Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications

Molten salts are utilized in concentrated solar power (CSP) as a working fluid to store and transfer solar thermal energy. In this study, we attempted to enhance the thermal energy storage (TES) characteristics of the ternary nitrate molten salt of KNO3, NaNO2, and NaNO3, also known as HITEC molten...

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Main Authors: Aljaerani, Hatem Ahmad, M., Samykano, A. K., Pandey, K., Kadirgama, George, Mathew, R., Saidur
Format: Article
Language:English
Published: Elsevier 2022
Subjects:
Online Access:http://umpir.ump.edu.my/id/eprint/34706/7/Thermophysical%20properties%20enhancement%20and%20characterization.pdf
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author Aljaerani, Hatem Ahmad
M., Samykano
A. K., Pandey
K., Kadirgama
George, Mathew
R., Saidur
author_facet Aljaerani, Hatem Ahmad
M., Samykano
A. K., Pandey
K., Kadirgama
George, Mathew
R., Saidur
author_sort Aljaerani, Hatem Ahmad
collection UMP
description Molten salts are utilized in concentrated solar power (CSP) as a working fluid to store and transfer solar thermal energy. In this study, we attempted to enhance the thermal energy storage (TES) characteristics of the ternary nitrate molten salt of KNO3, NaNO2, and NaNO3, also known as HITEC molten salt, using cupric oxide (CuO) as additives for CSP applications. HITEC was doped with 0.1, 1, 3, and 5 wt% of CuO nanoparticles using the two-step wet method. Differential scanning calorimeter (DSC) was utilized to evaluate the specific heat capacity, melting point, and latent heat of the prepared material. Thermal stability was measured by thermogravimetric analysis (TGA) while the characterization analysis was performed using Fourier-Transform Infrared (FT-IR) spectroscopy, Field Emission Scanning Electron Microscope (FESEM), and Energy Dispersive X-ray Spectroscopy (EDS). The results showed that 0.1 wt% CuO nanoparticles is the optimum CuO nanoparticles concentration which resulted in a specific heat capacity enhancement of 5.6%, a 30% improvement of latent heat, and 9% enhancement of thermal stability. The morphological analysis revealed the formation of bright chain-like nanostructure due to nanoparticle dispersion, which may the possible reason for the thermophysical property enhancement.
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spelling UMPir347062022-08-24T08:28:00Z http://umpir.ump.edu.my/id/eprint/34706/ Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications Aljaerani, Hatem Ahmad M., Samykano A. K., Pandey K., Kadirgama George, Mathew R., Saidur TJ Mechanical engineering and machinery Molten salts are utilized in concentrated solar power (CSP) as a working fluid to store and transfer solar thermal energy. In this study, we attempted to enhance the thermal energy storage (TES) characteristics of the ternary nitrate molten salt of KNO3, NaNO2, and NaNO3, also known as HITEC molten salt, using cupric oxide (CuO) as additives for CSP applications. HITEC was doped with 0.1, 1, 3, and 5 wt% of CuO nanoparticles using the two-step wet method. Differential scanning calorimeter (DSC) was utilized to evaluate the specific heat capacity, melting point, and latent heat of the prepared material. Thermal stability was measured by thermogravimetric analysis (TGA) while the characterization analysis was performed using Fourier-Transform Infrared (FT-IR) spectroscopy, Field Emission Scanning Electron Microscope (FESEM), and Energy Dispersive X-ray Spectroscopy (EDS). The results showed that 0.1 wt% CuO nanoparticles is the optimum CuO nanoparticles concentration which resulted in a specific heat capacity enhancement of 5.6%, a 30% improvement of latent heat, and 9% enhancement of thermal stability. The morphological analysis revealed the formation of bright chain-like nanostructure due to nanoparticle dispersion, which may the possible reason for the thermophysical property enhancement. Elsevier 2022 Article PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/34706/7/Thermophysical%20properties%20enhancement%20and%20characterization.pdf Aljaerani, Hatem Ahmad and M., Samykano and A. K., Pandey and K., Kadirgama and George, Mathew and R., Saidur (2022) Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications. International Communications in Heat and Mass Transfer, 132 (105898). pp. 1-9. ISSN 0735-1933. (Published) https://doi.org/10.1016/j.icheatmasstransfer.2022.105898 https://doi.org/10.1016/j.icheatmasstransfer.2022.105898
spellingShingle TJ Mechanical engineering and machinery
Aljaerani, Hatem Ahmad
M., Samykano
A. K., Pandey
K., Kadirgama
George, Mathew
R., Saidur
Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications
title Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications
title_full Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications
title_fullStr Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications
title_full_unstemmed Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications
title_short Thermophysical properties enhancement and characterization of CuO nanoparticles enhanced HITEC molten salt for concentrated solar power applications
title_sort thermophysical properties enhancement and characterization of cuo nanoparticles enhanced hitec molten salt for concentrated solar power applications
topic TJ Mechanical engineering and machinery
url http://umpir.ump.edu.my/id/eprint/34706/7/Thermophysical%20properties%20enhancement%20and%20characterization.pdf
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