Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating

This research aims to synthesize a biobased polyurethane coating from epoxidized palm oil (EPO) and determine the effect of different silicon dioxide (SiO2) loadings on the hydrophobicity performance of the coating. In this work, EPO was firstly undergoing an acrylation reaction and followed by the...

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Main Authors: Mustapha, Siti Noor Hidayah, Md Nizam, Muhd Nazrin, Mohamad Isa, Mohamad Ismail, Roslan, Rasidi, Mustapha, Rohani
Format: Conference or Workshop Item
Language:English
English
Published: Elsevier Ltd 2021
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/34026/1/1-s2.0-S2214785321076598-main.pdf
http://umpir.ump.edu.my/id/eprint/34026/7/Synthesis%20and%20characterization%20of%20hydrophobic%20properties%20of%20silicon%20dioxide%20.pdf
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author Mustapha, Siti Noor Hidayah
Md Nizam, Muhd Nazrin
Mohamad Isa, Mohamad Ismail
Roslan, Rasidi
Mustapha, Rohani
author_facet Mustapha, Siti Noor Hidayah
Md Nizam, Muhd Nazrin
Mohamad Isa, Mohamad Ismail
Roslan, Rasidi
Mustapha, Rohani
author_sort Mustapha, Siti Noor Hidayah
collection UMP
description This research aims to synthesize a biobased polyurethane coating from epoxidized palm oil (EPO) and determine the effect of different silicon dioxide (SiO2) loadings on the hydrophobicity performance of the coating. In this work, EPO was firstly undergoing an acrylation reaction and followed by the addition of isophorone diisocyanate (IPDI) to form Polyurethane (PU). Improvement was made by adding SiO2 at different loadings into the palm oil-based PU to provide hydrophobic properties to the coating materials. The sample was characterized using Fourier Transform Infrared Spectroscopy (FTIR), water sliding angle test, and water absorption test. Based on the FTIR results, PU was successfully synthesized from EPO with SiO2 addition. The results also proved that the addition of SiO2 successfully improved the hydrophobicity of the coating. The higher the SiO2 content in palm oil PU, the shorter the time taken for the water to slide down the 25° angle coated glass and lower the water absorption percentage of the coating material. Based on the analysis, 3 phr SiO2 content showed the highest hydrophobicity performance, which could be applied in further research.
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spelling UMPir340262022-09-05T07:37:26Z http://umpir.ump.edu.my/id/eprint/34026/ Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating Mustapha, Siti Noor Hidayah Md Nizam, Muhd Nazrin Mohamad Isa, Mohamad Ismail Roslan, Rasidi Mustapha, Rohani QD Chemistry TP Chemical technology This research aims to synthesize a biobased polyurethane coating from epoxidized palm oil (EPO) and determine the effect of different silicon dioxide (SiO2) loadings on the hydrophobicity performance of the coating. In this work, EPO was firstly undergoing an acrylation reaction and followed by the addition of isophorone diisocyanate (IPDI) to form Polyurethane (PU). Improvement was made by adding SiO2 at different loadings into the palm oil-based PU to provide hydrophobic properties to the coating materials. The sample was characterized using Fourier Transform Infrared Spectroscopy (FTIR), water sliding angle test, and water absorption test. Based on the FTIR results, PU was successfully synthesized from EPO with SiO2 addition. The results also proved that the addition of SiO2 successfully improved the hydrophobicity of the coating. The higher the SiO2 content in palm oil PU, the shorter the time taken for the water to slide down the 25° angle coated glass and lower the water absorption percentage of the coating material. Based on the analysis, 3 phr SiO2 content showed the highest hydrophobicity performance, which could be applied in further research. Elsevier Ltd 2021-12-18 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/34026/1/1-s2.0-S2214785321076598-main.pdf pdf en http://umpir.ump.edu.my/id/eprint/34026/7/Synthesis%20and%20characterization%20of%20hydrophobic%20properties%20of%20silicon%20dioxide%20.pdf Mustapha, Siti Noor Hidayah and Md Nizam, Muhd Nazrin and Mohamad Isa, Mohamad Ismail and Roslan, Rasidi and Mustapha, Rohani (2021) Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating. In: Materials Today: Proceedings; 3rd Symposium on Industrial Science and Technology, SISTEC 2021 , 25 - 26 August 2021 , Kuantan, Pahang. pp. 1415-1419., 51. ISSN 2214-7853 https://doi.org/10.1016/j.matpr.2021.11.636
spellingShingle QD Chemistry
TP Chemical technology
Mustapha, Siti Noor Hidayah
Md Nizam, Muhd Nazrin
Mohamad Isa, Mohamad Ismail
Roslan, Rasidi
Mustapha, Rohani
Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating
title Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating
title_full Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating
title_fullStr Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating
title_full_unstemmed Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating
title_short Synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio-coating
title_sort synthesis and characterization of hydrophobic properties of silicon dioxide in palm oil based bio coating
topic QD Chemistry
TP Chemical technology
url http://umpir.ump.edu.my/id/eprint/34026/1/1-s2.0-S2214785321076598-main.pdf
http://umpir.ump.edu.my/id/eprint/34026/7/Synthesis%20and%20characterization%20of%20hydrophobic%20properties%20of%20silicon%20dioxide%20.pdf
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