Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater

Environmental pollution by toxic compounds is gaining wider concern in modern developed society. The petroleum refining industry produces a large amount of wastewater due to the amount of water used in refining the processes, particularly for cooling systems and lead to increasing wastewater that wi...

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Main Authors: Bala, M.S., Abdul Aziz, Mohd Azoddein, Ahdash, M.I., Alshwal, B.Y.
Format: Article
Language:English
Published: Malaysian Technical Universities Network (MTUN) 2018
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/31442/1/COMPARATIVE%20STUDY%20FOR%20ACTIVATION%20OF%20%20%20HYDROGEN%20PEROXIDE%20BY%20CHEMICAL%20REAGENTS.pdf
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author Bala, M.S.
Abdul Aziz, Mohd Azoddein
Ahdash, M.I.
Alshwal, B.Y.
author_facet Bala, M.S.
Abdul Aziz, Mohd Azoddein
Ahdash, M.I.
Alshwal, B.Y.
author_sort Bala, M.S.
collection UMP
description Environmental pollution by toxic compounds is gaining wider concern in modern developed society. The petroleum refining industry produces a large amount of wastewater due to the amount of water used in refining the processes, particularly for cooling systems and lead to increasing wastewater that will impact the environment. The aim of this research is to reduce chemical oxygen demand (COD) in petrochemical wastewater by activation of hydrogen peroxide using two different reagents (Fe2+, Al3+). In this research was compared several parameters to COD removals such as the effects of concentration / dosage of H2O2, concentration, and dosages of Al2(SO4)3 and concentration and dosages of FeSO4 on the removal efficiency of COD. In this study is proven the effect of Fenton’s reagent process besides the dosage between hydrogen peroxide (H2O2) and ferrous ion (Fe2+) in the reagent that Fenton process was highly efficient to decrease COD and total suspended solid (TSS) reduction. However, addition of aluminium with hydrogen peroxide does not have any effect to remove COD. The result found that overall removal was achieved by 70% in term of COD, and 88 % in term of TSS using Fenton’s reagent process.
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spelling UMPir314422021-09-17T06:21:57Z http://umpir.ump.edu.my/id/eprint/31442/ Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater Bala, M.S. Abdul Aziz, Mohd Azoddein Ahdash, M.I. Alshwal, B.Y. TP Chemical technology Environmental pollution by toxic compounds is gaining wider concern in modern developed society. The petroleum refining industry produces a large amount of wastewater due to the amount of water used in refining the processes, particularly for cooling systems and lead to increasing wastewater that will impact the environment. The aim of this research is to reduce chemical oxygen demand (COD) in petrochemical wastewater by activation of hydrogen peroxide using two different reagents (Fe2+, Al3+). In this research was compared several parameters to COD removals such as the effects of concentration / dosage of H2O2, concentration, and dosages of Al2(SO4)3 and concentration and dosages of FeSO4 on the removal efficiency of COD. In this study is proven the effect of Fenton’s reagent process besides the dosage between hydrogen peroxide (H2O2) and ferrous ion (Fe2+) in the reagent that Fenton process was highly efficient to decrease COD and total suspended solid (TSS) reduction. However, addition of aluminium with hydrogen peroxide does not have any effect to remove COD. The result found that overall removal was achieved by 70% in term of COD, and 88 % in term of TSS using Fenton’s reagent process. Malaysian Technical Universities Network (MTUN) 2018-07 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/31442/1/COMPARATIVE%20STUDY%20FOR%20ACTIVATION%20OF%20%20%20HYDROGEN%20PEROXIDE%20BY%20CHEMICAL%20REAGENTS.pdf Bala, M.S. and Abdul Aziz, Mohd Azoddein and Ahdash, M.I. and Alshwal, B.Y. (2018) Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater. Journal of Engineering and Technology, 9 (2). pp. 1-12. ISSN 2180-3811 (print); 2289-814X (online). (Published) https://journal.utem.edu.my/index.php/jet/article/view/1681/COMPARATIVE%20STUDY%20FOR%20ACTIVATION%20OF%20HYDROGEN%20PEROXIDE
spellingShingle TP Chemical technology
Bala, M.S.
Abdul Aziz, Mohd Azoddein
Ahdash, M.I.
Alshwal, B.Y.
Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater
title Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater
title_full Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater
title_fullStr Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater
title_full_unstemmed Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater
title_short Comparative study for activation of hydorgen peroxide by chemical reagents (Fe2+, Al3+) to reduce chemical oxygen demand in petrochemical wastewater
title_sort comparative study for activation of hydorgen peroxide by chemical reagents fe2 al3 to reduce chemical oxygen demand in petrochemical wastewater
topic TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/31442/1/COMPARATIVE%20STUDY%20FOR%20ACTIVATION%20OF%20%20%20HYDROGEN%20PEROXIDE%20BY%20CHEMICAL%20REAGENTS.pdf
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AT abdulazizmohdazoddein comparativestudyforactivationofhydorgenperoxidebychemicalreagentsfe2al3toreducechemicaloxygendemandinpetrochemicalwastewater
AT ahdashmi comparativestudyforactivationofhydorgenperoxidebychemicalreagentsfe2al3toreducechemicaloxygendemandinpetrochemicalwastewater
AT alshwalby comparativestudyforactivationofhydorgenperoxidebychemicalreagentsfe2al3toreducechemicaloxygendemandinpetrochemicalwastewater