Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation
The rod-like SBA-15 was transformed into fibrous type SBA-15 (F-SBA-15). The Ni/F-SBA-15 was catalytically evaluated in CO2 methanation and compared with conventional Ni/SBA-15. A superior catalytic performance was shown by Ni/F-SBA-15 (CO2 conversion = 99.7%, and CH4 yield = 98.2%) than Ni/SBA-15 (...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2021
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| Online Access: | http://umpir.ump.edu.my/id/eprint/33852/1/NiFibrous%20type%20SBA-15.pdf |
| _version_ | 1825814287755509760 |
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| author | Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil |
| author_facet | Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil |
| author_sort | Syahida Nasuha, Bukhari |
| collection | UMP |
| description | The rod-like SBA-15 was transformed into fibrous type SBA-15 (F-SBA-15). The Ni/F-SBA-15 was catalytically evaluated in CO2 methanation and compared with conventional Ni/SBA-15. A superior catalytic performance was shown by Ni/F-SBA-15 (CO2 conversion = 99.7%, and CH4 yield = 98.2%) than Ni/SBA-15 (CO2 conversion = 91.1%, and CH4 yield = 87.5%). This phenomenon was attributed to the favorable physicochemical properties of F-SBA-15 as evidenced by the characterization results. A higher homogeneity of finer Ni was embedded onto the F-SBA-15 support, subsequently strengthened the Ni interaction with F-SBA-15, and increased the amount of moderate basic sites. The in situ FTIR studies evidenced the CO2 methanation over both catalysts proceeded via CO2 dissociation pathway. Three intermediate species (linear carbonyl, unidentate, and bidentate carbonates) were detected for Ni/F-SBA-15, while only bidentate carbonates were detected for Ni/SBA-15, signifying excellent catalytic attributes of Ni/F-SBA-15. Additionally, Ni/F-SBA-15 demonstrated higher stability and coke resistance ability than Ni/SBA-15. |
| first_indexed | 2024-03-06T12:56:31Z |
| format | Article |
| id | UMPir33852 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:56:31Z |
| publishDate | 2021 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | UMPir338522022-04-22T04:25:43Z http://umpir.ump.edu.my/id/eprint/33852/ Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil TP Chemical technology The rod-like SBA-15 was transformed into fibrous type SBA-15 (F-SBA-15). The Ni/F-SBA-15 was catalytically evaluated in CO2 methanation and compared with conventional Ni/SBA-15. A superior catalytic performance was shown by Ni/F-SBA-15 (CO2 conversion = 99.7%, and CH4 yield = 98.2%) than Ni/SBA-15 (CO2 conversion = 91.1%, and CH4 yield = 87.5%). This phenomenon was attributed to the favorable physicochemical properties of F-SBA-15 as evidenced by the characterization results. A higher homogeneity of finer Ni was embedded onto the F-SBA-15 support, subsequently strengthened the Ni interaction with F-SBA-15, and increased the amount of moderate basic sites. The in situ FTIR studies evidenced the CO2 methanation over both catalysts proceeded via CO2 dissociation pathway. Three intermediate species (linear carbonyl, unidentate, and bidentate carbonates) were detected for Ni/F-SBA-15, while only bidentate carbonates were detected for Ni/SBA-15, signifying excellent catalytic attributes of Ni/F-SBA-15. Additionally, Ni/F-SBA-15 demonstrated higher stability and coke resistance ability than Ni/SBA-15. Elsevier 2021 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/33852/1/NiFibrous%20type%20SBA-15.pdf Syahida Nasuha, Bukhari and Chi, Cheng Chong and Setiabudi, Herma Dina and Yoke, Wang Cheng and Lee, Peng Teh and Aishah, Abdul Jalil (2021) Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation. Chemical Engineering Science, 229 (116141). pp. 1-12. ISSN 0009-2509. (Published) https://doi.org/10.1016/j.ces.2020.116141 https://doi.org/10.1016/j.ces.2020.116141 |
| spellingShingle | TP Chemical technology Syahida Nasuha, Bukhari Chi, Cheng Chong Setiabudi, Herma Dina Yoke, Wang Cheng Lee, Peng Teh Aishah, Abdul Jalil Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation |
| title | Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation |
| title_full | Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation |
| title_fullStr | Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation |
| title_full_unstemmed | Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation |
| title_short | Ni/Fibrous type SBA-15: Highly active and coke resistant catalyst for CO2 methanation |
| title_sort | ni fibrous type sba 15 highly active and coke resistant catalyst for co2 methanation |
| topic | TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/33852/1/NiFibrous%20type%20SBA-15.pdf |
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