatography3010009 |
| spellingShingle | TP Chemical technology Otsuka, Yu Nakatani, Nobutake Takahashi, Takuya Kozaki, Daisuke Mori, Masanobu Tanaka, Kazuhiko The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector |
| title | The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector |
| title_full | The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector |
| title_fullStr | The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector |
| title_full_unstemmed | The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector |
| title_short | The simultaneous determination of silicic, boric and carbonic acids in natural water via ion-exclusion chromatography with a charged aerosol detector |
| title_sort | simultaneous determination of silicic boric and carbonic acids in natural water via ion exclusion chromatography with a charged aerosol detector |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/29878/1/The%20simultaneous%20determination%20of%20silicic%2C%20boric%20and%20carbonic.pdf |
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