Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design

Naturally inspired biosorbent from macro alga species is favored because of its excellent biosorptive capability and low cost. The present investigation reports the potential of red macro-alga, E. spinosum as a biosorbent to remove both anionic and cationic azo dyes, namely Acid Yellow 17 (AY17) and...

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Main Authors: Nadiah, Mokhtar, Edriyana, Abd Aziz, Azmi, Aris, Syazwan, N.moni
Format: Article
Language:English
English
Published: Elsevier Ltd. 2020
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/31566/8/JPCE_2020_20_Original_V3%20%282%29updated.pdf
http://umpir.ump.edu.my/id/eprint/31566/14/Biosorption%20of%20cationic%20and%20anionic%20azo%20dye%20onto%20red%20macro%20alga.pdf
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author Nadiah, Mokhtar
Edriyana, Abd Aziz
Azmi, Aris
Syazwan, N.moni
author_facet Nadiah, Mokhtar
Edriyana, Abd Aziz
Azmi, Aris
Syazwan, N.moni
author_sort Nadiah, Mokhtar
collection UMP
description Naturally inspired biosorbent from macro alga species is favored because of its excellent biosorptive capability and low cost. The present investigation reports the potential of red macro-alga, E. spinosum as a biosorbent to remove both anionic and cationic azo dyes, namely Acid Yellow 17 (AY17) and Methylene Blue (MB) from aqueous solution. A resolution V fractional factorial design (2v5-1) analysis was employed to study the main effects and interaction of variables on the biosorption process. Factorial matrix with five variables; pH (2-12), dosage (0.4-2 g/L), initial concentration (50-200 mg/L), contact time (5-120 min) and temperature (30-50ºC) at two levels were conducted in batch study. Pareto charts and ANOVA (within 95% confidence level) were applied to examine the relationship and significance between independent variables and their interactions. A regression model with R2AY17=0.9998 and R2MB=0.9995 was implemented to fit the experimental data. The result indicated that the most significant variables that affect the biosorption process were initial concentration and dosage. Experimental screenings such as this is crucial in optimization studies. The successful capability of E.Spinosum as biosorbent for both dyes implies a great potential for local marine macro alga as an alternative resource for biosorption process.
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spelling UMPir315662021-11-10T04:21:01Z http://umpir.ump.edu.my/id/eprint/31566/ Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design Nadiah, Mokhtar Edriyana, Abd Aziz Azmi, Aris Syazwan, N.moni TA Engineering (General). Civil engineering (General) Naturally inspired biosorbent from macro alga species is favored because of its excellent biosorptive capability and low cost. The present investigation reports the potential of red macro-alga, E. spinosum as a biosorbent to remove both anionic and cationic azo dyes, namely Acid Yellow 17 (AY17) and Methylene Blue (MB) from aqueous solution. A resolution V fractional factorial design (2v5-1) analysis was employed to study the main effects and interaction of variables on the biosorption process. Factorial matrix with five variables; pH (2-12), dosage (0.4-2 g/L), initial concentration (50-200 mg/L), contact time (5-120 min) and temperature (30-50ºC) at two levels were conducted in batch study. Pareto charts and ANOVA (within 95% confidence level) were applied to examine the relationship and significance between independent variables and their interactions. A regression model with R2AY17=0.9998 and R2MB=0.9995 was implemented to fit the experimental data. The result indicated that the most significant variables that affect the biosorption process were initial concentration and dosage. Experimental screenings such as this is crucial in optimization studies. The successful capability of E.Spinosum as biosorbent for both dyes implies a great potential for local marine macro alga as an alternative resource for biosorption process. Elsevier Ltd. 2020 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/31566/8/JPCE_2020_20_Original_V3%20%282%29updated.pdf pdf en http://umpir.ump.edu.my/id/eprint/31566/14/Biosorption%20of%20cationic%20and%20anionic%20azo%20dye%20onto%20red%20macro%20alga.pdf Nadiah, Mokhtar and Edriyana, Abd Aziz and Azmi, Aris and Syazwan, N.moni (2020) Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design. Physics and Chemistry of the Earth, Parts A/B/C. ISSN 1474-7065. (Unpublished) (Unpublished)
spellingShingle TA Engineering (General). Civil engineering (General)
Nadiah, Mokhtar
Edriyana, Abd Aziz
Azmi, Aris
Syazwan, N.moni
Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design
title Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design
title_full Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design
title_fullStr Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design
title_full_unstemmed Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design
title_short Biosorption of cationic and anionic azo dye onto red macro alga: euchema spinosum. determination of the optimal experimental variables using resolution V fractional factorial design
title_sort biosorption of cationic and anionic azo dye onto red macro alga euchema spinosum determination of the optimal experimental variables using resolution v fractional factorial design
topic TA Engineering (General). Civil engineering (General)
url http://umpir.ump.edu.my/id/eprint/31566/8/JPCE_2020_20_Original_V3%20%282%29updated.pdf
http://umpir.ump.edu.my/id/eprint/31566/14/Biosorption%20of%20cationic%20and%20anionic%20azo%20dye%20onto%20red%20macro%20alga.pdf
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AT edriyanaabdaziz biosorptionofcationicandanionicazodyeontoredmacroalgaeuchemaspinosumdeterminationoftheoptimalexperimentalvariablesusingresolutionvfractionalfactorialdesign
AT azmiaris biosorptionofcationicandanionicazodyeontoredmacroalgaeuchemaspinosumdeterminationoftheoptimalexperimentalvariablesusingresolutionvfractionalfactorialdesign
AT syazwannmoni biosorptionofcationicandanionicazodyeontoredmacroalgaeuchemaspinosumdeterminationoftheoptimalexperimentalvariablesusingresolutionvfractionalfactorialdesign