Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes
In this study, biopolymer composite electrolytes based on chitosan:ammonium iodide:Zn(II)-complex plasticized with glycerol were successfully prepared using the solution casting technique. Various electrical and electrochemical parameters of the biopolymer composite electrolytes’ films were evaluate...
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI
2020
|
| Subjects: | |
| Online Access: | http://umpir.ump.edu.my/id/eprint/30865/1/Investigation%20of%20ion%20transport%20parameters%20and%20electrochemical%20performance.pdf |
| _version_ | 1825813760206438400 |
|---|---|
| author | M. Hadi, Jihad Aziz, Shujahadeen B. Saeed, Salah R. Brza, Mohamad A. Abdulwahid, Rebar T. Hamsan, Muhamad H. Abdullah, Ranjdar M. Mohd F. Z., Kadir Saifful Kamaluddin, Muzakir |
| author_facet | M. Hadi, Jihad Aziz, Shujahadeen B. Saeed, Salah R. Brza, Mohamad A. Abdulwahid, Rebar T. Hamsan, Muhamad H. Abdullah, Ranjdar M. Mohd F. Z., Kadir Saifful Kamaluddin, Muzakir |
| author_sort | M. Hadi, Jihad |
| collection | UMP |
| description | In this study, biopolymer composite electrolytes based on chitosan:ammonium iodide:Zn(II)-complex plasticized with glycerol were successfully prepared using the solution casting technique. Various electrical and electrochemical parameters of the biopolymer composite electrolytes’ films were evaluated prior to device application. The highest conducting plasticized membrane was found to have a conductivity of 1.17 × 10−4 S/cm. It is shown that the number density, mobility, and diffusion coefficient of cations and anions fractions are increased with the glycerol amount. Field emission scanning electron microscope and Fourier transform infrared spectroscopy techniques are used to study the morphology and structure of the films. The non-Debye type of relaxation process was confirmed from the peak appearance of the dielectric relaxation study. The obtained transference number of ions (cations and anions) and electrons for the highest conducting sample were identified to be 0.98 and 0.02, respectively. Linear sweep voltammetry shows that the electrochemical stability of the highest conducting plasticized system is 1.37 V. The cyclic voltammetry response displayed no redox reaction peaks over its entire potential range. It was discovered that the addition of Zn(II)-complex and glycerol plasticizer improved the electric double-layer capacitor device performances. Numerous crucial parameters of the electric double-layer capacitor device were obtained from the charge-discharge profile. The prepared electric double-layer capacitor device showed that the initial values of specific capacitance, equivalence series resistance, energy density, and power density are 36 F/g, 177 Ω, 4.1 Wh/kg, and 480 W/kg, respectively. |
| first_indexed | 2024-03-06T12:48:48Z |
| format | Article |
| id | UMPir30865 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:48:48Z |
| publishDate | 2020 |
| publisher | MDPI |
| record_format | dspace |
| spelling | UMPir308652021-06-30T14:20:37Z http://umpir.ump.edu.my/id/eprint/30865/ Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes M. Hadi, Jihad Aziz, Shujahadeen B. Saeed, Salah R. Brza, Mohamad A. Abdulwahid, Rebar T. Hamsan, Muhamad H. Abdullah, Ranjdar M. Mohd F. Z., Kadir Saifful Kamaluddin, Muzakir TP Chemical technology In this study, biopolymer composite electrolytes based on chitosan:ammonium iodide:Zn(II)-complex plasticized with glycerol were successfully prepared using the solution casting technique. Various electrical and electrochemical parameters of the biopolymer composite electrolytes’ films were evaluated prior to device application. The highest conducting plasticized membrane was found to have a conductivity of 1.17 × 10−4 S/cm. It is shown that the number density, mobility, and diffusion coefficient of cations and anions fractions are increased with the glycerol amount. Field emission scanning electron microscope and Fourier transform infrared spectroscopy techniques are used to study the morphology and structure of the films. The non-Debye type of relaxation process was confirmed from the peak appearance of the dielectric relaxation study. The obtained transference number of ions (cations and anions) and electrons for the highest conducting sample were identified to be 0.98 and 0.02, respectively. Linear sweep voltammetry shows that the electrochemical stability of the highest conducting plasticized system is 1.37 V. The cyclic voltammetry response displayed no redox reaction peaks over its entire potential range. It was discovered that the addition of Zn(II)-complex and glycerol plasticizer improved the electric double-layer capacitor device performances. Numerous crucial parameters of the electric double-layer capacitor device were obtained from the charge-discharge profile. The prepared electric double-layer capacitor device showed that the initial values of specific capacitance, equivalence series resistance, energy density, and power density are 36 F/g, 177 Ω, 4.1 Wh/kg, and 480 W/kg, respectively. MDPI 2020-11 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/30865/1/Investigation%20of%20ion%20transport%20parameters%20and%20electrochemical%20performance.pdf M. Hadi, Jihad and Aziz, Shujahadeen B. and Saeed, Salah R. and Brza, Mohamad A. and Abdulwahid, Rebar T. and Hamsan, Muhamad H. and Abdullah, Ranjdar M. and Mohd F. Z., Kadir and Saifful Kamaluddin, Muzakir (2020) Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes. Membranes, 10 (11). pp. 1-27. ISSN 2077-0375. (Published) https://doi.org/10.3390/membranes10110363 https://doi.org/10.3390/membranes10110363 |
| spellingShingle | TP Chemical technology M. Hadi, Jihad Aziz, Shujahadeen B. Saeed, Salah R. Brza, Mohamad A. Abdulwahid, Rebar T. Hamsan, Muhamad H. Abdullah, Ranjdar M. Mohd F. Z., Kadir Saifful Kamaluddin, Muzakir Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes |
| title | Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes |
| title_full | Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes |
| title_fullStr | Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes |
| title_full_unstemmed | Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes |
| title_short | Investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan-based proton conducting polymer composite electrolytes |
| title_sort | investigation of ion transport parameters and electrochemical performance of plasticized biocompatible chitosan based proton conducting polymer composite electrolytes |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/30865/1/Investigation%20of%20ion%20transport%20parameters%20and%20electrochemical%20performance.pdf |
| work_keys_str_mv | AT mhadijihad investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT azizshujahadeenb investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT saeedsalahr investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT brzamohamada investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT abdulwahidrebart investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT hamsanmuhamadh investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT abdullahranjdarm investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT mohdfzkadir investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes AT saiffulkamaluddinmuzakir investigationofiontransportparametersandelectrochemicalperformanceofplasticizedbiocompatiblechitosanbasedprotonconductingpolymercompositeelectrolytes |