W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte

W18O49 nanowires (NWs)-reduced graphene oxide (rGO) nanocomposite is examined as a new active material for supercapacitors electrode, which reveals its high specific capacitance and excellent rate performance in AlCl3 aqueous electrolyte. Electrochemical studies show that the presence of rGO enhance...

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Main Authors: Thalji, Mohammad R., Ali, Gomaa A. M., Liu, Porun, Zhong, Yu Lin, K. F., Chong
Format: Article
Language:English
Published: Elsevier 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/32019/1/W18O49%20nanowires-graphene%20nanocomposite.pdf
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author Thalji, Mohammad R.
Ali, Gomaa A. M.
Liu, Porun
Zhong, Yu Lin
K. F., Chong
author_facet Thalji, Mohammad R.
Ali, Gomaa A. M.
Liu, Porun
Zhong, Yu Lin
K. F., Chong
author_sort Thalji, Mohammad R.
collection UMP
description W18O49 nanowires (NWs)-reduced graphene oxide (rGO) nanocomposite is examined as a new active material for supercapacitors electrode, which reveals its high specific capacitance and excellent rate performance in AlCl3 aqueous electrolyte. Electrochemical studies show that the presence of rGO enhances Al3+ ions diffusion in the nanocomposite, thus provides more ions for intercalation pseudocapacitance. The fabrication of asymmetric supercapacitor W18O49 NWs-rGO//rGO demonstrates high specific capacitance of 365.5 F g−1 at 1 A g−1 and excellent cycling stability with 96.7% capacitance retention at 12,000 cycles. Interestingly, it delivers high energy density of 28.5 Wh kg−1 and power density of 751 W kg−1, which is the highest energy density value for all reported W18O49-based supercapacitor device. The work explores W18O49 NWs-rGO nanocomposite as a new electrode material for supercapacitors application with superior electrochemical performance, which may open up a new direction for high-performance energy storage in Al3+ electrolyte.
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spelling UMPir320192021-09-14T03:09:23Z http://umpir.ump.edu.my/id/eprint/32019/ W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte Thalji, Mohammad R. Ali, Gomaa A. M. Liu, Porun Zhong, Yu Lin K. F., Chong TK Electrical engineering. Electronics Nuclear engineering W18O49 nanowires (NWs)-reduced graphene oxide (rGO) nanocomposite is examined as a new active material for supercapacitors electrode, which reveals its high specific capacitance and excellent rate performance in AlCl3 aqueous electrolyte. Electrochemical studies show that the presence of rGO enhances Al3+ ions diffusion in the nanocomposite, thus provides more ions for intercalation pseudocapacitance. The fabrication of asymmetric supercapacitor W18O49 NWs-rGO//rGO demonstrates high specific capacitance of 365.5 F g−1 at 1 A g−1 and excellent cycling stability with 96.7% capacitance retention at 12,000 cycles. Interestingly, it delivers high energy density of 28.5 Wh kg−1 and power density of 751 W kg−1, which is the highest energy density value for all reported W18O49-based supercapacitor device. The work explores W18O49 NWs-rGO nanocomposite as a new electrode material for supercapacitors application with superior electrochemical performance, which may open up a new direction for high-performance energy storage in Al3+ electrolyte. Elsevier 2021 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/32019/1/W18O49%20nanowires-graphene%20nanocomposite.pdf Thalji, Mohammad R. and Ali, Gomaa A. M. and Liu, Porun and Zhong, Yu Lin and K. F., Chong (2021) W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte. Chemical Engineering Journal, 409 (128216). pp. 1-11. ISSN 1385-8947. (Published) https://doi.org/10.1016/j.cej.2020.128216 https://doi.org/10.1016/j.cej.2020.128216
spellingShingle TK Electrical engineering. Electronics Nuclear engineering
Thalji, Mohammad R.
Ali, Gomaa A. M.
Liu, Porun
Zhong, Yu Lin
K. F., Chong
W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte
title W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte
title_full W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte
title_fullStr W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte
title_full_unstemmed W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte
title_short W18O49 nanowires-graphene nanocomposite for asymmetric supercapacitors employing AlCl3 aqueous electrolyte
title_sort w18o49 nanowires graphene nanocomposite for asymmetric supercapacitors employing alcl3 aqueous electrolyte
topic TK Electrical engineering. Electronics Nuclear engineering
url http://umpir.ump.edu.my/id/eprint/32019/1/W18O49%20nanowires-graphene%20nanocomposite.pdf
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