Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production
The replacement of traditional diesel fuels with an alternative energy source like biodiesel is an excellent choice to lessen the depletion of non-renewable energy source such as fossil fuels. For application of low-cost heterogeneous catalyst for generation of biodiesel, most of waste-based catalys...
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| Format: | Conference or Workshop Item |
| Language: | English English |
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Elsevier Ltd
2020
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| Online Access: | http://umpir.ump.edu.my/id/eprint/35605/1/Synthesis%20of%20aluminum%20chloride%20hexahydrate_polyvinyl%20alcohol%20catalyst%20for%20biodiesel%20production.pdf http://umpir.ump.edu.my/id/eprint/35605/2/Synthesis%20of%20aluminum%20chloride%20hexahydrate_polyvinyl%20alcohol%20catalyst_Abs.pdf |
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| author | F. Ismail, Nur Ishami Sulaiman, Sarina Kabbashi, Nassereldeen A. Sulaiman, Siti Zubaidah |
| author_facet | F. Ismail, Nur Ishami Sulaiman, Sarina Kabbashi, Nassereldeen A. Sulaiman, Siti Zubaidah |
| author_sort | F. Ismail, Nur Ishami |
| collection | UMP |
| description | The replacement of traditional diesel fuels with an alternative energy source like biodiesel is an excellent choice to lessen the depletion of non-renewable energy source such as fossil fuels. For application of low-cost heterogeneous catalyst for generation of biodiesel, most of waste-based catalysts are derived from inexpensive CaO resources. In this research, heterogeneous catalyst aluminum chloride hexahydrate (AlCl36H2O)/PVA was synthesized from aluminum foil wastes supported by PVA. Transesterification was used to produce biodiesel from waste cooking oil (WCO). The effect of aluminum chloride hexahydrate (AlCl36H2O)/PVA catalyst towards the yield percentage of FAME was investigated using three different operating conditions. Parameters optimized in transesterification included methanol to oil ratio (6:1, 12:1 and 18:1), reaction temperature (55°, 60°, and 65°), and amount of catalyst (2 wt%, 5 wt%, and 8 wt%). The findings showed that the catalyst loading of 2 wt%, methanol to oil molar ratio of 6:1, and temperature of 55° yielded the highest biodiesel yield from WCO. This study proves that heterogeneous catalyst aluminum chloride hexahydrate (AlCl36H2O)/PVA can replace homogeneous catalysts and to simplify the manufacturing of biodiesel, especially in the separation phase. |
| first_indexed | 2024-03-06T13:01:20Z |
| format | Conference or Workshop Item |
| id | UMPir35605 |
| institution | Universiti Malaysia Pahang |
| language | English English |
| last_indexed | 2024-03-06T13:01:20Z |
| publishDate | 2020 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | UMPir356052023-04-13T07:00:19Z http://umpir.ump.edu.my/id/eprint/35605/ Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production F. Ismail, Nur Ishami Sulaiman, Sarina Kabbashi, Nassereldeen A. Sulaiman, Siti Zubaidah QD Chemistry TA Engineering (General). Civil engineering (General) TP Chemical technology The replacement of traditional diesel fuels with an alternative energy source like biodiesel is an excellent choice to lessen the depletion of non-renewable energy source such as fossil fuels. For application of low-cost heterogeneous catalyst for generation of biodiesel, most of waste-based catalysts are derived from inexpensive CaO resources. In this research, heterogeneous catalyst aluminum chloride hexahydrate (AlCl36H2O)/PVA was synthesized from aluminum foil wastes supported by PVA. Transesterification was used to produce biodiesel from waste cooking oil (WCO). The effect of aluminum chloride hexahydrate (AlCl36H2O)/PVA catalyst towards the yield percentage of FAME was investigated using three different operating conditions. Parameters optimized in transesterification included methanol to oil ratio (6:1, 12:1 and 18:1), reaction temperature (55°, 60°, and 65°), and amount of catalyst (2 wt%, 5 wt%, and 8 wt%). The findings showed that the catalyst loading of 2 wt%, methanol to oil molar ratio of 6:1, and temperature of 55° yielded the highest biodiesel yield from WCO. This study proves that heterogeneous catalyst aluminum chloride hexahydrate (AlCl36H2O)/PVA can replace homogeneous catalysts and to simplify the manufacturing of biodiesel, especially in the separation phase. Elsevier Ltd 2020 Conference or Workshop Item PeerReviewed pdf en http://umpir.ump.edu.my/id/eprint/35605/1/Synthesis%20of%20aluminum%20chloride%20hexahydrate_polyvinyl%20alcohol%20catalyst%20for%20biodiesel%20production.pdf pdf en http://umpir.ump.edu.my/id/eprint/35605/2/Synthesis%20of%20aluminum%20chloride%20hexahydrate_polyvinyl%20alcohol%20catalyst_Abs.pdf F. Ismail, Nur Ishami and Sulaiman, Sarina and Kabbashi, Nassereldeen A. and Sulaiman, Siti Zubaidah (2020) Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production. In: Materials Today: Proceedings; 3rd International Conference on Separation Technology, ICoST 2020 , 15 -16 August 2020 , Johor. pp. 1273-1279., 47 (171967). ISSN 2214-7853 (Published) https://doi.org/10.1016/j.matpr.2021.02.794 |
| spellingShingle | QD Chemistry TA Engineering (General). Civil engineering (General) TP Chemical technology F. Ismail, Nur Ishami Sulaiman, Sarina Kabbashi, Nassereldeen A. Sulaiman, Siti Zubaidah Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production |
| title | Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production |
| title_full | Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production |
| title_fullStr | Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production |
| title_full_unstemmed | Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production |
| title_short | Synthesis of aluminum chloride hexahydrate/polyvinyl alcohol catalyst for biodiesel production |
| title_sort | synthesis of aluminum chloride hexahydrate polyvinyl alcohol catalyst for biodiesel production |
| topic | QD Chemistry TA Engineering (General). Civil engineering (General) TP Chemical technology |
| url | http://umpir.ump.edu.my/id/eprint/35605/1/Synthesis%20of%20aluminum%20chloride%20hexahydrate_polyvinyl%20alcohol%20catalyst%20for%20biodiesel%20production.pdf http://umpir.ump.edu.my/id/eprint/35605/2/Synthesis%20of%20aluminum%20chloride%20hexahydrate_polyvinyl%20alcohol%20catalyst_Abs.pdf |
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