Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte
In the present work, hybrid polymer electrolyte based on carboxymethyl cellulose-polyvinyl alcohol-ammonium nitrate-ethylene carbonate (CMC–PVA–NH4NO3–C3H4O3) become the promising materials that has demonstrated outstanding physical properties as an electrolytes system in solar cell. In the frame of...
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| Format: | Article |
| Language: | English English |
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John Wiley & Sons, Inc.
2021
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| Online Access: | http://umpir.ump.edu.my/id/eprint/33143/1/Effect%20of%20C3%20H4%20O3%C2%A0on%20band%20gap%20narrowing.pdf http://umpir.ump.edu.my/id/eprint/33143/7/Effect%20of%20C3H4O3%20on%20Band%20Gap%20Narrowing%20of%20Proton%20Conductive%20Hybrid%20Polymer%20Electrolyte.pdf |
| _version_ | 1825814156191727616 |
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| author | Saadiah, Mohd Ali Singh, Pramod Kumar Samsudin, Ahmad Salihin |
| author_facet | Saadiah, Mohd Ali Singh, Pramod Kumar Samsudin, Ahmad Salihin |
| author_sort | Saadiah, Mohd Ali |
| collection | UMP |
| description | In the present work, hybrid polymer electrolyte based on carboxymethyl cellulose-polyvinyl alcohol-ammonium nitrate-ethylene carbonate (CMC–PVA–NH4NO3–C3H4O3) become the promising materials that has demonstrated outstanding physical properties as an electrolytes system in solar cell. In the frame of solar cell progress, the electrical conductivity and optical bandgap of polymer electrolytes are equally explored. The characterization is carried out via electrical impedance spectroscopy (EIS) and ultraviolet visible-near infrared (UV-VIS-NIR) spectroscopy. An equivalent circuit of parallel combination, bulk resistance (Rb), and constant phase element (CPE) is obtained from transparent conductive film, CMC–PVA–NH4NO3–C3H4O3. The optimum ionic conductivity is accomplished at 3.92 × 10−3 S cm-1 for sample containing with 6 wt.% of C3H4O3. The absorption spectra are evaluated in the wavelength ranging from 200 to 1100 nm. Theoretical analysis reveals that the addition of 6 wt. % EC is initiating the band gap narrowing from 4.96 to 4.88 eV. The results show that the present developed materials-based polymer electrolytes have great potential for solar energy devices. |
| first_indexed | 2024-03-06T12:54:41Z |
| format | Article |
| id | UMPir33143 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-03-06T12:54:41Z |
| publishDate | 2021 |
| publisher | John Wiley & Sons, Inc. |
| record_format | dspace |
| spelling | UMPir331432023-12-14T07:09:40Z http://umpir.ump.edu.my/id/eprint/33143/ Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte Saadiah, Mohd Ali Singh, Pramod Kumar Samsudin, Ahmad Salihin TS Manufactures In the present work, hybrid polymer electrolyte based on carboxymethyl cellulose-polyvinyl alcohol-ammonium nitrate-ethylene carbonate (CMC–PVA–NH4NO3–C3H4O3) become the promising materials that has demonstrated outstanding physical properties as an electrolytes system in solar cell. In the frame of solar cell progress, the electrical conductivity and optical bandgap of polymer electrolytes are equally explored. The characterization is carried out via electrical impedance spectroscopy (EIS) and ultraviolet visible-near infrared (UV-VIS-NIR) spectroscopy. An equivalent circuit of parallel combination, bulk resistance (Rb), and constant phase element (CPE) is obtained from transparent conductive film, CMC–PVA–NH4NO3–C3H4O3. The optimum ionic conductivity is accomplished at 3.92 × 10−3 S cm-1 for sample containing with 6 wt.% of C3H4O3. The absorption spectra are evaluated in the wavelength ranging from 200 to 1100 nm. Theoretical analysis reveals that the addition of 6 wt. % EC is initiating the band gap narrowing from 4.96 to 4.88 eV. The results show that the present developed materials-based polymer electrolytes have great potential for solar energy devices. John Wiley & Sons, Inc. 2021 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33143/1/Effect%20of%20C3%20H4%20O3%C2%A0on%20band%20gap%20narrowing.pdf pdf en http://umpir.ump.edu.my/id/eprint/33143/7/Effect%20of%20C3H4O3%20on%20Band%20Gap%20Narrowing%20of%20Proton%20Conductive%20Hybrid%20Polymer%20Electrolyte.pdf Saadiah, Mohd Ali and Singh, Pramod Kumar and Samsudin, Ahmad Salihin (2021) Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte. Macromolecular Symposia, 397 (1). pp. 1-2. ISSN 1521-3900. (Published) https://doi.org/10.1002/masy.202000237 https://doi.org/10.1002/masy.202000237 |
| spellingShingle | TS Manufactures Saadiah, Mohd Ali Singh, Pramod Kumar Samsudin, Ahmad Salihin Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title | Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_full | Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_fullStr | Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_full_unstemmed | Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_short | Effect of C3 H4 O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_sort | effect of c3 h4 o3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| topic | TS Manufactures |
| url | http://umpir.ump.edu.my/id/eprint/33143/1/Effect%20of%20C3%20H4%20O3%C2%A0on%20band%20gap%20narrowing.pdf http://umpir.ump.edu.my/id/eprint/33143/7/Effect%20of%20C3H4O3%20on%20Band%20Gap%20Narrowing%20of%20Proton%20Conductive%20Hybrid%20Polymer%20Electrolyte.pdf |
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