Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte
In the present work, hybrid polymer electrolyte based on carboxymethyl cellulose-polyvinyl alcohol-ammonium nitrate-ethylene carbonate (CMC–PVA–NH4NO3–C3H4O3) become the promising materials that has demonstrated outstanding physical properties as an electrolytes system in solar cell. In the frame of...
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| Format: | Article |
| Language: | English |
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John Wiley and Sons Inc
2021
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| Online Access: | http://umpir.ump.edu.my/id/eprint/33169/1/Effect%20of%20C3H4O3%20on%20band%20gap%20narrowing%20of%20proton%20conductive%20hybrid.pdf |
| _version_ | 1825814161159880704 |
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| author | Saadiah, Mohd Ali Singh, Pramod Kumar Ahmad Salihin, Samsudin |
| author_facet | Saadiah, Mohd Ali Singh, Pramod Kumar Ahmad Salihin, Samsudin |
| author_sort | Saadiah, Mohd Ali |
| collection | UMP |
| description | In the present work, hybrid polymer electrolyte based on carboxymethyl cellulose-polyvinyl alcohol-ammonium nitrate-ethylene carbonate (CMC–PVA–NH4NO3–C3H4O3) become the promising materials that has demonstrated outstanding physical properties as an electrolytes system in solar cell. In the frame of solar cell progress, the electrical conductivity and optical bandgap of polymer electrolytes are equally explored. The characterization is carried out via electrical impedance spectroscopy (EIS) and ultraviolet visible-near infrared (UV-VIS-NIR) spectroscopy. An equivalent circuit of parallel combination, bulk resistance (Rb), and constant phase element (CPE) is obtained from transparent conductive film, CMC–PVA–NH4NO3–C3H4O3. The optimum ionic conductivity is accomplished at 3.92 × 10−3 S cm-1 for sample containing with 6 wt.% of C3H4O3. The absorption spectra are evaluated in the wavelength ranging from 200 to 1100 nm. Theoretical analysis reveals that the addition of 6 wt. % EC is initiating the band gap narrowing from 4.96 to 4.88 eV. The results show that the present developed materials-based polymer electrolytes have great potential for solar energy devices. |
| first_indexed | 2024-03-06T12:54:45Z |
| format | Article |
| id | UMPir33169 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:54:45Z |
| publishDate | 2021 |
| publisher | John Wiley and Sons Inc |
| record_format | dspace |
| spelling | UMPir331692023-10-17T07:13:29Z http://umpir.ump.edu.my/id/eprint/33169/ Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte Saadiah, Mohd Ali Singh, Pramod Kumar Ahmad Salihin, Samsudin T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology In the present work, hybrid polymer electrolyte based on carboxymethyl cellulose-polyvinyl alcohol-ammonium nitrate-ethylene carbonate (CMC–PVA–NH4NO3–C3H4O3) become the promising materials that has demonstrated outstanding physical properties as an electrolytes system in solar cell. In the frame of solar cell progress, the electrical conductivity and optical bandgap of polymer electrolytes are equally explored. The characterization is carried out via electrical impedance spectroscopy (EIS) and ultraviolet visible-near infrared (UV-VIS-NIR) spectroscopy. An equivalent circuit of parallel combination, bulk resistance (Rb), and constant phase element (CPE) is obtained from transparent conductive film, CMC–PVA–NH4NO3–C3H4O3. The optimum ionic conductivity is accomplished at 3.92 × 10−3 S cm-1 for sample containing with 6 wt.% of C3H4O3. The absorption spectra are evaluated in the wavelength ranging from 200 to 1100 nm. Theoretical analysis reveals that the addition of 6 wt. % EC is initiating the band gap narrowing from 4.96 to 4.88 eV. The results show that the present developed materials-based polymer electrolytes have great potential for solar energy devices. John Wiley and Sons Inc 2021-06 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33169/1/Effect%20of%20C3H4O3%20on%20band%20gap%20narrowing%20of%20proton%20conductive%20hybrid.pdf Saadiah, Mohd Ali and Singh, Pramod Kumar and Ahmad Salihin, Samsudin (2021) Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte. Macromolecular Symposia, 397 (1). pp. 1-5. ISSN 1022-1360. (Published) https://doi.org/10.1002/masy.202000237 https://doi.org/10.1002/masy.202000237 |
| spellingShingle | T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology Saadiah, Mohd Ali Singh, Pramod Kumar Ahmad Salihin, Samsudin Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title | Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_full | Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_fullStr | Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_full_unstemmed | Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_short | Effect of C3H4O3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| title_sort | effect of c3h4o3 on band gap narrowing of proton conductive hybrid polymer electrolyte |
| topic | T Technology (General) TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/33169/1/Effect%20of%20C3H4O3%20on%20band%20gap%20narrowing%20of%20proton%20conductive%20hybrid.pdf |
| work_keys_str_mv | AT saadiahmohdali effectofc3h4o3onbandgapnarrowingofprotonconductivehybridpolymerelectrolyte AT singhpramodkumar effectofc3h4o3onbandgapnarrowingofprotonconductivehybridpolymerelectrolyte AT ahmadsalihinsamsudin effectofc3h4o3onbandgapnarrowingofprotonconductivehybridpolymerelectrolyte |