Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties
In this study, a renewable phenolic component was synthesized using empty fruit bunch fibers via microwave-assisted liquefaction known as Liquefied Empty Fruit Bunch (LEFB). LEFB can be used as phenolic derivative to replace petroleum-based phenol as it contains aromatic group in lignin that can be...
| Main Authors: | , , , , , |
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| Format: | Conference or Workshop Item |
| Language: | English English |
| Published: |
Trans Tech Publications, Switzerland
2020
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| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/30505/1/9.1%20Lignin-based%20polybenzoxazine%20derived%20from%20empty%20fruit%20bunch%20fibers.pdf http://umpir.ump.edu.my/id/eprint/30505/7/Lignin-based%20polybenzoxazine%20derived%20from%20empty%20fruit%20bunch%20fibers%20with%20good%20thermal%20and%20mechanical%20properties.pdf |
| _version_ | 1796994441650634752 |
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| author | Nurfatin Farhanah, Rohimi Rasidi, Roslan Nurjannah, Salim Siti Noor Hidayah, Mustapha Sarani, Zakaria Chin, Hua Chia |
| author_facet | Nurfatin Farhanah, Rohimi Rasidi, Roslan Nurjannah, Salim Siti Noor Hidayah, Mustapha Sarani, Zakaria Chin, Hua Chia |
| author_sort | Nurfatin Farhanah, Rohimi |
| collection | UMP |
| description | In this study, a renewable phenolic component was synthesized using empty fruit bunch fibers via microwave-assisted liquefaction known as Liquefied Empty Fruit Bunch (LEFB). LEFB can be used as phenolic derivative to replace petroleum-based phenol as it contains aromatic group in lignin that can be used as starting materials to synthesis polybenzoxazine resins. A Lignin-based benzoxazine (L-PBz) has been synthesized using a solventless approach from the reaction of LEFB, furfurylamine as the amine component and paraformaldehyde via Mannich condensation reaction. Two different ratios of LEFB:furfurylamine:paraformaldehyde which are 1:1:1 and 1:1:2 were investigated. The thermal properties and polymerization behavior of the L-PBz were analyzed using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), respectively. In addition, cured-polybenzoxazine composites were also prepared by hot-pressing the uncured L-PBz at 250 °C for 4 hours, and the mechanical properties of the composites were assessed through Izod impact strength test. TGA analysis showed that, L-PBz with ratio of 1:1:1 exhibit a high char yield compared to 1:1:2 which is 47% vs 43%, respectively, after being heated until 900 °C. However, L-PBz with ratio of 1:1:2 showed good polymerization behavior compared to 1:1:1 which indicated by the curing temperature 215 °C vs 238 °C. L-PBz composites, which added with cellulose nanocrystal (CNC) fillers have better strength compared with the absence of fillers. As a conclusion, the aromatic structure of lignin in empty fruit bunch fibers has presented a promising alternative to replace petroleum-based phenol in polybenzoxazine synthesis. |
| first_indexed | 2024-03-06T12:47:51Z |
| format | Conference or Workshop Item |
| id | UMPir30505 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-03-06T12:47:51Z |
| publishDate | 2020 |
| publisher | Trans Tech Publications, Switzerland |
| record_format | dspace |
| spelling | UMPir305052021-02-22T06:23:29Z http://umpir.ump.edu.my/id/eprint/30505/ Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties Nurfatin Farhanah, Rohimi Rasidi, Roslan Nurjannah, Salim Siti Noor Hidayah, Mustapha Sarani, Zakaria Chin, Hua Chia T Technology (General) In this study, a renewable phenolic component was synthesized using empty fruit bunch fibers via microwave-assisted liquefaction known as Liquefied Empty Fruit Bunch (LEFB). LEFB can be used as phenolic derivative to replace petroleum-based phenol as it contains aromatic group in lignin that can be used as starting materials to synthesis polybenzoxazine resins. A Lignin-based benzoxazine (L-PBz) has been synthesized using a solventless approach from the reaction of LEFB, furfurylamine as the amine component and paraformaldehyde via Mannich condensation reaction. Two different ratios of LEFB:furfurylamine:paraformaldehyde which are 1:1:1 and 1:1:2 were investigated. The thermal properties and polymerization behavior of the L-PBz were analyzed using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), respectively. In addition, cured-polybenzoxazine composites were also prepared by hot-pressing the uncured L-PBz at 250 °C for 4 hours, and the mechanical properties of the composites were assessed through Izod impact strength test. TGA analysis showed that, L-PBz with ratio of 1:1:1 exhibit a high char yield compared to 1:1:2 which is 47% vs 43%, respectively, after being heated until 900 °C. However, L-PBz with ratio of 1:1:2 showed good polymerization behavior compared to 1:1:1 which indicated by the curing temperature 215 °C vs 238 °C. L-PBz composites, which added with cellulose nanocrystal (CNC) fillers have better strength compared with the absence of fillers. As a conclusion, the aromatic structure of lignin in empty fruit bunch fibers has presented a promising alternative to replace petroleum-based phenol in polybenzoxazine synthesis. Trans Tech Publications, Switzerland 2020 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/30505/1/9.1%20Lignin-based%20polybenzoxazine%20derived%20from%20empty%20fruit%20bunch%20fibers.pdf pdf en http://umpir.ump.edu.my/id/eprint/30505/7/Lignin-based%20polybenzoxazine%20derived%20from%20empty%20fruit%20bunch%20fibers%20with%20good%20thermal%20and%20mechanical%20properties.pdf Nurfatin Farhanah, Rohimi and Rasidi, Roslan and Nurjannah, Salim and Siti Noor Hidayah, Mustapha and Sarani, Zakaria and Chin, Hua Chia (2020) Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties. In: Symposium on Industrial Science and Technology, SISTEC 2019 , 22-23 Aug. 2019 , Kuantan, Malaysia. pp. 121-126., 981. ISSN 1662-9752 https://doi.org/10.4028/www.scientific.net/MSF.981.121 |
| spellingShingle | T Technology (General) Nurfatin Farhanah, Rohimi Rasidi, Roslan Nurjannah, Salim Siti Noor Hidayah, Mustapha Sarani, Zakaria Chin, Hua Chia Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| title | Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| title_full | Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| title_fullStr | Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| title_full_unstemmed | Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| title_short | Lignin-based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| title_sort | lignin based polybenzoxazine derived from empty fruit bunch fibers with good thermal and mechanical properties |
| topic | T Technology (General) |
| url | http://umpir.ump.edu.my/id/eprint/30505/1/9.1%20Lignin-based%20polybenzoxazine%20derived%20from%20empty%20fruit%20bunch%20fibers.pdf http://umpir.ump.edu.my/id/eprint/30505/7/Lignin-based%20polybenzoxazine%20derived%20from%20empty%20fruit%20bunch%20fibers%20with%20good%20thermal%20and%20mechanical%20properties.pdf |
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