Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles
The optoelectronic advantages of anchoring plasmonic silver and copper particles and non-plasmonic titanium particles onto zinc oxide (ZnO) nanoflower (NF) scaffolds for the fabrication of perovskite solar cells (PSCs) are addressed in this article. The metallic particles were sputter-deposited as a...
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| Format: | Article |
| Language: | English |
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MDPI
2022
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| Online Access: | http://umpir.ump.edu.my/id/eprint/34880/1/Optoelectronic%20enhancement%20of%20perovskite%20solar%20cells%20through%20the%20incorporation%20of%20plasmonic%20particles.pdf |
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| author | Saheed, Mohamed Salleh Mohamed Mohamed, Norani Muti Balbir Singh Mahinder, Singh Saheed, Mohamed Shuaib Mohamed Jose, Rajan |
| author_facet | Saheed, Mohamed Salleh Mohamed Mohamed, Norani Muti Balbir Singh Mahinder, Singh Saheed, Mohamed Shuaib Mohamed Jose, Rajan |
| author_sort | Saheed, Mohamed Salleh Mohamed |
| collection | UMP |
| description | The optoelectronic advantages of anchoring plasmonic silver and copper particles and non-plasmonic titanium particles onto zinc oxide (ZnO) nanoflower (NF) scaffolds for the fabrication of perovskite solar cells (PSCs) are addressed in this article. The metallic particles were sputter-deposited as a function of sputtering time to vary their size on solution-grown ZnO NFs on which methylammonium lead iodide perovskite was crystallized in a controlled environment. Optical absorption measurements showed impressive improvements in the light-harvesting efficiency (LHE) of the devices using silver nanoparticles and some concentrations of copper, whereas the LHE was relatively lower in devices used titanium than in a control device without any metallic particles. Fully functional PSCs were fabricated using the plasmonic and non-plasmonic metallic film-deco-rated ZnO NFs. Several fold enhancements in photoconversion efficiency were achieved in the sil-ver-containing devices compared with the control device, which was accompanied by an increase in the photocurrent density, photovoltage, and fill factor. To understand the plasmonic effects in the photoanode, the LHE, photo-current density, photovoltage, photoluminescence, incident pho-ton-to-current conversion efficiency, and electrochemical impedance properties were thoroughly investigated. This research showcases the efficacy of the addition of plasmonic particles onto photo anodes, which leads to improved light scattering, better charge separation, and reduced electron– hole recombination rate. |
| first_indexed | 2024-03-06T12:59:18Z |
| format | Article |
| id | UMPir34880 |
| institution | Universiti Malaysia Pahang |
| language | English |
| last_indexed | 2024-03-06T12:59:18Z |
| publishDate | 2022 |
| publisher | MDPI |
| record_format | dspace |
| spelling | UMPir348802022-08-11T03:18:55Z http://umpir.ump.edu.my/id/eprint/34880/ Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles Saheed, Mohamed Salleh Mohamed Mohamed, Norani Muti Balbir Singh Mahinder, Singh Saheed, Mohamed Shuaib Mohamed Jose, Rajan Q Science (General) QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology The optoelectronic advantages of anchoring plasmonic silver and copper particles and non-plasmonic titanium particles onto zinc oxide (ZnO) nanoflower (NF) scaffolds for the fabrication of perovskite solar cells (PSCs) are addressed in this article. The metallic particles were sputter-deposited as a function of sputtering time to vary their size on solution-grown ZnO NFs on which methylammonium lead iodide perovskite was crystallized in a controlled environment. Optical absorption measurements showed impressive improvements in the light-harvesting efficiency (LHE) of the devices using silver nanoparticles and some concentrations of copper, whereas the LHE was relatively lower in devices used titanium than in a control device without any metallic particles. Fully functional PSCs were fabricated using the plasmonic and non-plasmonic metallic film-deco-rated ZnO NFs. Several fold enhancements in photoconversion efficiency were achieved in the sil-ver-containing devices compared with the control device, which was accompanied by an increase in the photocurrent density, photovoltage, and fill factor. To understand the plasmonic effects in the photoanode, the LHE, photo-current density, photovoltage, photoluminescence, incident pho-ton-to-current conversion efficiency, and electrochemical impedance properties were thoroughly investigated. This research showcases the efficacy of the addition of plasmonic particles onto photo anodes, which leads to improved light scattering, better charge separation, and reduced electron– hole recombination rate. MDPI 2022-07 Article PeerReviewed pdf en cc_by_4 http://umpir.ump.edu.my/id/eprint/34880/1/Optoelectronic%20enhancement%20of%20perovskite%20solar%20cells%20through%20the%20incorporation%20of%20plasmonic%20particles.pdf Saheed, Mohamed Salleh Mohamed and Mohamed, Norani Muti and Balbir Singh Mahinder, Singh and Saheed, Mohamed Shuaib Mohamed and Jose, Rajan (2022) Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles. Micromachines, 13 (7). pp. 1-16. ISSN 2072-666X. (Published) https://doi.org/10.3390/mi13070999 https://doi.org/10.3390/mi13070999 |
| spellingShingle | Q Science (General) QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology Saheed, Mohamed Salleh Mohamed Mohamed, Norani Muti Balbir Singh Mahinder, Singh Saheed, Mohamed Shuaib Mohamed Jose, Rajan Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| title | Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| title_full | Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| title_fullStr | Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| title_full_unstemmed | Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| title_short | Optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| title_sort | optoelectronic enhancement of perovskite solar cells through the incorporation of plasmonic particles |
| topic | Q Science (General) QD Chemistry T Technology (General) TK Electrical engineering. Electronics Nuclear engineering TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/34880/1/Optoelectronic%20enhancement%20of%20perovskite%20solar%20cells%20through%20the%20incorporation%20of%20plasmonic%20particles.pdf |
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