Kinetic modelling characterization of cellulose modified surface for methylene blue removal from aqueous media

In this work, commercial cellulose was modified with allylthiourea (Cel-AT) to remove methylene blue (MB) from aqueous solution. Characterization study include FTIR analysis along with UV spectrophotometer. A variety of physico-chemical properties such as kinetic, total sorption capacity loaded and...

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Bibliographic Details
Main Authors: Siti Maizatul Ameera, Azhar, Ahmad Salihin, Samsudin, Wan Norfazilah, Wan Ismail, Nurlin, Abu Samah
Format: Article
Language:English
Published: John Wiley & Sons, Inc. 2021
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Online Access:http://umpir.ump.edu.my/id/eprint/31591/1/MB.pdf
Description
Summary:In this work, commercial cellulose was modified with allylthiourea (Cel-AT) to remove methylene blue (MB) from aqueous solution. Characterization study include FTIR analysis along with UV spectrophotometer. A variety of physico-chemical properties such as kinetic, total sorption capacity loaded and pH effect by using Cel-AT sorbent has been carried out. The main finding was the adsorption total capacity of Cel-AT for MB was 3 times more than commercial cellulose (Cel) when the concentration of MB increase in batch mode. In kinetic study, the MB removal efficiency was at 90% after 5 min of removal using Cel-AT as a sorbent and Cel-AT fulfil pseudo second order of reaction. The optimum MB removal is at pH 11 with 95% of removal. There was spectral peak was observed in the spectrum of FTIR and it has been addressed accordingly. As a conclusion, the suggested method improved the quality of MB sorption onto the Cel-AT in terms of contact time and less laborious.